About The Journal
  Aims and Scope
  Editorial Board
  Submit a Manuscript 
  Subscription Information
  Guidelines for Publication
  Ethics
Articles & Issues
  Search
  Issue
  Online First
  KJChE on
For Authors
  Instructions to Authors
  Ethical Responsibilities of
  Authors in KJChE
  Ethics in Publishing
  Peer Review Process
  Author's Checklist
  Copyright Transfer Form
Contact us
 
 
 
Issue
Korean Journal of Chemical Engineering,
Vol.37, No.2, 322-331, 2020
Study on the feasibility of using a pilot plant Scheibel extraction column for the extraction and separation of lanthanum and cerium from aqueous solution
Asadollahzadeh M, Torkaman R, Torab-Mostaedi M
Batch and continuous experiments were carried out in a Scheibel extraction column to separate La(III) from Ce(III). Central composite design was used to evaluate the influence of pH, extractant concentration in the batch experiments, and the influence of rotor speed, phase flow rates in the continuous experiments. At optimum conditions (pH 3.5, D2EHPA extractant concentration 0.05 M, rotor speed 128 rpm, dispersed phase flow rate 32 L/h and continuous phase flow rate 18 L/h), high extraction efficiency and separation factor equal to 88.12% and 4.89, respectively, for cerium separation from lanthanum were reasonably well predicted by the model. At higher rotor speed, La(III) and Ce(III) ions move faster from aqueous to the organic phase, which retards the higher interaction between ions and D2EHPA extractant. The results showed that this extraction column could be a potential candidate for the extraction and separation of La(III) and Ce(III) ions or other industrial wastewater.
Keywords: Rare Earth; Scheibel Column; Slip Velocity; Dispersed Phase Holdup
[References]
  1. Atwood DA, The rare earth elements: fundamentals and application, Wiley, New York (2016).
  2. Krishnamurthy N, Gupta CK, Extractive metallurgy of rare earths, CRC Press, New York (2016).
  3. Zhang J, Zhao B, Schreiner B, Separation Hydrometallurgy of Rare Earth Elements, Springer, New York (2016).
  4. Ramasamy DL, Khan S, Repo E, Sillanpaa M, Chem. Eng. J., 322, 56, 2017
  5. Ftekhar S, Srivastava V, Hammouda SB, Sillanpaa M, Carbohydr. Polym., 194, 274, 2018
  6. Zhang W, Honaker RQ, Int. J. Coal Geology, 195, 189, 2018
  7. Yin X, Wang Y, Bai X, Wang Y, Chen L, Xiao C, Diwu J, Du S, Chai Z, Albrecht-Schmitt TE, Wang S, Nature Comm., 8, 14438, 2017
  8. Zhang F, Wu W, Bian X, Zeng W, Hydrometallurgy, 149, 238, 2014
  9. Habibpour R, Dargahi M, Kashi E, Bagherpour M, Metall. Res. Technol., 115, 207, 2018
  10. Ramakul P, Leepipatpiboon N, Yamoum C, Thubsuang U, Bunnak S, Pancharoen U, Korean J. Chem. Eng., 26(3), 765, 2009
  11. Jiang F, Yin SH, Srinivasakannan C, Li SW, Peng JH, Chem. Eng. J., 334, 2208, 2018
  12. Ryu KH, Lee C, Lee GG, Jo S, Sung SW, Korean J. Chem. Eng., 30(10), 1946, 2013
  13. Kashi E, Habibpour R, Gorzin H, Maleki A, J. Rare Earths, 36, 317, 2018
  14. Abhilash, Sinha S, Sinha MK, Pandey BD, Inter. J. Miner. Process, 127, 70, 2014
  15. Sahu SK, Mishra S, Sep. Sci. Technol., 51(3), 447, 2016
  16. Banda R, Jeon HS, Lee MS, Metal. Mater. Tran. B, 45, 2009, 2014
  17. Padhan E, Sarangi K, Hydrometallurgy, 167, 134, 2017
  18. Prakorn R, Weerawat P, Ura P, Korean J. Chem. Eng., 23(1), 85, 2006
  19. Prakorn R, Ura P, Korean J. Chem. Eng., 20(4), 724, 2003
  20. Roy S, Basu S, Anitha M, Singh DK, Korean J. Chem. Eng., 34(6), 1740, 2017
  21. Song N, Zhao X, Jia Q, Zhou W, Liao W, Korean J. Chem. Eng., 27(4), 1258, 2010
  22. Xie F, Zhang TA, Dreisinger D, Doyle F, Miner. Eng., 56, 10, 2014
  23. Angelov G, Gourdon C, Korean J. Chem. Eng., 32(1), 37, 2015
  24. Amani P, Amani M, Hasanvandian R, Korean J. Chem. Eng., 34(5), 1456, 2017
  25. Lee YK, Ju DP, Kim C, Korean J. Chem. Eng., 8(2), 80, 1991
  26. Lee SC, Hyun GH, Korean J. Chem. Eng., 19(5), 827, 2002
  27. Lo TC, Commercial liquid-liquid extraction equipment, in Handbook of separation techniques for chemical engineers, P.A. Schweitzer, McGraw-Hill, New York (1979).
  28. Thornton JD, Science and Practice of Liquid-Liquid Extraction, Oxford University Press, Oxford (1992).
  29. Bart HJ, Reactive Extraction, Springer, New York (2001).
  30. Rydberg J, Cox M, Musikas C, Choppin GR, Solvent Extraction: Principles and Practice, Marcel Dekker, New York (2004).
  31. Ritcey GM, Ashbrook AW, Solvent extraction: principles and applications to process metallurgy, Elsevier, New York (1984).
  32. Asadollahzadeh M, Torab-Mostaedi M, Shahhosseini S, Ghaemi A, Chem. Eng. Process., 100, 65, 2016
  33. Torkaman R, Asadollahzadeh M, Torab-Mostaedi M, Chem. Eng. Process., 111, 7, 2017
  34. Asadollahzadeh M, Torkaman R, Torab-Mostaedi M, Chem. Eng. Res. Des., 127, 146, 2017
  35. Torab-Mostaedi M, Jalilvand H, Outokesh M, Chem. Ind. Chem. Eng. Q., 17, 333, 2011
  36. Asadollahzadeh M, Torab-Mostaedi M, Torkaman R, Chem. Eng. Process., 109, 97, 2016
  37. Asadollahzadeh M, Torab-Mostaedi M, Shahhosseini S, Ghaemi A, Chem. Eng. Res. Des., 105, 177, 2016
  38. Asadollahzadeh M, Torab-Mostaedi M, Shahhosseini S, Ghaemi A, Torkaman R, Sep. Purif. Technol., 158, 275, 2016
  39. Houshyar S, Torab-Mostaedi M, Mousavi SH, J. Chem. Pet. Eng., 51, 105, 2017
[Cited By]
  1. Asadollahzadeh M, Torkaman R, Korean Journal of Chemical Engineering, 39(1), 134, 2022
참고문헌정보(참고문헌, 인용문헌)는 화학공학소재연구정보센터에 의해 제공되고 있습니다.