Korean Journal of Chemical Engineering, Vol.37, No.9, 1599-1608, 2020
Nickel-cobalt alloy coatings prepared by electrodeposition Part I: Cathodic current efficiency, alloy composition, polarization behavior and throwing power
A systematic study was carried out to electrodeposit Ni-Co alloy coatings from a complexing acidic glycine bath on copper substrates. The effects of [Co2+]/[Ni2+] ratio, gly concentration, pH, current density and temperature on the current efficiency, Co content in the coatings and on polarization behavior were investigated. It was found that the CCE of these baths has a wide range starting from 55% up to a maximum value of 99.3%, relying on the operating parameters and the bath constituent. However, the CCE decreased from 96.2% to 84.8% when the gly content was enhanced from 25 to 150 g/L. On the other hand, the Co content in the deposit reached 97% (wt%) at [Co2+]/ [Ni2+]=0.43, i=16 mA cm-2, t=10min, T=20 °C. The codeposition of Co and Ni from acidic gly baths obeys the anomalous type of codeposition. The kinetic results indicate that the Tafel slope increased in the case of alloy deposition, while both the transfer coefficient αc and the exchange current io decreased. Moreover, the obtained results indicated that increasing the Co2+ content in the electrolytic solution has an inhibiting impact on the kinetics of the nickel-cobalt alloy plating. The throwing power is enhanced with enhancing [Co2+]/[Ni2+] ratios, while the addition of gly decreases it. However, the outcomes of macrothrowing power, throwing index and Wagner numbers are in excellent accord.
[References]
Mahalingam T, Sundaram K, Velumani S, Raja M, Thanikaikarasan S, Kim YD, Asomoza R, Adv. Mater. Res. , 68 , 52, 2009
Tian L, Xu J, Xiao S, Vacuum , 86 , 27, 2011
Carac G, Ispas A, J. Solid State Electrochem. , 16 , 3457, 2012
Bakhit B, Akbari A, J. Coat. Technol. Res. , 10 (2), 285, 2013
Esteves MC, Sumodjo PTA, Podlaha EJ, Electrochim. Acta , 56 (25), 9082, 2011
Karimzadeha A, Aliofkhazraeia M, Walsh FC, Surf. Coat. Technol. , 372 , 463, 2019
Abdel-Karim R, Ramadan M, El-Raghy SM, J. Nanomaterials , 2018 , 13, 2018
Vasefi S, Parvari M, Korean J. Chem. Eng. , 27 (2), 422, 2010
Park HJ, Kim KM, Kim HY, Kim DW, Won YS, Kim SK, Korean J. Chem. Eng. , 35 (7), 1547, 2018
Jeong MG, Zhuo K, Cherevko S, Chung CH, Korean J. Chem. Eng. , 29 (12), 1802, 2012
Jang KI, Hong E, Kim JH, Korean J. Chem. Eng. , 30 (3), 620, 2013
He Y, Hwang S, Cullen DA, Uddin MA, Langhorst L, et al., Energy Environ. Sci. , 12 , 250, 2019
Dokouzis A, Bella F, Theodosiou K, Gerbaldi C, Leftheriotis G, Mater. Today Energy , 15 , 100365, 2020
Kamppinen A, Aitola K, Poskela A, Miettunen K, Lund PD, Electrochim. Acta , 335 , 135652, 2020
Baptayev B, Aukenova A, Mustazheb D, Balanay MP, J. Photochem. Photobiol. A-Chem. , 383 , 11977, 2019
Nita N, Wu F, Lee JT, Yushin G, Mater. Today , 18 (5), 252, 2015
Jovic VD, Jovic BM, Pavlovic MG, Maksimovic V, J. Solid State Electrochem. , 10 , 959, 2006
Kandalkar SG, Lee HM, Seo SH, Lee K, Kim CK, Korean J. Chem. Eng. , 28 (6), 1464, 2011
Vijayakumar J, Mohan S, Kumar SA, Suseendiran SR, Pavithra S, Int. J. Hydrog. Energy , 38 (25), 10208, 2013
You YH, Gu CD, Wang XL, Tu JP, Surf. Coat. Technol. , 206 , 3632, 2012
Li JM, Cai C, Song LX, Li JF, Zhang Z, Xue MZ, Liu YG, Trans. Nonferrous Met. Soc. China , 23 , 2300, 2013
Shi L, Sun CF, Gao P, Zhou F, Liu WM, Surf. Coat. Technol. , 200 , 4870, 2006
Correia AN, Machado SAS, J. Appl. Electrochem. , 33 (5), 367, 2003
Schwartz M, Myung NV, Nobe K, J. Electrochem. Soc. , 151 (7), C468, 2004
Rahman IZ, Khaddem-Mousavi MV, Gandhi AA, Lynch TF, Rahman MA, J. Phys. Conference Series , 61 , 523, 2007
Harper CA, Electronic materials and processes handbook, McGraw Hill Professional, 1.6, New York NY (2003).
