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Issue
Korean Journal of Chemical Engineering,
Vol.37, No.11, 2054-2063, 2020
Superwetting TiO2-decorated single-walled carbon nanotube composite membrane for highly efficient oil-in-water emulsion separation
Sun Y, Zhao R, Wang Q, Zheng Y, Li G, Sun D, Wu T, Li Y
With the advantages of one-dimensional hollow structure, high porosity and prominent mechanical strength, single-walled carbon nanotubes (SWCNTs) have been extensively utilized to improve conventional filtration membranes for oil/water separation. Their intrinsic hydrophobicity, however, adversely affects the anti-fouling performance of the SWCNT membrane. Herein, a super-hydrophilic and underwater super-oleophobic hierarchical modified membrane with enhanced permeability and anti-fouling property was fabricated using the vacuum-assisted filtration technique by synergistically assembling SWCNTs and titanium dioxide (TiO2) nanoparticles on a cellulose acetate membrane. Highly dispersed SWCNTs were obtained by carboxylating treatment of agglomerate SWCNTs. The controlled stacking of SWCNTs fibers and a controllable amount of TiO2 rendered a modified membrane with high porosity and hierarchical structure, leading to an ultrahigh water flux up to 4,777.07 L·m-2·h-1, and excellent separation performance with efficiency greater than 99.47%. Most importantly, the membrane exhibited excellent anti-fouling ability during ten cycles with the aid of the super-wetting property of TiO2 nanoparticles. The results indicated that coating TiO2 nanoparticles on SWCNTs modified the surface topography of the obtained SWCNT/TiO2 membrane, which improved hydrophilicity, permeability and anti-fouling property, manifesting attractive potential applications in oil/water separation.
Keywords: Oil-in-water Emulsions; Super-hydrophilic; Underwater Super-oleophobic; SWCNT/TiO2 Membranes; SWCNT Membrane
[References]
  1. Zhang W, Zhu Y, Liu X, Wang D, Li J, Jinag L, Jin J, Angew. Chem.-Int. Edit., 53, 856, 2014
  2. Yue XJ, Li JX, Zhang T, Qiu FX, Yang DY, Xue MW, Chem. Eng. J., 328, 117, 2017
  3. Zhang S, Wang P, Fu X, Chung TS, Water Res., 52, 112, 2014
  4. Kajitvichyanukul P, Hung YT, Wang LK, Handbook of environmental engineering, Humana Press, Totowa (2011).
  5. Shannon MA, Bohn PW, Elimelech M, Georgiadis JG, Marinas BJ, Mayes AM, Nature, 452, 301, 2008
  6. Li Z, Shi T, Zhang T, Guo Q, Qiu F, Yue X, Yang D, Korean J. Chem. Eng., 36(1), 92, 2019
  7. Hu XB, Yu Y, Zhou JE, Wang YQ, Liang J, Zhang XZ, Chang QB, Song LX, J. Membr. Sci., 476, 200, 2015
  8. Fard AK, Rhadfi T, Mckay G, Al-marri M, Abdala A, Hilal N, Hussien MA, Chem. Eng. J., 293, 90, 2016
  9. Das B, Chakrabarty B, Barkakati P, Korean J. Chem. Eng., 34(10), 2559, 2017
  10. Ong C, Shi Y, Chang J, Alduraiei F, Wehbe N, Ahmed Z, Wang P, Sep. Purif. Technol., 227, 115657, 2019
  11. Chakrabarty B, Ghoshal AK, Purkait MK, J. Membr. Sci., 325(1), 427, 2008
  12. Zhang F, Zhang WB, Shi Z, Wang D, Jin J, Jiang L, Adv. Mater., 25(30), 4192, 2013
  13. Zhang W, Liu N, Cao Y, Lin X, Liu Y, Feng L, Adv. Mater. Interfaces, 4, 160002, 2017
  14. Rajakovic-Ognjanovic V, Aleksic G, Rajakovic L, J. Hazard. Mater., 154(1-3), 558, 2008
  15. Liu L, Lei J, Li L, Zhang R, Mi N, Chen H, Huang D, Li N, Mater. Lett., 195, 66, 2017
  16. Wang Z, Wang D, Li Z, Wang Y, Cellulose, 27, 2427, 2016
  17. Liu R, Li X, Liu H, Luo Z, Ma J, Zhang Z, Fu Q, RSC Adv., 6, 30301, 2016
  18. Salahi A, Mohammadi T, Behbahani RM, Hemmati M, Korean J. Chem. Eng., 32(6), 1101, 2015
  19. Wang L, Ji SL, Wang NX, Zhang R, Zhang GJ, Li JR, J. Membr. Sci., 452, 143, 2014
  20. Basumatary AK, Kumar RV, Ghoshal AK, Pugazhenthi G, J. Membr. Sci., 475, 521, 2015
