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Issue
Korean Journal of Chemical Engineering,
Vol.33, No.3, 823-830, 2016
Influence of phosphorous addition on Bi3Mo2Fe1 oxide catalysts for the oxidative dehydrogenation of 1-butene
Park JH, Shin CH
Bi3Mo2Fe1Px oxide catalysts were prepared by a co-precipitation method and the influence of phosphorous content on the catalytic performance in the oxidative dehydrogenation of 1-butene was investigated. The addition of phosphorous up to 0.4mole ratio to Bi3Mo2Fe1 oxide catalyst led to an increase in the catalytic performance; however, a higher phosphorous content (above P=0.4) led to a decrease of conversion. Of the tested catalysts, Bi3Mo2Fe1P0.4 oxide catalyst exhibited the highest catalytic performance. Characterization results showed that the catalytic performance was related to the quantity of a π-allylic intermediate, facile desorption behavior of adsorbed intermediates and ability for re-oxidation of catalysts.
Keywords: Butadiene; Oxidative Dehydrogenation; Bi3Mo2Fe1Px Oxide Catalyst; 1-C4H8-temperature-programmed Desorption; Temperature-programmed Re-oxidation
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[Cited By]
  1. Mendoza JA, Hwang SW, Korean Journal of Chemical Engineering, 35(11), 2157, 2018
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