Korean Journal of Chemical Engineering, Vol.36, No.5, 763-779, 2019
CO2 separation over light gases for nano-composite membrane comprising modified polyurethane with SiO2 nanoparticles
Owing to the potential of polymeric and nanocomposite membranes for industrial application in CO2 capturing and gas separation processes, permeation properties of CO2, N2 and O2 through the polymer matrix have been an object of extensive research. We measured the permeation rates of gases (pure and mixed gas) within a novel nanocomposite membrane composed of poly tetramethyleneglycol (PTMG), hexamethylene diisocyanate (HDI), and diamine chain extender, 4,4- methylenebis(2-chloroaniline) (MOCA) at various silica loadings and operating conditions. The novel polyurethane was prepared by a two-step bulk polymerization technique based on the molar ratios of the used constituents 1 : 3 : 2 for PTMG: HDI :MOCA, respectively. The FTIR spectra indicated that the extent of phase separation decreased by increase in the SiO2 content. From the DSC and XRD analyses, the existence of small crystalline areas within the soft and hard segments of matrix was proved. High thermal stability of new nanocomposites was authenticated by a 90 °C increase in the decomposition temperature upon including the SiO2 particles into the polymer matrix. By providing a longer diffusion path, a reduction in the permeation of penetrants occurred after the incorporation of SiO2 content. By raising the temperature from 25 to 45 °C, the gas permeation value of CO2, O2 and N2 rose steeply: 35, 54 and 81% in neat PU and 49, 64 and 137% in PU containing 15 wt%, respectively. Conversely, the obtained results for increasing the feed gas pressure from 6 to 10 bar revealed that the penetration of non-condensable gases, O2 and N2, decreased while the permeation rate of CO2 polar gas surged dramatically. Nevertheless, a simultaneous increment in the selectivity amounts of both gas pairs was revealed. For the gaseous mixtures, the trend of changes in permeability and selectivity values were almost identical with those of pure gas: decrease in permeation, and vice versa increase in gas pair selectivity. Eventually, the separation results of the prepared membranes indicated a strong tendency to move towards Robeson’s line by incorporation of SiO2 nanoparticles into the matrix of membranes.
[References]
Nematollahi MH, Carvalho PJ, Curr. Opin. Green Sustain. Chem. , 18 , 25, 2019
Feng CY, Khulbe KC, Matsuura T, Ismail AF, Sep. Purif. Technol. , 111 , 43, 2013
Nematollahi MH, Dehaghani AHS, Abedini R, Korean J. Chem. Eng. , 33 (2), 657, 2016
Mozafari M, Abedini R, Rahimpour A, J. Mater. Chem. A , 6 , 12380, 2018
Merkel TC, Freeman BD, Spontak RJ, He Z, Pinnau I, Meakin P, Hill AJ, Chem. Mater. , 15 , 109, 2003
Shao L, Samseth J, Hagg MB, J. Membr. Sci. , 326 (2), 285, 2009
Olivieri L, Ligi S, De Angeis MG, Cucca G, Pettinau A, Ind. Eng. Chem. Res. , 54 (44), 11199, 2015
Abedini R, Mosayebi A, Mokhtari M, Process Saf. Environ. Protect. , 114 , 229, 2018
