Issue
Korean Journal of Chemical Engineering,
Vol.34, No.5, 1377-1384, 2017
Removal of chlorinated phenol from aqueous solution utilizing activated carbon derived from papaya (Carica Papaya) seeds
Activated carbons (ACs) were prepared from papaya seeds with different dry weight impregnation ratios of zinc chloride (ZnCl2) to papaya seeds by using a two-stage self-generated atmosphere method. The papaya seeds were first semi-carbonized in a muffle furnace at 300 °C for 1 h and then impregnated with ZnCl2 before activation at 500 °C for 2 h. Several physical and chemical characteristics such as moisture, ash, pH, functional groups, morphological structure and porosity of prepared ACs were studied and presented here. AC2, with the impregnation ration of 1 : 2 (papaya seeds: ZnCl2), yielded a product that had the highest adsorption capacity, 91.75%, achieved after 180min contact time. The maximum Brunauer, Emmett and Teller (BET) surface area of AC2 was 546m2/g. Adsorption studies indicated that AC2 complied well with the Langmuir isotherm (qm=39.683mg g-1) and the pseudo-second-order (qe=29.36mg g-1). This indicated that chemisorption was the primary adsorption method for AC2. The intraparticle diffusion model proved that the mechanism of adsorption was separated into two stages: the instantaneous stage and the gradual adsorption stage. Overall, this work demonstrated the suitability of using papaya seeds as a precursor to manufacture activated carbon.
[References]
  1. Tan IA, Ahmad AL, Hameed BH, J. Hazard. Mater., 153(1), 709, 2008
  2. Shaarani FW, Hameed BH, Desalination, 255(1-3), 159, 2010
  3. Olaniran AO, Igbinosa EO, Chemosphere, 83, 1297, 2011
  4. Nowicki P, Kazmierczak J, Pietrzak R, Powder Technol., 269, 312, 2015
  5. Joseph CG, Bono A, Anisuzzaman SM, Krishnaiah D, J.Appl. Sci., 14, 3182, 2014
  6. Krishnaiah D, Anisuzzaman SM, Bono A, Sarbatly R, J.King Saud University - Sci., 25, 251, 2013
  7. Anisuzzaman SM, Joseph CG, Taufiq-Yap YH, Krishnaiah D, Tay VV, J. King Saud University - Sci., 27, 318, 2015
  8. Anisuzzaman SM, Joseph CG, Daud WMAW, Krishnaiah D, Yee HS, Int. J. Ind. Chem, 6, 9, 2015
  9. Anisuzzaman SM, Joseph CG, Krishnaiah D, Bono A, Ooi LC, Water Sci. Technol., 72, 896, 2015
  10. Gupta VK, Nayak A, Chem. Eng. J., 180, 81, 2012
  11. Mittal A, Kaur D, Malviya A, Mittal J, Gupta VK, J. Colloid Interface Sci., 337(2), 345, 2009
  12. Tan IAW, Ahmad AL, Hameed BH, J. Hazard. Mater., 164(2-3), 473, 2009
  13. Fan JL, Zhang JA, Zhang CL, Ren LA, Shi QQ, Desalination, 267(2-3), 139, 2011
  14. Hesas RH, Roozbeh, Daud WMAW, Sahu JN, Arami- Niya A, J. Anal. Appl. Pyrolysis, 100, 1, 2013
  15. Ahmed MJ, Theydan SK, J. Anal. Appl. Pyrolysis, 100, 253, 2013
  16. Okman I, Karagoz S, Tay T, Erdem M, Appl. Surf. Sci., 293, 138, 2014
  17. Foo KY, Hameed BH, Chem. Eng. J., 170(1), 338, 2011
  18. Ozhan A, Omer S, Kucuk MM, Saka C, Cellulose, 21, 2457, 2014
  19. Boudrahem F, Aissani-Benissad F, Ait-Amar H, J. Environ. Manage., 90, 3031, 2009
  20. Ucar S, Erdem M, Tay T, Karagoz S, Appl. Surf. Sci., 255(21), 8890, 2009
