Korean Journal of Chemical Engineering, Vol.35, No.12, 2365-2378, 2018
Effect of vanadium surface density and structure in VOx/TiO2 on selective catalytic reduction by NH3
We investigated the correlation between vanadium surface density and VOx structure species in the selective catalytic reduction of NOx by NH3. The properties of the VOx/TiO2 catalysts were investigated using physicochemical measurements, including BET, XRD, Raman spectroscopy, FE-TEM, UV-visible DRS, NH3-TPD, H2-TPR, O2-On/ Off. Catalysts were prepared using the wet impregnation method by supporting 1.0-3.0 wt% vanadium on TiO2 thermally treated at various calcination temperatures. Through the above analysis, we found that VOx surface density was 3.4 VOx/nm2, and the optimal V loading amounts were 2.0-2.5 wt% and the specific surface area was 65-80m2/g. In addition, it was confirmed that the optimal VOx surface density and formation of vanadium structure species correlated with the reaction activity depending on the V loading amounts and the specific surface area size.
[References]
Qi GS, Yang RT, J. Catal. , 217 (2), 434, 2003
Granger P, Parvulescu VI, Chem. Rev. , 111 (5), 3155, 2011
Liu Z, Woo SI, Catal. Rev. Sci. Eng. , 48 , 43, 2006
Cavani F, Cortelli C, Frattini A, Panzacchi B, Ravaglia V, Trifiro F, Fumagalli C, Leanza R, Mazzoni G, Catal. Today , 118 (3-4), 298, 2006
Nielsen UG, Topsoe NY, Brorson M, Skibsted J, Jakobsen HJ, J. Am. Chem. Soc. , 126 (15), 4926, 2004
Bellifa A, Lahcene D, Tchenar Y, Choukchou-Braham A, Bachir R, Bedrane S, Kappensteine C, Appl. Catal. A: Gen. , 305 (1), 1, 2006
Liu Z, Zhang S, Li J, Zhu J, Ma L, Appl. Catal. B: Environ. , 158-159 , 11, 2014
Giraud F, Geantet C, Guihaume N, Loridant S, Gros S, Porcheron L, Kanniche M, Bianchi D, J. Phys. Chem. C , 119 , 15401, 2015
Georgiadou I, Papadopoulou C, Matralis HK, Voyiatzis GA, Lycourghiotis A, Kordulis C, J. Phys. Chem. B , 102 (43), 8459, 1998
Balikdjian JP, Davidson A, Launay S, Eckert H, Che M, J. Phys. Chem. B , 104 (38), 8931, 2000
Srinivas D, Holderich WF, Kujath S, Valkenberg MH, Raja T, Saikia L, Hinze R, Ramaswamy V, J. Catal. , 259 (2), 165, 2008
Giakoumelou L, Fountzoula C, Kordulis C, Boghosian S, J. Catal. , 239 (1), 1, 2006
Tang F, Zhuang K, Yang F, Yang L, Xu B, Qiu J, Fan Y, Chin. J. Catal. , 33 , 933, 2012
Wu Z, Schwartz V, Li M, Rondinone AJ, Overbury SH, J. Phys. Chem. Lett. , 3 , 1517, 2012
Lietti L, Nova I, Forzatti P, Top. Catal. , 11-12 , 111, 2000
Peng Y, Wang CZ, Li JH, Appl. Catal. B: Environ. , 144 , 538, 2014
Banares MA, Alemany LJ, Jimenez MC, Larrubia MA, Delgado F, Granados ML, Martinez-Arias A, Blasco JM, J. Solid State Chem. , 124 , 69, 1996
Wachs IE, Catal. Today , 27 (3-4), 437, 1996
Engweiler J, Harf J, Baiker A, J. Catal. , 159 (2), 259, 1996
Kobayashi M, Miyoshi K, Appl. Catal. B: Environ. , 72 (3-4), 253, 2007
Panagiotou GD, Petsi T, Bourikas K, Kordulis C, Lycourghiotis A, J. Catal. , 262 (2), 266, 2009
Shannon RD, Pask JA, J. Amer. Cer. Soc. , 48 , 391, 2006