Merkel TC, He ZJ, Pinnau I, Freeman BD, Meakin P, Hill AJ, Macromolecules , 36 (22), 8406, 2003
Okamoto Y, Du Q, Koike K, Mikes F, Merkel TC, He Z, Zhang H, Koike Y, Polym. Adv. Technol. , 27 , 33, 2016
Sundell BJ, Lawrence JA, Harrigan DJ, Vaughn JT, Pilyugina TS, Smith DR, RSC Adv. , 6 , 51619, 2016
Belov N, Nikiforov R, Starannikova L, Gmernicki KR, Maroon CR, Long BK, Shantarovich V, Yampolskii Y, Eur. Polym. J. , 93 , 602, 2017
Chu ML, Xiao YC, Chung TS, J. Membr. Sci. , 415-416 , 375, 2012
Rogan Y, Malpass-Evans R, Carta M, Lee M, Jansen JC, Bernardo P, Clarizia G, Tocci E, Friess K, Lanc M, McKeown NB, J. Mater. Chem. A , 2 , 4874, 2014
Ghanem BS, Swaidan R, Litwiller E, Pinnau I, Adv. Mater. , 26 (22), 3688, 2014
Swaidan R, Ghanem BS, Litwiller E, Pinnau I, J. Membr. Sci. , 457 , 95, 2014
Abedini R, Omidkhah MR, Dorosti F, RSC Adv. , 4 , 36522, 2014
Nematollahi MH, Dehaghani AHS, Pirouzfar V, Akhondi E, Macromol. Res. , 24 (9), 782, 2016
Murali RS, Sridhar S, Sankarshana T, Ravikumar YVL, Ind. Eng. Chem. Res. , 49 (14), 6530, 2010
Semsarzadeh MA, Ghalei B, J. Membr. Sci. , 432 , 115, 2013
Lovineh SG, Asghari M, Khanbabaei G, Appl. Surf. Sci. , 318 , 176, 2014
Vaughn JT, Koros WJ, J. Membr. Sci. , 465 , 107, 2014
Mozaffari V, Sadeghi M, Fakhar A, Khanbabaei G, Ismail AF, Sep. Purif. Technol. , 185 , 202, 2017
Guseva EN, Zuev VV, Fuller. Nanotub. Car. , 24 , 474, 2016
Chattopadhyay DK, Raju KVSN, Prog. Polym. Sci , 32 , 352, 2007
Semsarzadeh MA, Ghalei B, Fardi M, Esmaeeli M, Vakili E, Korean J. Chem. Eng. , 31 (5), 841, 2014
Molki B, Aframehr WM, Bagheri R, Salimi J, J. Membr. Sci. , 549 , 588, 2018
Gavgani JN, Adelnia H, Gudarzi MM, J. Mater. Sci. , 49 , 243, 2007
Joshi M, Adak B, Butola BS, Prog. Mater. Sci. , 97 , 230, 2007
Amedi HR, Aghajani M, J. Nat. Gas Sci. Eng. , 35 , 695, 2007
Aghili F, Ghoreyshi AA, Rahimpour A, Rahimnejad M, Process Saf. Environ. Protect. , 107 , 528, 2007
Azizi N, Mohammadi T, Behbahani RM, J. Nat. Gas Sci. Eng. , 37 , 39, 2007
Shi S, Shen D, Zhang TXY, Compos. Sci. Technol. , 164 , 17, 2007
Afarani HT, Sadeghi M, Moheb A, Esfahani EN, Chin. J. Chem. Eng. , 27 (1), 110, 2019
Gheimasi KM, Bakhtiari O, Ahmadi M, Chem. Eng. Res. Des. , 133 , 222, 2007
Karimi MB, Hassanajili S, J. Membr. Sci. , 543 , 4048, 2007
Sadeghi M, Talakesh MM, Ghalei B, Shafiei M, J. Membr. Sci. , 427 , 21, 2013
Beganskiene A, Sirutkaitis V, Kurtinaitiene M, Juskenas R, Kareiva A, Mater. Sci. , 10 , 287, 2007
Yılgor E, Yılgor I, Yurtsever E, Polymer , 43 , 6551, 2007
Bistricic L, Baranovic G, Leskovac M, Bajsic EG, Eur. Polym. J. , 46 , 1975, 2007
Ameri E, Sadeghi M, Zarei N, Pournaghshband A, J. Membr. Sci. , 479 , 11, 2007
Hassanajili S, Masoudi E, Karimi G, Khademi M, Sep. Purif. Technol. , 116 , 1, 2007
Hassanajili S, Khademi M, Keshavarz P, J. Membr. Sci. , 453 , 369, 2007
Dorosti F, Omidkhah MR, Abedini R, Chem. Eng. Res. Des. , 92 , 2439, 2007
Jamshidi M, Pirouzfar V, Abedini R, Pedram MZ, Korean J. Chem. Eng. , 34 , 829, 2007