  21. Pereira RG, Veloso CM, da Silva NM, de Sousa LF, Bonomo RCF, de Souza AO, Souza MOD, Fontan RDI, Fuel Process. Technol., 126, 476, 2014
  22. Olivares-Marin M, Fernandez-Gonzalez C, Macias-Garcia A, Gomez-Serrano V, Appl. Surf. Sci., 252(17), 5967, 2006
  23. Alshehri SM, Naushad M, Ahamad T, Alothman ZA, Aldalbahi A, Chem. Eng. J., 254, 181, 2014
  24. Kumar A, Guo C, Sharma G, PathaniaD, Naushad M, Kalia S, Dhiman P, RSC Adv., 6, 13251, 2016
  25. Alqadami AA, Naushad M, Abdalla MA, Ahamad T, ALOthman ZA, Alshehri SM, RSC Adv., 6, 22679, 2016
  26. Al Othman ZA, Naushad M, Environ. Sci. Pollut. Res., 20, 3351, 2013
  27. Naushad M, Al Othman ZA, Desalination Water Treatment, 53, 2158, 2015
  28. Kumar A, Sharma G, Naushad M, Singh P, Kalia S, Ind. Eng. Chem. Res., 53(40), 15549, 2014
  29. Naushad M, AL Othman ZA, Awual MR,Alam MM, Eldesoky GE, Ionics, 21, 2237, 2015
  30. Naushad M, AL Othman ZA, Sharma G, Inamuddin, Ionics, 2, 1453, 2015
  31. Bushra R, Naushad M, Adnan R, ALOthman ZA, Rafatullah M, J. Ind. Eng. Chem., 21, 1112, 2015
  32. Naushad M, ALOthman ZA, Inamuddin, Javadian H, J. Ind. Eng. Chem., 25, 35, 2015
  33. Naushad M, Ahamad T, Sharma G, Al-Muhtaseb AH, Albadarin AB, Alam MM, ALOthman ZA, Alshehri SM, Ghfar AA, Chem. Eng. J., 300, 306, 2016
  34. Gundogdu A, Duran C, Senturk HB, Soylak M, Imamoglu M, Onal Y, J. Anal. Appl. Pyrolysis, 104, 249, 2013
  35. Gundogdu A, Duran C, Senturk HB, Soylak M, Ozdes D, Serencam H, Imamoglu M, J. Chem. Eng. Data, 57(10), 2733, 2012
  36. Duran C, Ozdes D, Gundogdu A, Imamoglu M, Senturk HB, Anal. Chim. Acta, 688, 75, 2011
  37. Srinivasakannan C, Abu Bakar MZ, Biomass Bioenerg., 27(1), 89, 2004
  38. Kennedy LJ, Vijaya JJ, Kayalvizhi K, Sekaran G, Chem. Eng. J., 132(1-3), 279, 2007
  39. Ganan-Gomez J, Macias-Garcia A, Diaz-Diez MA, Gonzalez-Garcia C, Sabio-Rey E, Appl. Surf. Sci., 252(17), 5976, 2006
  40. Wang JP, Chen YZ, Feng HM, Zhang SJ, Yu HQ, J. Colloid Interface Sci., 313(1), 80, 2007
  41. Qian QR, Machida M, Tatsumoto H, Bioresour. Technol., 98(2), 353, 2007
  42. Farzad S, Taghikhani V, Ghotbi C, Aminshahidi B, Lay EN, J. Natural Gas Chem, 16, 22, 2007
  43. Zhou L, Ming L, Sun Y, Zhou Y, Carbon, 39, 773, 2001
  44. Ozdemir I, Sahin M, Orhan R, Erdem M, Fuel Process. Technol., 125, 200, 2014
  45. Acharya J, Sahu JN, Mohanty CR, Meikap BC, Chem. Eng. J., 149(1-3), 249, 2009
  46. Silgado KJ, Marrugo GD, Puello J, Chem. Eng. Transactions, 37, 721, 2014
  47. Yenisoy-Karakas S, Augun A, Gunes M, Tajtasalal E, Carbon, 42, 477, 2004
  48. Weber CT, Foletto EL. Meili L, Water, Air Soil Pollution, 224, 1427, 2013
  49. Unuabonah EI, Adie GU, Onah LO, Adeyemi OG, Chem. Eng. J., 155(3), 567, 2009
  50. Pavan FA, Camacho ES, Lima EC, Dotto GL, Branco VTA, Dias SLP, J. Environ. Chem. Eng, 2, 230, 2014
  51. Cardoso NF, Lima EC, Pinto IS, Amavisca CV,Betina R, Pinto RB, Alencar WS, Pereira SFP, J. Environ. Manage., 92, 1237, 2011
  52. Karim MM, Das AK, Lee SH, Analytica Chimica Acta, 576, 37, 2006
  53. Wang L, Zhang JA, Zhao R, Zhang C, Cong L, Ye L, Desalination, 266(1-3), 175, 2011