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Issue
Korean Journal of Chemical Engineering,
Vol.35, No.4, 853-858, 2018
Biosynthesized Au/TiO2@SBA-15 catalysts for selective oxidation of cyclohexane with O2
Yao F, Xu L, Luo J, Li X, An Y, Wan C
A variety of TiO2@SBA-15 supporters with various TiO2 loadings were synthesized using a facile sol-gel method. Gold (Au)-based catalysts were prepared with an environmentally benign and economical bioreduction method via Cacumen Platycladi (CP) leaf extract and immobilized on various TiO2@SBA-15 supporters with different TiO2 loadings. The as-prepared biosynthesized Au catalysts were applied in the liquid-phase cyclohexane oxidation. The results showed that the Au nanoparticles were well-dispersed on TiO2@SBA-15, and the Au existed as Au0. These biosynthesized Au catalysts are promising for cyclohexane oxidation, achieving a turnover frequency up to 3,426 h.1 with a 14.1% cyclohexane conversion rate.
Keywords: Cyclohexane Oxidation; Biosynthesis; Nanocomposites; Au/TiO2@SBA-15; Oxygen
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[Cited By]
  1. Yuan E, Gu M, Jian P, Korean Journal of Chemical Engineering, 37(7), 1137, 2020
  2. Yuan E, Gu M, Jian P, Korean Journal of Chemical Engineering, 37(7), 1137, 2020
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