Korean Journal of Chemical Engineering, Vol.33, No.10, 2878-2890, 2016
Application of mesoporous magnetic carbon composite for reactive dyes removal: Process optimization using response surface methodology
Discharging the effluents of textile wastewaters into potable water resources can endanger the ecosystem, due to their reactivity, toxicity, and chemical stability. In this research, the application of powder activated carbon modified with magnetite nanoparticles (PAC-MNPs) as an adsorbent for removal of reactive dyes (Reactive black 5 (RB5) and reactive red 120 (RR120)) was studied in a batch system. The adsorption performance was evaluated as a function of temperature, contact time and different adsorbent and adsorbate concentrations. The levels of factors were statistically optimized using Box-Behnken Design (BBD) from the response surface methodology (RSM) to maximize the efficiency of the system. The adsorption process of both dyes was fit with the pseudo-second order kinetic and Langmuir isotherm models. The identified optimum conditions of adsorption were 38.7 ℃, 46.3 min, 0.8 g/L and 102mg/L for temperature, contact time, adsorbent dose, and initial dyes concentration, respectively. According to the Langmuir isotherm, the maximum sorption capacities of 175.4 and 172.4mg/g were obtained for RB5 and RR120, respectively. Thermodynamics studies indicated that the adsorption process of the reactive dyes was spontaneous, feasible, and endothermic. After five cycles, the adsorption efficiency was around 84 and 83% for RB5 and RR120, respectively. A high value of desorption was achieved, suggesting that the PAC-MNPs have a good potential in regeneration and reusability, and also can be effectively utilized in industrial applications. PAC-MNPs also show a good anti-interference potential for removal of reactive dyes in dye-industry wastewaters.
[References]
Babaei AA, Khataee A, Ahmadpour E, Sheydaei M, Kakavandi B, Alaee Z, Korean J. Chem. Eng. , 33 , 1352, 2015
Gupta VK, Jain R, Mittal A, Saleh TA, Nayak A, Agarwal S, Sikarwar S, Mater. Sci. Eng. C-Biomimetic Supramol. Syst. , 32 , 12, 2012
Mittal A, Mittal J, Malviya A, Gupta VK, J. Colloid Interface Sci. , 340 (1), 16, 2009
Kalantry RR, Jafari AJ, Esrafili A, Kakavandi B, Gholizadeh A, Azari A, Desalination Water Treatment. , 57 , 6411, 2016
Mittal A, Mittal J, Malviya A, Kaur D, Gupta VK, J. Colloid Interface Sci. , 342 (2), 518, 2010
Rafatullah M, Sulaiman O, Hashim R, Ahmad A, J. Hazard. Mater. , 177 (1-3), 70, 2010
Yao YY, Wang L, Sun LJ, Zhu S, Huang ZF, Mao YJ, Lu WY, Chen WX, Chem. Eng. Sci. , 101 , 424, 2013
Ahmad MA, Alrozi R, Chem. Eng. J. , 171 (2), 510, 2011
Ghaedi M, Sadeghian B, Pebdani AA, Sahraei R, Daneshfar A, Duran C, Chem. Eng. J. , 187 , 133, 2012
Gupta VK, Jain R, Nayak A, Agarwal S, Shrivastava M, Mater. Sci. Eng. C-Biomimetic Supramol. Syst. , 31 , 1062, 2011
Jaafarzadeh N, Kakavandi B, Takdastan A, Kalantary RR, Azizi M, Jorfi S, RSC Adv. , 5 , 84718, 2015
Azari A, Kakavandi B, Kalantary RR, Ahmadi E, Gholami M, Torkshavand Z, Azizi M, J. Porous Mat. , 22 , 1083, 2015
Esfahani AR, Hojati S, Azimi A, Farzadian M, Khataee A, J. Taiw. Inst. Chem. Eng. , 49 , 172, 2014
Gupta VK, Ali I, Saleh TA, Siddiqui M, Agarwal S, Environ. Sci. Pollut. Res. , 20 , 1261, 2013
Gupta VK, Suhas, J. Environ. Manage. , 90 , 2323, 2009
Saleh TA, Gupta VK, Adv. Colloid Interface Sci. , 211 , 93, 2014
Saleh TA, Gupta VK, Environ. Sci. Pollut. Res. , 19 , 1224, 2012
Babaei AA, Bahrami M, Firouzi AF, Esfahani AR, Alidokht L, Desalination Water Treatment. , 56 , 3380, 2015
Kakavandi B, Jafari AJ, Kalantary RR, Nasseri S, Esrafili A, Gholizadeh A, Azari A, J. Chem. Technol. Biotechnol. , DOI:10.1002/jctb.4925., 2016
Kakavandi B, Takdastan A, Jaafarzadeh N, Azizi M, Mirzaei A, Azari A, J. Photochem. Photobiol. A-Chem. , 314 , 178, 2016
Gupta VK, Srivastava SK, Mohan D, Sharma S, Waste Manage. , 17 , 517, 1998
Gupta VK, Nayak A, Chem. Eng. J. , 180 , 81, 2012
Yang J, Dong Y, Li J, Liu Z, Min F, Li Y, Korean J. Chem. Eng. , 32 (11), 2247, 2015
Kakavandi B, Kalantary RR, Jafari AJ, Nasseri S, Ameri A, Esrafili A, Azari A, CLEAN - Soil, Air, Water , 43 , 1157, 2015
Afshar A, Sadjadi SAS, Mollahosseini A, Eskandarian MR, Korean J. Chem. Eng. , 33 (2), 669, 2016
Gong JL, Wang B, Zeng GM, Yang CP, Niu CG, Niu QY, Zhou WJ, Liang Y, J. Hazard. Mater. , 164 (2-3), 1517, 2009
Gupta VK, Kumar R, Nayak A, Saleh TA, Barakat MA, Adv. Colloid Interface Sci. , 193-194 , 24, 2013
Zhu HY, Jiang R, Xiao L, Li W, J. Hazard. Mater. , 179 (1-3), 251, 2010
Huang J, Wu Z, Chen L, Sun Y, J. Mol. Liq. , 209 , 753, 2015
American Society for Testing and Material (ASTM) (2012).
