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Issue
Korean Journal of Chemical Engineering,
Vol.35, No.5, 1089-1098, 2018
Photoreduction of CO2 into CH4 using Bi2S3-TiO2 double-layered dense films
Kim JY, Do JY, Park NK, Lee SJ, Hong JP, Kang MS
Nano-sized bismuth sulfide (Bi2S3) and titanium dioxide (TiO2) with the orthorhombic and anatase tetragonal structures, respectively, were synthesized for application as catalysts for the reduction of carbon dioxide (CO2) to methane (CH4). Four double-layered dense films were fabricated with different coating sequences.TiO2 (bottom layer)/Bi2S3 (top layer), Bi2S3/TiO2, TiO2/Bi2S3 : TiO2 (1 : 1) mix, and Bi2S3 : TiO2 (1 : 1) mix/Bi2S3 : TiO2 (1 : 1) mix.and applied to the photoreduction of CO2 to CH4; the catalytic activity of the fabricated films was compared to that of the pure TiO2/TiO2 and Bi2S3/Bi2S3 doubled-layered films. The TiO2/Bi2S3 double-layered film exhibited superior photocatalytic behavior, and higher CH4 production was obtained with the TiO2/Bi2S3 double-layered film than with the other films. A model of the mechanism underlying the enhanced photoactivity of the TiO2/Bi2S3 double-layered film was proposed, and it was attributed in effective charge separation.
Keywords: Double Layered Film; Bismuth Sulfide; Coating Sequence; Carbon Dioxide; Photoreduction; Charge Separation
[References]
  1. Pittelkow CM, Adviento-Borbe MA, Hill JE, Six J, van Kessel C, Linquist BA, Agric. Ecosysyst. Environ., 177, 10, 2013
  2. Kang TJ, {Ark HJ, Namkung H, Xu LH, Park JH, Heo IJ, Chang TS, Kim BK, Kim HT, Korean J. Chem. Eng., 34(10), 2597, 2017
  3. Ziemkiewicz P, Stauffer PH, Sullivan-Graham J, Chu SP, Bourcier WL, Buscheck TA, Carr T, Donovan J, Jiao Z, Lin L, Song L, Wagoner JL, Tianjin PR China Int. J. Greenhouse Gas Control., 54, 538, 2016
  4. Choi JH, Kim YE, Nam SC, Yun SH, Yoon YI, Lee JH, Korean J. Chem. Eng., 33(11), 3222, 2016
  5. Lee B, Lim H, Korean J. Chem. Eng., 34(1), 199, 2017
  6. Yu T, Yuan QY, Lu JF, Ding J, Lu YL, Appl. Energy, 185, 1994, 2017
  7. Erb TJ, Zarzycki J, Curr. Opin. Chem. Biol., 34, 72, 2016
  8. Lei XF, Zhang ZN, Wu ZX, Piao YJ, Chen C, Li X, Xue XX, Yang H, Sep. Purif. Technol., 174, 66, 2017
  9. Senboku H, Katayama A, Curr. Opinion Green Sustain. Chem., 3, 50, 2017
  10. Jo SW, Kwak BS, Kim KM, Don JY, Park NK, Ryu SO, Ryu HJ, Baek JI, Kang M, Appl. Surf. Sci., 355, 891, 2015
  11. Li X, Wen J, Low J, Fang Y, Yu J, Sci. China Mater., 57, 70, 2014
  12. Lee H, Kwak BS, Park NK, Baek JI, Ryu HJ, Kang M, Appl. Surf. Sci., 393, 385, 2017
  13. Lee JH, Kim SI, Park SM, Kang M, Ceram. Int., 43, 1768, 2017
  14. Meng X, Yu Q, Liu G, Shi L, Zhao G, Liu H, Li P, Chang K, Kako T, Ye J, Nano Energy, 34, 524, 2017
  15. Reddy CV, Shim J, Cho M, J. Phys. Chem. Solids, 103, 209, 2017
  16. Garcia RGA, Avendano CAM, Pal M, Delgado FP, Mathews NR, Mater. Sci. Semicon. Proc., 44, 91, 2016
  17. Sun Y, Li G, Xu J, Sun Z, Mater. Lett., 174, 238, 2016
  18. Li H, Yang J, Zhang J, Zhou M, Roy. Soc. Chem., 2, 6258, 2012
  19. Kim J, Kang M, Int. J. Photoenergy, 37, 8249, 2012
  20. Wu W, Wu Z, Yu T, Jiang C, Kim WS, Sci. Technol. Adv. Mater., 16, 023501, 2015
  21. Im Y, Kang S, Kim KM, Ju T, Han GB, Park NK, Lee TJ, Kang M, Int. J. Photoenergy, 2013, 452542, 2013
  22. Kumar S, Sharma S, Sood S, Umar A, Kansal SK, Ceram. Int., 42, 17551, 2016
  23. Deshpande MP, Sakariya PN, Bhatt SV, Garg N, Patel K, Chaki SH, Mater. Sci. Semicond. Process, 21, 108, 2014
  24. Chaturvedi A, Joshi MP, Mondal P, Sinha AK, Srivastava AK, Appl. Surf. Sci., 396, 303, 2017
  25. Park M, Kwak BS, Jo SW, Kang M, Energy Conv. Manag., 103, 431, 2015
  26. Wang J, Xia Y, Dong Y, Chen RS, Xiang L, Komarneni S, Appl. Catal. B: Environ., 192, 8, 2016
  27. Panesar DK, Francis J, Constr. Build. Mater., 52, 52, 2014
  28. Khalfaoui M, Knani S, Hachicha MA, Ben Lamine A, J. Colloid Interface Sci., 263(2), 350, 2003
  29. Ndolomingo MJ, Meijboom R, Appl. Surf. Sci., 390, 224, 2016
  30. Tahir M, Amin NS, Appl. Catal. B: Environ., 142-143, 512, 2013
  31. Kubacka A, Munoz-Batista MJ, Ferrer M, Fernandez-Garcia M, Appl. Catal. B: Environ., 140-141, 680, 2013
  32. Jung KD, Bell AT, J. Catal., 193(2), 207, 2000
  33. Yao Y, Goodman DW, J. Mol. Catal. A-Chem., 383-384, 239, 2014
  34. Abou Asi M, Zhu LF, He C, Sharma VK, Shu D, Li SZ, Yang JN, Xiong Y, Catal. Today, 216, 268, 2013
  35. Singhal N, Kumar U, Mol. Catal., 439, 91, 2017
  36. Yu H, Huang J, Zhang H, Zhao Q, Zhong X, Nanotechnology, 25, 215702, 2014
  37. Kato T, Hakari Y, Ikeda S, Jia Q, Iwase A, Kudo A, J. Phys. Chem. Lett., 6, 1042, 2015
  38. He H, Berglund SP, Xiao P, Chemelewski WD, Zhang Y, Mullins CB, J. Mater. Chem. A, 1, 12826, 2013
  39. Farhangi N, Chowdhury RR, Medina-Gonzalez Y, Ray MB, Charpentier PA, Appl. Catal. B: Environ., 110, 25, 2011
  40. Lee JH, Lee H, Kang M, Mater. Lett., 178, 316, 2016
  41. Kalanur SS, Hwang YJ, Joo OS, J. Colloid Interface Sci., 402, 94, 2013
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