| Issue |
Korean Journal of Chemical Engineering,
Vol.35, No.10, 2043-2051, 2018
Vol.35, No.10, 2043-2051, 2018
Determination and correlation of the solubility of L-arabinose and D-galactose in binary solvent mixtures from 278.15 to 333.15 K
L-arabinose and D-galactose could be released during the hydrolysis process of Arabic gum. The development of a crystallization process of L-arabinose is highly dependent on the knowledge of the solubility of both saccharides. In this work, the solubility of L-arabinose and D-galactose in binary mixtures of methanol-water or ethanolwater (mole fraction of water ≤ 0.5816) was determined at temperatures between 278.15 and 333.15 K by a static equilibrium method. The experimental data correlated well with the modified Apelblat equation, the simplified polynomial empirical equation, NRTL model and UNIQUAC model. Additionally, the thermodynamic properties including the dissolution enthalpy and entropy were obtained from the experimental data. Within the studied temperature range, the dissolution is endothermic and the dissolution process is non-spontaneous.
[References]
- Ha GS, Kim JH, Korean J. Chem. Eng., 34(9), 2451, 2017
- Wang Z, Wang Q, Liu X, Fang W, Li Y, Xiao H, Korean J. Chem. Eng., 30(4), 931, 2013
- Wongkaew K, Mohdee V, Sotak T, Hronec M, Pancharoen U, Arpornwichanop A, Fluid Phase Equilib., 450, 75, 2017
- Sharma G, Mo CC, Tetrahedron Lett., 44, 8161, 2003
- Jung ME, Xu Y, Org. Lett., 1, 1517, 1999
- Sanai K, Seri K, Inoue S, J. Jpn. Soc. Nutr. Food Sci., 50, 133, 1997
- Li YS, Li XH, Tan CX, Org. Prep. Proced. Int., 45, 332, 2017
- Tsavas P, Polydorou S, Voutsas EC, Magoulas KG, Naraghi K, Halling PJ, J. Chem. Eng. Data, 47(3), 513, 2002
- Lu M, Guo F, Fan B, Ren Z, Li Q, J. Mol. Liq., 246, 332, 2017
- Zhang L, Gong XC, Wang YF, Qu HB, J. Chem. Eng. Data, 57(7), 2018, 2012
- Jiang L, Li S, Jiang J, Qiu J, Wang P, J. Mol. Liq., 211, 406, 2015
- Hu B, Huang K, Zhang X, Zhang P, Yu S, Food Sci. Technol. Brazil, 35, 51, 2015
- Cao Y, Yang Q, Xing H, Bao Z, Su B, Yang Y, Ren Q, Chinese J. Chem. Eng., 22, 1141, 2014
- Liang RS, Bao ZB, Su BG, Xing HB, Ren QL, J. Chem. Eng. Data, 57(8), 2328, 2012
- Chen W, Su BG, Xing HB, Yang YW, Ren QL, Fluid Phase Equilib., 287(1), 1, 2009
- Gong X, Wang S, Qu H, Chinese J. Chem. Eng., 19, 217, 2011
- Lenka M, Sarkar D, Fluid Phase Equilib., 412, 168, 2016
- Yang JS, Qian G, Wu YY, Zhang XY, Liu Y, Li ZW, Zhou XG, Fluid Phase Equilib., 445, 1, 2017
- Huang Z, Yu C, Xue W, Lin F, Zeng Z, Korean J. Chem. Eng., 34(1), 206, 2017
- Apelblat A, Manzurola E, J. Chem. Thermodyn., 31(1), 85, 1999
- Hong MH, Wu SW, Qi MH, Ren GB, Fluid Phase Equilib., 409, 1, 2016
- Lim J, Jang S, Kim H, Cho HK, Shin MS, Korean J. Chem. Eng., 30(1), 181, 2013
- Liu Y, Wang Y, Liu YM, Xu SJ, Chen MY, Du SC, Gong JB, J. Chem. Thermodyn., 105, 1, 2017
- He M, Wang YL, Xiao LP, Lou YJ, Su NN, Li Y, Hao HX, Fluid Phase Equilib., 454, 1, 2017
- Fan JP, Liao DD, Zhen B, Xu XK, Zhang XH, Ind. Eng. Chem. Res., 54(51), 12981, 2015
- Shan YY, Fu MF, Yan WD, J. Chem. Eng. Data, 62(1), 568, 2017
- van Putten RJ, Winkelman JGM, Keihan F, van der Waal JC, de Jong E, Heeres HJ, Ind. Eng. Chem. Res., 53(19), 8285, 2014
- Tang WW, Xie C, Wang Z, Wu SG, Feng Y, Wang XM, Wang JK, Gong JB, Fluid Phase Equilib., 363, 86, 2014
- Yang W, Wu K, Hu Y, Zhang T, Guo Q, Yang S, Shi Y, Korean J. Chem. Eng., 32(6), 1158, 2015
- Zhu P, Chen Y, Fang J, Wang Z, Xie C, Hou B, Chen W, Xu F, J. Chem. Thermodyn., 92, 1982, 2016
- Shakeel F, Haq N, Siddiqui NA, Alanazi FK, Alsarra IA, Food Chem., 188, 57, 2015
- Shu M, Zhu L, Yuan M, Wang L, Wang Y, Yang L, Sha Z, Zeng M, J. Solution Chem., 46, 1995, 2017
참고문헌정보(참고문헌, 인용문헌)는 화학공학소재연구정보센터에 의해 제공되고 있습니다.