Orme CJ, Harrup MK, Luther TA, Lash RP, Houston KS, Weinkauf DH, Stewart FF, J. Membr. Sci. , 186 , 249, 2007
Gharibi R, Ghadimi A, Yeganeh H, Sadatnia B, Gharedaghi M, J. Membr. Sci. , 548 , 572, 2018
Zhang CL, Li P, Cao B, J. Membr. Sci. , 530 , 176, 2017
Talakesh MM, Sadeghi M, Chenar MP, Khosravi A, J. Membr. Sci. , 415-416 , 469, 2012
Lee JH, Park CH, Jung JP, Kim JH, Kim JH, Chem. Eng. J. , 334 , 939, 2018
Zhou TT, Luo L, Hua S, Wang SF, Zhang RN, Wu H, Jiang ZY, Wang BY, Yang J, J. Membr. Sci. , 489 , 1, 2015
Rabiee H, Alsadat SM, Soltanieh M, Mousavi SA, Ghadimi A, J. Ind. Eng. Chem. , 27 , 223, 2015
Aghaei Z, Naji L, Asl VH, Khanbabaei G, Dezhagah F, Sep. Purif. Technol. , 199 , 47, 2018
Sadeghi M, Semsarzadeh MA, Barikani M, Ghalei B, J. Membr. Sci. , 354 (1-2), 40, 2010
Mondal S, Hu JL, J. Membr. Sci. , 274 (1-2), 219, 2006
Beiragh HH, Omidkhah MR, Abedini R, Khosravi T, Pakseresht S, Asia-Pacific J. Chem. Eng. , 11 , 522, 2016
Nezhadmoghadam E, Chenar MP, Omidkhah M, Nezhadmoghadam A, Abedini R, Korean J. Chem. Eng. , 35 (2), 526, 2018
Ahn JY, Chung WJ, Pinnau I, Guiver MD, J. Membr. Sci. , 314 (1-2), 123, 2008
Tirouni I, Sadeghi M, Pakizeh M, Sep. Purif. Technol. , 141 , 394, 2015
Sadeghi M, Afarani HT, Tarashi Z, Korean J. Chem. Eng. , 32 (1), 97, 2015
Abdellah L, Boutevin B, Guida-Pietrasanta F, Smaihi M, J. Membr. Sci. , 217 (1-2), 295, 2003
Zhou H, Chen Y, Fan HJ, Shi HH, Luo ZY, Shi B, J. Membr. Sci. , 318 (1-2), 71, 2008
Saedi S, Madaeni SS, Hassanzadeh K, Shamsabadi AA, Laki S, J. Ind. Eng. Chem. , 20 (4), 1916, 2014
Aschenbrenner O, Styring P, Energy Environ. Sci. , 3 , 1106, 2010
Shamiri A, Shafeeyan MS, Tee HC, Leo CY, Aroua MK, Aghamohammadi N, J. Nat. Gas Sci. Eng. , 35 , 605, 2016
Maxwell C, Treatise on Electricity and Magnetism, Oxford Univ. Press, London (1873).
Moghadam F, Omidkhah MR, Vasheghani-Farahani E, Pedram MZ, Dorosti F, Sep. Purif. Technol. , 77 (1), 128, 2011
Abedini R, Omidkhah M, Dorosti F, Int. J. Hydrog. Energy , 39 (15), 7897, 2014
Cong HL, Radosz M, Towler BF, Shen YQ, Sep. Purif. Technol. , 55 (3), 281, 2007
Aroon MA, Ismail AF, Matsuura T, Montazer-Rahmati MM, Sep. Purif. Technol. , 75 (3), 229, 2010
Hashemifard SA, Ismail AF, Matsuura T, Chem. Eng. J. , 170 (1), 316, 2011
Bos A, Punt IGM, Wessling M, Strathmann H, J. Membr. Sci. , 155 (1), 67, 1999
Semsarzadeh MA, Sadeghi M, Barikani M, Moadel H, Iran. Polym. J. , 16 , 819, 2007
Li H, Freeman BD, Ekiner OM, J. Membr. Sci. , 369 (1-2), 49, 2011
Stern SA, Fang SM, J. Polym. Sci. , 10 , 201, 1972
Sadrzadeh M, Shahidi K, Mohammadi T, J. Membr. Sci. , 342 (1-2), 327, 2009
Robeson LM, J. Membr. Sci. , 62 , 165, 1991
Rafiq S, Man Z, Maitra S, Maulud A, Ahmad F, Muhammad N, Korean J. Chem. Eng. , 28 (10), 2050, 2011
Semsarzadeh MA, Ghalei B, Fardi M, Esmaeeli M, Vakili E, Korean J. Chem. Eng. , 31 (5), 841, 2014
Cong HL, Hu XD, Radosz M, Shen YQ, Ind. Eng. Chem. Res. , 46 (8), 2567, 2007
Isfahani AP, Ghalei B, Bagheri R, Kinoshita Y, Kitagawa H, J. Membr. Sci. , 513 , 58, 2007
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