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Issue
Korean Journal of Chemical Engineering,
Vol.34, No.8, 2225-2235, 2017
Response surface approach for optimization of Hg(II) adsorption by 3-mercaptopropyl trimethoxysilane-modified kaolin minerals from aqueous solution
Yılmaz S, Sahan T, Karabakan A
The optimization of Hg(II) adsorption conditions from aqueous solutions with 3-mercaptopropyl trimethoxysilane- modified kaolin (MMK) used as a new adsorbent was analyzed by response surface methodology (RSM) approach. The MMK adsorbent was characterized by means of energy-dispersive X-ray spectroscopy (EDX), Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD). According to the quadratic model obtained from central composite design (CCD) in RSM, the optimal conditions for adsorption were found to be 30.83mg/L, 0.1 g, 7.44 and 31.41 °C for Co, adsorbent dosage, initial pH, and T (°C), respectively. With the obtained model, the maximum amount of adsorbed Hg(II) and %Hg(II) removed was calculated to be 30.10mg/g and 98.01%, respectively. Langmuir and Dubinin-Radushkevich isotherms fitted well the experimental results. Thermodynamic studies revealed that the adsorption was physical, exothermic, spontaneous. The results indicate that MMK a new adsorbent has great potential for the removal of Hg(II) from aqueous media.
Keywords: Adsorption; Central Composite Design; Kaolin; Mercapto; Mercury; Response Surface Methodology
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[Cited By]
  1. Saman N, Kong H, Mohtar SS, Johari K, Mansor AF, Hassan O, Ali N, Mat H, Korean Journal of Chemical Engineering, 36(7), 1069, 2019
  2. Duan L, Hu X, Sun D, Liu Y, Guo Q, Zhang T, Zhang B, Korean Journal of Chemical Engineering, 37(7), 1166, 2020
  3. Ying TY, Raman AAA, Bello MM, Buthiyappan A, Korean Journal of Chemical Engineering, 37(12), 2179, 2020
  4. Lalhmunsiama, Malsawmdawngzela R, Vanlalhmingmawia C, Tiwari D, Yoon YY, Applied Chemistry for Engineering, 33(5), 502, 2022
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