Korean Journal of Chemical Engineering, Vol.37, No.7, 1174-1180, 2020
Upgrading of bio-oil by ex-situ catalytic pyrolysis and in-line esterification in fluidized bed reactor
Ex-situ catalytic pyrolysis of Quercus mongolica over HZSM-5 and in-line esterification of pyrolysis/catalytic pyrolysis vapors with liquid phase n-butyl alcohol were carried out in a fluidized bed reactor. The ex-situ catalytic pyrolysis over HZSM-5 beads was performed to produce bio-oil containing aromatic hydrocarbons. The temperature of the ex-situ catalytic upgrading reaction was varied from 450 °C to 600 °C, and the maximum aromatic hydrocarbons yield was obtained at 450 °C. The selectivity for aromatic hydrocarbons as a function of catalytic reaction temperature varied depending on aromatic ring number, as the selectivity for mono-aromatic hydrocarbons decreased and that for poly-aromatic hydrocarbons increased with temperature. In-line esterification of the pyrolysis/catalytic pyrolysis vapors with liquid n-butyl alcohol was also carried out, and the GC/MS analysis results showed that the acids, aldehydes and ketones in the bio-oil were converted to esters and acetals.
[References]
Yuan Z, Eden MR, Curr. Opin. Chem. Eng. , 10 , 70, 2015
Mishra RK, Mohanty K, Renew. Energy , 141 , 549, 2019
Yao C, Tian H, Hu Z, Yin Y, Chen D, Yan X, Korean Chem. Eng. , 35 , 511, 2018
Saraeian A, Nolte MW, Shanks BH, Renew. Sust. Energ. Rev. , 104 , 262, 2019
Wang Z, Fu Z, Lin W, Li S, Song W, Korean J. Chem. Eng. , 36 (8), 1235, 2019
Sharifzadeh M, Sadeqzadeh M, Guo M, Borhani TN, Konda NVSNM, Garcia MC, Wang L, Hallett J, Shah N, Prog. Energy Combust. Sci. , 71 , 1, 2019
Ma Z, Troussard E, van Bokhoven JA, Appl. Catal. A: Gen. , 423-424 , 130, 2012
Aho A, Kumar N, Eranen K, Salmi T, Hupa M, Murzin DY, Fuel , 87 (12), 2493, 2008
Lee HW, Park SH, Jeon JK, Ryoo R, Kim W, Suh DJ, Park YK, Catal. Today , 232 , 119, 2014
Zhang L, Bao Z, Xia S, Lu Q, Walters KB, Catalysts , 8 , 659, 2018
Rahman MM, Liu RH, Cai JM, Fuel Process. Technol. , 180 , 32, 2018
Jae J, Tompsett GA, Foster AJ, Hammond KD, Auerbach SM, Lobo RF, Huber GW, J. Catal. , 279 (2), 257, 2011
Xin X, Pang S, Mercader FM, Torr KM, J. Anal. Appl. Pyrolysis , 138 , 145, 2019
Kim JY, Lee JH, Park J, Kim JK, An D, Song IK, Choi JW, J. Anal. Appl. Pyrolysis , 114 , 273, 2015
Paasikallio V, Kalogiannis K, Lappas A, Lehto J, Lehtonen J, Energy Technol. , 4 , 1, 2016
Iisa K, French RJ, Orton KA, Yung MM, Johnson DK, ten Dam J, Watson MJ, Nimlos MR, Energy Fuels , 30 (3), 2144, 2016
Sundqvist T, Oasmaa A, Koskinen A, Energy Fuels , 29 (4), 2527, 2015
Kim HN, Shafaghat H, Kim JK, Knag BS, Jeon JK, Jung SC, Lee IG, Park YK, Korean J. Chem. Eng. , 35 (4), 922, 2018
Bulushev DA, Ross JRH, Catal. Today , 171 (1), 1, 2011
Hu X, Gunawan R, Mourant D, Hasan M, Wu L, Song Y, Lievens C, Li CZ, Fuel Process. Technol. , 155 , 2, 2017
Hilten RN, Bibens BP, Kastner JR, Das JC, Energy Fuels , 24 , 673, 2010
Lee HW, Kim YM, Jae J, Sung BH, Jung SC, Kim SC, Jeon JK, Park YK, J. Anal. Appl. Pyrolysis , 122 , 282, 2016
Sluiter A, Hames B, Ruiz R, Scarlata C, Sluiter J, Templeton D, Crocker D, Technical Report, NREL/TP-510-42618 (2008).
Fan LL, Zhang YN, Liu SY, Zhou N, Chen P, Cheng YL, Addy M, Lu Q, Omar MM, Liu YH, Wang YP, Dai LL, Anderson E, Peng P, Lei HW, Ruan R, Bioresour. Technol. , 241 , 1118, 2017
Dorrestijn E, Laarhoven LJ, Arends IW, Mulder P, J. Anal. Appl. Pyrolysis , 54 , 153, 2000
Wang K, Kim KH, Brown RC, Green Chem. , 16 , 727, 2014
Zhou G, Jensen PA, Le DM, Knudsen MO, Jensen AD, Green Chem. , 18 , 1965, 2016
Carlson TR, Jae J, Lin YC, Tompsett GA, Huber GW, J. Catal. , 270 (1), 110, 2010
To AT, Resasco DE, Appl. Catal. A: Gen. , 487 , 62, 2014
Zhang HY, Xiao R, Huang H, Xiao G, Bioresour. Technol. , 100 (3), 1428, 2009
Lopez A, de Marco I, Caballero BM, Adrados A, Laresgoiti MF, Waste Manage. , 31 , 1852, 2011
Ma Z, van Bokhoven JA, ChemCatChem , 4 , 2036, 2012
Baloch HA, Nizamuddin S, Siddiqui MTH, Riaz S, Jatoi AS, Dumbre DK, Mubarak NM, Srinivasan MP, Griffin GJ, J. Environ. Chem. Eng. , 6 , 5101, 2018
Ciddor L, Bennett JA, Hunns JA, Wilson K, Lee AF, J. Chem. Technol. Biotechnol. , 90 (5), 780, 2015
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