Bulushev DA, Kiwi-Minsker L, Rainone F, Renken A, J. Catal. , 205 (1), 115, 2002
Busca G, J. Raman Spectrosc. , 33 , 348, 2002
Banares MA, Wachs IE, J. Raman Spectrosc. , 33 , 359, 2002
Went GT, Oyama ST, Bell AT, J. Phys. Chem. , 94 , 4240, 1990
Christodoulakis A, Machli M, Lemonidou AA, Boghosian S, J. Catal. , 222 (2), 293, 2004
Engweiler J, Harf J, Baiker A, J. Catal. , 159 (2), 259, 1996
Kobayashi M, Miyoshi K, Appl. Catal. B: Environ. , 72 (3-4), 253, 2007
Panagiotou GD, Petsi T, Bourikas K, Kordulis C, Lycourghiotis A, J. Catal. , 262 (2), 266, 2009
Bulanek R, Capek L, Setnicka M, Cicmanec P, J. Phys. Chem. C , 115 , 12430, 2011
Moussa N, Ghorbel A, Appl. Surf. Sci. , 255 (5), 2270, 2008
Catana G, Rao RR, Weckhuysen BM, Van Der Voort P, Vansant E, Schoonheydt RA, J. Phys. Chem. B , 102 (41), 8005, 1998
Wei D, Wang H, Feng XB, Chueh WT, Ravikovitch P, Lyubovsky M, Li C, Takeguchi T, Haller GL, J. Phys. Chem. B , 103 (12), 2113, 1999
Miller JM, Lakshmi LJ, J. Mol. Catal. A-Chem. , 144 , 451, 1999
Due-Hansen J, Rasmussen SB, Mikolajska E, Banares MA, Avila P, Fehrmann R, Appl. Catal. B: Environ. , 107 (3-4), 340, 2011
Alyea EC, Lakshmi LJ, Ju Z, Langmuir , 13 (21), 5621, 1997
Kwon DW, Park KH, Hong SC, Appl. Catal. A: Gen. , 499 , 1, 2015
Kompio PGWA, Bruckner A, Hipler F, Auer G, Loffler E, Grunert W, J. Catal. , 286 , 237, 2012
Meiqing S, Chenxu L, Jianqiang W, Lili X, Wulin W, Jun W, RSC Adv. , 5 , 35155, 2015
Kumar RR, Rao KN, Rajanna K, Phani AR, Mater. Lett. , 106 , 164, 2013
Salman MM, Kumar PA, Phil HH, Appl. Catal. B: Environ. , 152-153 , 28, 2014
Zhao K, Han WL, Lu GX, Lu JY, Tang ZC, Zhen XP, Appl. Surf. Sci. , 379 , 316, 2016
Pinaeva LG, Suknev AP, Budneva AA, Paukshtis EA, Bal’zhinimaev BS, J. Catal. , 193 , 145, 2000
Lietti L, Ramis G, Berti F, Toledo G, Robba D, Busca G, Forzatti P, Catal. Today , 42 (1-2), 101, 1998
Handy BE, Baiker A, Schraml-Marth M, Wokaun A, J. Catal. , 133 , 1, 1992
Martinez S, Morales R, Galindo MGC, Rodriguez AG, Handy BE, Thermochim. Acta , 434 , 74, 2005
Shi AJ, Wang XQ, Yu T, Shen MQ, Appl. Catal. B: Environ. , 106 (3-4), 359, 2011
Wang CZ, Yang SJ, Chang HZ, Peng Y, Li JH, Chem. Eng. J. , 255 , 520, 2013
Sun CZ, Dong LH, Yu WJ, Liu LC, Li H, Gao F, Dong L, Chen Y, J. Mol. Catal. A-Chem. , 346 (1-2), 29, 2011
Roozeboom F, Mittelmeijer-Hazeleger MC, Moulijn JA, Medema J, De Beer VHJ, Gellings PHJ, J. Phys. Chem. , 84 , 2783, 1980
Putluru SSR, Schill L, Godiksen A, Poreddy R, Mossin S, Jensen AD, Fehrmann R, Appl. Catal. B: Environ. , 183 , 282, 2016
Wang CZ, Yang SJ, Chang HZ, Peng Y, Li JH, Chem. Eng. J. , 225 , 520, 2013
Lietti L, Forzatti P, Bregani F, Ind. Eng. Chem. Res. , 35 (11), 3884, 1996
Amiridis MD, Wachs IE, Deo G, Jehng JM, Kim DS, J. Catal. , 161 (1), 247, 1996
Topsoe NY, Anstrom M, Dumesic JA, Catal. Lett. , 76 (1-2), 11, 2001
Inomata M, Miyamoto A, Murakami Y, J. Catal. , 62 , 140, 1980
Miyamoto A, Yamazaki Y, Inomata M, Kurakami Y, J. Phys. Chem. , 85 , 2366, 1981
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