  21. Adib H, Hassanajili S, Sheikhi-Kouhsar MR, Salahi A, Mohammadi T, Korean J. Chem. Eng., 32(1), 159, 2015
  22. Du L, Quan X, Fan XF, Chen S, Yu HT, Sep. Purif. Technol., 210, 891, 2019
  23. Kota AK, Kwon G, Choi W, Mabry JM, Tuteja A, Nat. Commun., 3, 1025, 2012
  24. Li F, Gao RT, Wu T, Li YJ, J. Membr. Sci., 543, 163, 2017
  25. Ghandashtani MB, Ashtiani FZ, Karimi M, Fouladitajar A, Appl. Surf. Sci., 349, 393, 2015
  26. Shi H, He Y, Pan Y, Di HH, Zeng GY, Zhang L, Zhang CL, J. Membr. Sci., 506, 60, 2016
  27. Hong A, Fane AG, Burford R, J. Membr. Sci., 222(1-2), 19, 2003
  28. Kawakatsu T, Boom RM, Nabetani H, Kikuchi Y, Nakajima M, AIChE J., 45(5), 967, 1999
  29. Kong J, Li K, Sep. Purif. Technol., 16(1), 83, 1999
  30. Wang S, Chu LY, Chen WM, Chin. J. Chem. Eng., 14(1), 37, 2006
  31. Zhu XY, Tu WT, Wee KH, Bai RB, J. Membr. Sci., 466, 36, 2014
  32. Wu Z, Chang Z, Peng K, Wang Q, Wang Z, Front. Env. Sci. Eng., 12, 1, 2018
  33. Gao SJ, Qin H, Liu P, Jin J, J. Mater. Chem. A, 3, 6649, 2015
  34. Pendergast MM, Hoek EMV, Energy Environ. Sci., 4, 1946, 2011
  35. Sun J, Iwasa M, Gao L, Zhang Q, Carbon, 42, 895, 2004
  36. Gu J, Xiao P, Chen J, Zhang J, Huang Y, Chen T, ACS Appl. Mater. Interfaces,, 6, 16204, 2014
  37. Grujicic M, Pandurangan B, Angstadt DC, Koudela KL, Cheeseman BA, J. Mater. Sci., 42(14), 5347, 2007
  38. Kalra A, Garde S, Hummer G, Proc. Natl. Acad. Sci. USA, 100, 10175, 2003
  39. Ma WJ, Song L, Yang R, Zhang TH, Zhao YC, Sun LF, Ren Y, et al., Nano Lett., 7, 2307, 2007
  40. Palama IE, D'Amone S, Biasiucci M, Gigli G, Cortese B, J. Mater. Chem. A, 2, 17666, 2014
  41. Yue XJ, Zhang T, Yang DY, Qiu FX, Li ZD, Ind. Eng. Chem. Res., 57(31), 10439, 2018
  42. Vatanpour V, Madaeni SS, Moradian R, Zinadini S, Astinchap B, Sep. Purif. Technol., 90, 69, 2012
  43. Abdelbasir SM, Shalan AE, Korean J. Chem. Eng., 36(8), 1209, 2019
  44. Thuyavan YL, Anantharaman N, Arthanareeswaran G, Ismail AF, Mangalaraja RV, Desalination, 365, 355, 2015
  45. Fujishima A, Zhang X, Tryk DA, Surf. Sci. Rep., 63, 515, 2008
  46. Yang HG, Sun CH, Qiao SZ, Zou J, Liu G, Smith SC, Cheng HM, Liu GQ, Nature, 453, 638, 2008
  47. Gao SJ, Shi Z, Zhang WB, Zhang F, Jin J, ACS Nano, 8, 6344, 2014
  48. Shi FM, Ma YX, Ma J, Wang PP, Sun WX, J. Membr. Sci., 389, 522, 2012
  49. Lopez-Lorente AI, Simonet BM, Valcarcel M, Anal. Chem., 82, 5399, 2010
  50. Moradian R, Astinchap B, Nano, 5, 139, 2010
  51. Adeli M, Bahari A, Hekmatara H, Nano, 3, 37, 2008
  52. Zhou JG, Zhou XT, Sun XH, Li RY, Murphy M, Ding ZF, Sun XL, Sham TK, Chem. Phys. Lett., 437(4-6), 229, 2007
  53. Yu Y, Yu JC, Yu JG, Kwok YC, Che YK, Zhao JC, Ding L, Ge WK, Wong PK, Appl. Catal. A: Gen., 289(2), 186, 2005
  54. Li XH, Niu JL, Zhang J, Li HL, Liu ZF, J. Phys. Chem. B, 107(11), 2453, 2003
  55. Wenzel RN, Ind. Eng. Chem., 28, 988, 1936
  56. Yuan T, Meng JQ, Hao TY, Zhang YF, Xu ML, J. Membr. Sci., 470, 112, 2014
  57. Gao P, Liu Z, Sun DD, Ng WJ, J. Mater. Chem. A, 2, 14082, 2014
  58. Peng XS, Jin J, Nakamura Y, Ohno T, Ichinose I, Nat. Nanotechnol., 4(6), 353, 2009
  59. Zhou JE, Chang QB, Wang YQ, Wang JM, Meng GY, Sep. Purif. Technol., 75(3), 243, 2010
  60. Liu YN, Su YL, Cao JL, Guan JY, Zhang RN, He MR, Fan L, Zhang Q, Jiang ZY, J. Membr. Sci., 542, 254, 2017
  61. Liu R, Raman AKY, Shaik I, Aichele C, Kim SJ, J. Water Process Eng., 26, 124, 2018
  62. Tian M, Liao Y, Wang R, J. Membr. Sci., 596, 1, 2020
  63. Zhang YQ, Shan LB, Tu ZY, Zhang YH, Sep. Purif. Technol., 63(1), 207, 2008
  64. Zhang YQ, Cui P, Du TD, Shan LB, Wang YL, Sep. Purif. Technol., 70(2), 153, 2009
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