| Issue |
Korean Journal of Chemical Engineering,
Vol.33, No.9, 2622-2627, 2016
Vol.33, No.9, 2622-2627, 2016
Efficient continuous epoxidation of biodiesel in a microstructured reactor
Efficient continuous epoxidation of biodiesel with peracetic acid generated in situ from hydrogen peroxide and acetic acid was studied in detail in a microstructured reactor. The effects of micromixer type, reaction temperature, catalyst usage, flow rate and residence time were considered. Results show the T-type glass micro-structured reactor (TTGMR) outperforms the interdigital multilamination micromixer. Under the optimized conditions, the final product from TTGMR has an epoxy value of 6.5 and an iodine value of 2.2.
[References]
- Chlebicki J, Matyschok H, Przem. Chem., 84(12), 933, 2005
- Gunstone FD, Padley FB, Lipid Technologies and Applications, Marcel Dekker Inc., New York (1997).
- De Torres M, Jimenez-Oses G, Mayoral JA, Pires E, Bioresour. Technol., 102(3), 2590, 2011
- Rani S, Joy ML, Nair KP, Ind. Crop. Prod., 65, 328, 2015
- Dinda S, Patwardhan AV, Goud VV, Pradhan NC, Bioresour. Technol., 99(9), 3737, 2008
- Campanella A, Fontanini C, Baltanas MA, Chem. Eng. J., 144(3), 466, 2008
- De Torres M, Arends IWCE, Mayoral JA, Pires E, Jimenez-Oses G, Appl. Catal. A: Gen., 425-426, 91, 2012
- Guidotti M, Psaro R, Ravasio N, Sgobba M, Gianotti E, Grinberg S, Catal. Lett., 122(1-2), 53, 2008
- Sepulveda J, Teixeira S, Schuchardt U, Appl. Catal. A: Gen., 318, 213, 2006
- Piazza GJ, Nunez A, Foglia TA, J. Mol. Catal. B-Enzym., 21, 143, 2003
- He W, Fang Z, Ji D, Chen K, Wan Z, Li X, Gan H, Tang S, Zhang K, Guo K, Org. Process Res. Dev., 17, 1137, 2013
- Protasova LN, Bulut M, Ormerod D, Buekenhoudt A, Berton J, Stevens CV, Org. Process Res. Dev., 17, 760, 2013
- Yang JX, Hu DD, Li W, Yi SH, Chem. Eng. J., 267, 93, 2015
- Zeng D, Pan M, Wang L, Tang Y, Appl. Energy, 91, 208, 2011
- Deng QL, Shen RW, Zhao ZM, Yan MM, Zhang LX, Chem. Eng. J., 262, 1168, 2015
- Yao X, Zhang Y, Du L, Liu J, Yao J, Renew. Sust. Energ. Rev., 47, 519, 2015
- Basavaraju KC, Sharma S, Singh AK, Im DJ, Kim DP, ChemSusChem, 7, 1864, 2014
- Lowe H, Hessel V, Lob P, Hubbard S, Org. Process Res. Dev., 10, 1144, 2005
- Nieuwland PJ, Koch K, van Harskamp N, Wehrens R, van Hest JCM, Rutjes FPJT, Chem.- Asian J., 5, 799, 2010
- Vajglova Z, Vesely M, Kristal J, Vychodilova H, Triska J, Jiricny V, Proce. Eng., 42, 1378, 2012
- Li B, Widlicka D, Boucher S, Hayward C, Lucas J, Murray JC, O’Neil BT, Pfisterer D, Samp L, VanAlsten J, Xiang Y, Young J, Org. Process Res. Dev., 16, 2031, 2012
- Rivas DF, Cintas P, Gardeniers HJGE, Chem. Commun., 48, 10935, 2012
- Paquot C, Hautfenne A, Fat and derivatives, 7th Ed., Blackwell Scientific Publications London (1987).
- Song H, Tice JD, Ismagilov RF, Angew. Chem.-Int. Edit., 42, 768, 2003
- Ren B, Jiang Y, Tang KY, Qin SF, Zheng XJ, Chem. Ind. Eng. Pro., 26, 702, 2007
- Panic S, Loebbecke S, Tuercke T, Antes J, Boskovic D, Chem. Eng. J., 101(1-3), 409, 2004
- Gan LH, Goh SH, Ooi KS, J. Am. Oil Chem. Soc., 69, 347, 1992
- Petrovic ZS, Zlatanic A, Lava CC, Sinadinovic-Ficer S, Eur. J. Lipid Sci. Technol., 104, 293, 2002
- Campanella A, Baltanas MA, Chem. Eng. Process., 46(3), 210, 2007
- Goud VV, Patwardhan AV, Pradhan NC, Bioresour. Technol., 97(12), 1365, 2006
- Bringer MR, Gerdts CJ, Song H, Tice JD, Ismagilov RF, Philos. Trans. R. Soc. Lond. Ser. A-Math. Phys. Eng. Sci., 362, 1087, 2004
- Burns JR, Ramshaw C, Lab. Chip, 1, 10, 2001
- Dummann G, Quittmann U, Grschel L, Agar DW, Wrz O, Morgenschweis K, Catal. Today, 70-80, 433, 2003
- Piazza G, Foglia T, Nunez A, J. Am. Oil Chem. Soc., 78, 589, 2001
- Yue J, Rebrov EV, Schouten JC, Lab. Chip, 14, 1632, 2014
- Wiles C, Watts P, Chem. Commun., 47, 6512, 2011
- Kongyai C, Chalermsinsuwan B, Hunsom M, Korean J. Chem. Eng., 30(2), 327, 2013
- Klaas MRG, Warwel S, J. Am. Oil Chem. Soc., 73, 1453, 1996
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