Lupi C, Dellera A, Pasquali M, Imperatori P, Surf. Coat. Technol. , 205 , 5394, 2011
Wang LP, Gao Y, Xue QJ, Liu HW, Xu T, Appl. Surf. Sci. , 242 (3-4), 326, 2005
Ergenema O, Sivaraman KM, Pane S, Pellicer E, Telekic A, Hirt AM, Baro MD, Nelson BJ, Electrochem. Acta , 56 , 1399, 2011
Golodnitsky D, Rosenberg Y, Ulus A, Electrochim. Acta , 47 (17), 2707, 2002
Yu-Fang Y, Bin D, Zhao-Hui W, Adv. Chem. Eng. Sci. , 1 , 27, 2011
Vazquez-Arenas J, Pritzker M, J. Solid State Electrochem. , 17 , 419, 2013
Gomez E, Pane S, Valles E, Electrochim. Acta , 51 (1), 146, 2005
El-Feky H, Negem M, Roy S, Helal N, Baraka A, Sci. China. Chem. , 56 (10), 1446, 2013
Goldbach S, de Kermadec R, Lapicque F, J. Appl. Electrochem. , 30 (3), 277, 2000
Karpuz A, Kockar H, Alper M, Appl. Surf. Sci. , 257 (8), 3632, 2011
Karpuz A, Kockar H, Alper M, Karaagac O, Haciismailoglu M, Appl. Surf. Sci. , 258 (8), 4005, 2012
Karpuz A, Kockar H, Alper M, J. Mater. Sci. Mater. Electron. , 24 , 3376, 2013
Golodnitsky D, Gudin NV, Volyanuk GA, J. Electrochem. Soc. , 147 (11), 4156, 2000
Idris J, Christian C, Gaius E, J. Nano Mat. , 2013 , 1, 2013
Hassani S, Raeissi K, Azzi M, Li D, Golozar MA, Szpunar JA, Corrosion Sci. , 51 , 2371, 2009
Bakhit B, Akbari A, J. Coat. Technol. Res. , 10 (2), 285, 2013
Hassani S, Raeissi K, Golozar MA, J. Appl. Electrochem. , 38 (5), 689, 2008
Marikkannu KR, Kalaignan GP, Vasudevan T, J. Alloy. Compd. , 438 , 332, 2007
Pellicer E, Pane S, Sivaraman KM, Ergeneman O, Surinach S, Baro MD, Nelson BJ, Sort J, Mater. Chem. Phys. , 130 (3), 1380, 2011
Taranina OA, Evreinova NV, Shoshina IA, Naraev VN, Tikhonov KI, Russ. J. Appl. Chem. , 83 (1), 58, 2010
Zhang YH, Feng L, Qiu W, J. Mater. Sci. , 54 (13), 9507, 2019
Tarozaite R, Sudavicius A, Sukackiene Z, Norkus E, Trans. IMF , 92 (3), 146, 2014
Gharahcheshmeh MH, Sohi MH, J. Appl. Electrochem. , 40 (8), 1563, 2010
Wei JC, Schwartz M, Nobe K, J. Electrochem. Soc. , 155 (10), D660, 2008
Boiadjieva T, Kovacheva D, Lyutov L, Monev M, J. Appl. Electrochem. , 38 (10), 1435, 2008
Lacnjevac U, Jovic BM, Jovic VD, J. Electrochem. Soc. , 159 (5), D310, 2012
Ibrahim MAM, Al Radadi RM, Mat. Chem. Phys. , 151 , 222, 2015
Ibrahim MAM, Al Radadi RM, Int. J. Electrochem. Sci. , 10 , 4946, 2015
Brenner A, Electrodeposition of alloys, Academic Press, New York, 1 (1963).
Ibrahim MAM, Bakdash RS, Surf. Coat. Technol. , 282 , 139, 2015
Ibrahim MAM, Bakdash RS, Trans. IMF , 92 (4), 218, 2014
Ibrahim MAM, J. Chem. Technol. Biotechnol. , 75 (8), 745, 2000
Muri R, Kurakane K, Sekine T, Bull. Chem. Soc. Jpn. , 49 , 335, 1976
Mohamed AE, Rashwan SM, Abdel-Wahaab SM, Kamel MM, J. Appl. Electrochem. , 33 (11), 1085, 2003
Rashwan SM, Mater. Chem. Phys. , 89 (2-3), 192, 2005
Ibrahim MAM, Abd El Rehim SS, El Naggar MM, Abbass MA, J. Appl. Surf. Finish. , 1 (4), 293, 2006
Smith RM, Martell AE, Motekaitis RJ, Critical Stability Constants of Metal Complexes Database, version 8.0, NIST, U.S. (2004).
Davies G, Kustin K, Pasternack RF, Inorg. Chem. , 8 , 1535, 1969
Guidelli R, Compton RG, Feliu JM, Gileadi E, Lipkowski J, Schmickler W, Trasatti S, Pure Appl. Chem. , 86 (2), 245, 2014
Mouanga M, Ricq L, Douglade G, Douglade J, Bercot P, Surf. Coat. Technol. , 201 , 762, 2006
Wagner C, J. Electrochem. Soc. , 98 , 116, 1951
이전 논문 다음 논문
Result Search