Tang Y, Liang S, Yu S, Gao N, Zhang J, Guo H, Wang Y, Colloids Surf. A: Physicochem. Eng. Asp. , 406 , 61, 2012
Bayazit SS, Kerkez O, Chem. Eng. Res. Des. , 92 (11), 2725, 2014
Singh KP, Gupta S, Singh AK, Sinha S, J. Hazard. Mater. , 186 (2-3), 1462, 2011
Mohseni-Bandpi A, Kakavandi B, Kalantary RR, Azari A, Keramati A, RSC Adv. , 5 , 73279, 2015
Nethaji S, Sivasamy A, Mandal AB, Bioresour. Technol. , 134 , 94, 2013
Depci T, Chem. Eng. J. , 181 , 467, 2012
Kakavandi B, Jahangiri-rad M, Rafiee M, Efahani AR, Babaei AA, Microporous Mesoporous Mater. , 231 , 192, 2016
Muhamad MH, Abdullah SRS, Mohamad AB, Rahman RA, Kadhum AAH, J. Environ. Manage. , 121 , 179, 2013
Mittal A, Kaur D, Malviya A, Mittal J, Gupta VK, J. Colloid Interface Sci. , 337 (2), 345, 2009
Mittal A, Mittal J, Malviya A, Gupta VK, J. Colloid Interface Sci. , 344 (2), 497, 2010
Konicki W, Pelech I, Mijowska E, Jasinska I, CLEAN-Soil Air Water , 42 , 284, 2014
Esfahani AR, Firouzi AF, Sayyad G, Kiasat A, Alidokht L, Khataee A, Res. Chem. Intermed. , 40 , 431, 2014
Esfahani AR, Hojati S, Azimi A, Alidokht L, Khataee A, Farzadian M, Korean J. Chem. Eng. , 31 (4), 630, 2014
Sulaymon AH, Abood WM, Desalination Water Treatment , 52 , 5485, 2014
Tanyildizi MS, Chem. Eng. J. , 168 (3), 1234, 2011
Gupta VK, Nayak A, Agarwal S, Environ. Eng. Res. , 20 , 1, 2015
Xue YJ, Hou HB, Zhu SJ, Chem. Eng. J. , 147 (2-3), 272, 2009
Elwakeel KZ, Rekaby M, J. Hazard. Mater. , 188 (1-3), 10, 2011
Jain AK, Gupta VK, Bhatnagar A, Suhas, Sep. Sci. Technol. , 38 (2), 463, 2003
Massoudinejad M, Asadi A, Vosoughi M, Gholami M, Kakavandi B, Karami MA, Korean J. Chem. Eng. , 32 (10), 2078, 2015
Tunc O, Tanaci H, Aksu Z, J. Hazard. Mater. , 163 (1), 187, 2009
Absalan G, Asadi M, Kamran S, Sheikhian L, Goltz DM, J. Hazard. Mater. , 192 (2), 476, 2011
Li Z, Cao M, Zhang W, Liu L, Wang J, Ge W, Yuan Y, Yue T, Li R, Yu WW, Food Chem. , 145 , 749, 2014
Celekli A, Ilgun G, Bozkurt H, Chem. Eng. J. , 191 , 228, 2012
Azari A, Kalantary RR, Ghanizadeh G, Kakavandi B, Farzadkia M, Ahmadi E, RSC Adv. , 5 , 87377, 2015
Gupta VK, Agarwal S, Saleh TA, J. Hazard. Mater. , 185 , 17, 2011
Organization WH, Guidelines for drinking-water quality: First addendum to volume 1, Recommendations, World Health Organization (2006).
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Dehghani MH, Zarei A, Mesdaghinia A, Nabizadeh R, Alimohammadi M, Afsharnia M, Korean Journal of Chemical Engineering , 34 (3), 757, 2017
Kim HG, Son HJ, Lee DK, Kim DW, Park HJ, Cho DH, Korean Journal of Chemical Engineering , 34 (7), 2099, 2017
Babaei AA, Kakavandic B, Rafiee M, Kalantarhormizi F, Purkaram I, Ahmadi E, Esmaeili S, Journal of Industrial and Engineering Chemistry , 56 , 163, 2017
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