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Issue
Korean Journal of Chemical Engineering,
Vol.33, No.6, 1942-1947, 2016
Crystal growth of ionic semiclathrate hydrate formed at interface between CO2+N2 gas mixture and tetrabutylammonium bromide aqueous solution
Hayama H, Akiba H, Asami Y, Ohmura R
This study reports a visual observation of the formation and growth of ionic semiclathrate hydrate on the surface of a Tetrabutylammonium bromide (TBAB) aqueous solution and CO2+N2 gas mixture. The composition of CO2+N2 gas mixture was 20 : 80. The experimental temperature range was from 280 K to 290 K, under the pressures of 2.3MPa and 4.7MPa, at wTBAB=0.10 and wTBAB=0.40, where wTBAB denotes the mass fraction of TBAB in the aqueous solution. At wTBAB=0.40, the hydrate crystals were initially observed to grow within the droplet, and followed by lateral growth at the droplet surface; but at wTBAB=0.10, the hydrate crystals grew exclusively in the liquid phase and did not cover the droplet surface. Two types of different crystals with different sizes were clearly observed.
Keywords: Clathrate Hydrate; Crystal Growth; Carbon Capture; Crystal Morphology; Tetrabutylammonium Bromide
[References]
  1. IPCC. Climate Change 2014, Mitigation of climate change, Contribution of Working Group III to the Fifth Assessment Report of the Intergovernmental Panel on Climate Change., Cambridge University Press, Cambridge (2014).
  2. Kang SP, Lee H, Environ. Sci. Technol., 34, 4397, 2000
  3. Mori YH, J. Chem. Ind. Eng., 54, 1, 2003
  4. Aifaa M, Kodama T, Ohmura R, Cryst. Growth Des., 15, 559, 2015
  5. Lee H, Lee JW, Kim DY, Park J, Seo YT, Zeng H, Moudrakovski IL, Ratcliffe CI, Ripmeester JA, Nature, 434, 743, 2005
  6. Shin K, Kim Y, Strobel TA, Prasad PSR, Sugahara T, Lee H, Sloan ED, Sum AK, Koh CA, J. Phys. Chem. A, 113(23), 6415, 2009
  7. Brewer PG, Friederich C, Peltzer ET, Orr FM, Science, 284(5416), 943, 1999
  8. Ohmura R, Mori YH, Environ. Sci. Technol., 32, 1120, 1998
  9. Tohidi B, Yang J, Salehabadi M, Anderson R, Chapoy A, Environ. Sci. Technol., 44, 1509, 2010
  10. Ogawa T, Ito T, Watanabe K, Tahara K, Hiraoka R, Ochiai J, Ohmura R, Mori YH, Appl. Therm. Eng., 26, 2157, 2006
  11. Park Y, Kim DY, Lee JW, Huh DG, Park KP, Lee J, Lee H, Natl. Acad. Sci. U.S.A., 34, 12690, 2006
  12. Seo YT, Moudrakovski IL, Ripmeester JA, Lee JW, Lee H, Environ. Sci. Technol., 39, 2315, 2005
  13. Bird RB, Stewart WE, Lightfoot EN, Transport Phenomena, 2nd Ed., Wiley, Hoboken, NJ, 196 (2006).
  14. Darbouret M, Cournil M, Herri JM, Int. J. Refrig., 28, 663, 2005
  15. Zhong DL, Englezos P, Energy Fuels, 26(4), 2098, 2012
  16. Zhong DL, Ye Y, Yang C, J. Chem. Eng. Data, 56(6), 2899, 2011
  17. Babu P, Chin WI, Kumar R, Linga P, Ind. Eng. Chem. Res., 53(12), 4878, 2014
  18. Li S, Fan S, Wang J, Lang X, Liang D, J. Nat. Gas Chem., 18, 15, 2009
  19. Belandria V, Mohammadi AH, Richon D, Chem. Eng. Sci., 84, 40, 2012
  20. Lee Y, Lee S, Lee J, Seo Y, Chem. Eng. J., 246, 20, 2014
  21. Deschamps J, Dalmazzone D, J. Therm. Anal. Calorim., 98, 113, 2009
  22. Oyama H, Shimada W, Ebinuma T, Kamata Y, Takeya S, Uchida T, Nagao J, Narita H, Fluid Phase Equilib., 234(1-2), 131, 2005
  23. Veluswamy HP, Yang T, Linga P, Cryst. Growth Des., 14, 1950, 2014
  24. Koyanagi S, Ohmura R, Cryst. Growth Des., 13, 2087, 2013
  25. Akiba H, Ueno H, Ohmura R, Cryst. Growth Des., 15, 3963, 2015
  26. Chapoy A, Anderson R, Tohidi B, J. Am. Chem. Soc., 129(4), 746, 2007
  27. Arjmandi M, Chapoy A, Tohidi B, J. Chem. Eng. Data, 52(6), 2153, 2007
  28. Meysel P, Oellrich L, Bishnoi PR, Clarke MA, J. Chem. Thermodyn., 43(10), 1475, 2011
  29. Kim S, Seo Y, Appl. Energy, 154, 987, 2015
  30. Muromachi S, Udachin KA, Shin K, Alavi S, Moudrakovski IL, Ohmura R, Ripmeester JA, Chem. Commun., 50, 11476, 2014
  31. Sato K, Tokutomi H, Ohmura R, Fluid Phase Equilib., 337, 115, 2013
  32. Tanaka R, Sakemoto R, Ohmura R, Cryst. Growth Des., 9, 2529, 2009
  33. Saito K, Kishimoto M, Tanaka R, Ohmura R, Cryst. Growth Des., 11, 295, 2011
  34. Georgiadis A, Maitland G, Trusler JPM, Bismarck A, J. Chem. Eng. Data, 55(10), 4168, 2010
  35. Akiba H, Ohmura R, J. Chem. Thermodyn., 92, 72, 2015
  36. Yan W, Zhao GY, Chen GJ, Guo TM, J. Chem. Eng. Data, 46, 1544, 2001
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