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Issue
Korean Journal of Chemical Engineering,
Vol.33, No.5, 1514-1529, 2016
Metal hollow sphere electrocatalysts
Chattopadhyay J, Pathak TS, Pak D, Srivastava R
Metal micro-/nano hollow spheres have been widely applied in numerous fields during the last decade. This review will only focus on the synthetic strategies to synthesize hollow spherical structures in the enhancement of their electrocatalytic activity, especially the metal hollow spherical materials. We present a comprehensive overview of synthetic strategies for metal hollow spherical structures which have been approached specifically in electrochemical reactions. These synthetic methods are mainly categorized as hard templates, soft templates, sacrificial templates and without templates. The review further includes electrocatalytic approaches of hollow spherical metals in different electrochemical processes, especially the methanol electro-oxidation reaction for methanol fuel cell application and hydrogen and oxygen evolution reactions in water electrolyzer, as metal hollow spherical materials are especially applied in these specific reactions.
Keywords: Metal Hollow Sphere; Synthesis; Electrocatalysts; Methanol Electro-oxidation; Water Electrolyzer
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