Korean Journal of Chemical Engineering, Vol.33, No.9, 2530-2537, 2016
Desulfurization of liquid fuels by air assisted peracid oxidation system in the presence of Fe-ZSM-5 catalyst
Catalytic oxidative desulfurization of the model oil or synthetic sulfur oil (SSO) and the different real/industrial industrial oil fractions was investigated using air assisted hydrogen peroxide and formic acid oxidation in the presence of Fe-ZSM-5 as catalyst. The reactivity of the different model sulfur compounds increased in the order of thiophene< dibenzothiophene (BT)<4-methyl dibenzothiophene (4-MDBT). The desulfurization yield in case of the model oil was increased in the presence of Fe-ZSM-5 and the sulfur content of the model oil was reduced from 1275 to less than 50 ppm in 60 min at 60 ℃ temperature. The catalyst also performed efficiently in ODS of real industrial oil fractions, i.e., untreated naphtha (UN), light gas oil (LGO), cooker derived combined heavy gas oil (HGO) and Athabasca oil sands derived bitumen (At. Bit.), and sulfur removal of 80, 78, 62 and 60% was attained, respectively. Kinetic investigation revealed that the ODS catalyzed by Fe-ZSM-5 followed the first-order kinetics.
[References]
Halabi MA, Stanislaus A, Qamra A, Chopra S, Stud. Surf. Sci. Catal. , 243, 1996
Ali MF, Al-Malki A, Ahmed S, Fuel Process. Technol. , 90 (4), 536, 2009
Attar A, Corcoran WH, Ind. Eng. Chem. Prod. Res. Dev. , 17 , 102, 1978
Caero LC, Hernandez E, Pedraza F, Murrieta F, Catal. Today , 107-108 , 564, 2005
Campos-Martin JM, Capel-Sanchez MC, Perez-Presas P, Fierro JLG, J. Chem. Technol. Biotechnol. , 85 (7), 879, 2010
Chen LJ, Guo SH, Zhao DS, Chin. J. Chem. Eng. , 14 (6), 835, 2006
Chen LJ, Guo SH, Zhao DS, Chin. J. Chem. Eng. , 15 (4), 520, 2007
Collins FM, Lucy AR, Sharp C, J. Mol. Catal. A-Chem. , 117 , 397, 1997
de Souza WF, Guimaraes LR, Guerreiro MC, Oliveira LCA, Appl. Catal. A: Gen. , 360 (2), 205, 2009
Deshpande A, Bassi A, Prakash A, Energy Fuels , 19 , 28, 2004
Ferraz W, Oliveira LCA, Dallago R, Conceicao LD, Catal. Commun. , 8 , 131, 2007
Zhang G, Yu F, Wang R, Pet. Coal. , 51 , 196, 2009
Guimaraes IR, Oliveira LCA, Queiroz PF, Ramalho TC, Pereira M, Fabris JD, Ardisson JD, Appl. Catal. A: Gen. , 347 (1), 89, 2008
Guo W, Wang CY, Lin P, Lu XP, Appl. Energy , 88 (1), 175, 2011
Hao L, Benxian S, Zhou X, Pet. Sci. Technol. , 23 , 991, 2005
Imtiaz A, Waqas A, Muhammad I, Chin. J. Catal. , 34 , 1839, 2013
Javadli R, de Klerk A, Energy Fuels , 26 , 594, 2011
Javadli R, Klerk A, Appl. Petrochem. Res. , 1 , 3, 2012
Knops-Gerrits PP, Goddard WA, J. Mol. Catal. A-Chem. , 166 (1), 135, 2001
Riad M, Mikhail S, Global J. Researches in Eng. , 10 , 85, 2010
Mondal S, Hangun-Balkir Y, Alexandrova L, Link D, Howard B, Zandhuis P, Cugini A, Horwitz CP, Collins TJ, Catal. Today , 116 (4), 554, 2006
Murata S, Murata K, Kidena K, Nomura M, Energy Fuels , 18 , 116, 2003
Ohman LO, Ganemi B, Bjornbom E, Rahkamaa K, Keiski RL, Paul J, Mater. Chem. Phys. , 73 (2-3), 263, 2002
Otsuki S, Nonaka T, Takashima N, Qian WH, Ishihara A, Imai T, Kabe T, Energy Fuels , 14 (6), 1232, 2000
Paybarah A, Bone RL, Corcoran WH, Ind. Eng. Chem. Process Des. Dev. , 21 , 426, 1982
Riad M, Mikhail S, Catal. Sci. Technol. , 2 , 1437, 2012
Schoonheydt RA, Catal. Rev. , 35 , 129, 1993
Shakirullah M, Ahmad W, Ahmad I, Ishaq M, Fuel Process. Technol. , 91 (11), 1736, 2010
Yamamoto S, Yao S, Kodama S, Mine C, Fujioka Y, The Open Catal. J. , 1 , 11, 2008
Sobati MA, Dehkordi AM, Shahrokhi M, Chem. Eng. Technol. , 33 (9), 1515, 2010
Tam PS, Kittrell JR, Eldridge JW, Ind. Eng. Chem. Res. , 29 , 321, 1990
Tam PS, Kittrell JR, Eldridge JW, Ind. Eng. Chem. Res. , 29 , 324, 1990
Te M, Fairbridge C, Ring Z, Appl. Catal. A: Gen. , 219 (1-2), 267, 2001
Rao TV, Sain B, Kafola S, Sharma YK, Nanoti SM, Garg MO, Energy Fuels , 21 (6), 3420, 2007
Wang DH, Qian EWH, Amano H, Okata K, Ishihara A, Kabe T, Appl. Catal. A: Gen. , 253 (1), 91, 2003
Wang Y, Li G, Wang XS, Jin CZ, Chin. J. Catal. , 7 , 567, 2005
Yu G, Lu S, Chen H, Zhu Z, Carbon , 43 , 2285, 2005
ZANNIKOS F, LOIS E, STOURNAS S, Fuel Process. Technol. , 42 (1), 35, 1995
Zhou XR, Gai HT, Wang J, Zang SS, Yang JZ, Zhang SF, Chin. J. Chem. Eng. , 17 (2), 189, 2009
Zhou XR, Li J, Wang XN, Jin K, Ma W, Fuel Process. Technol. , 90 (2), 317, 2009
이전 논문 다음 논문
Result Search