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Issue
Korean Journal of Chemical Engineering,
Vol.32, No.12, 2492-2500, 2015
Surface modification of poly(vinylidene fluoride) membrane with hydrophilic and anti-fouling performance via a two-step polymerization
Chen GE, Sun L, Xu ZL, Yang H, Hunag HH, Liu YJ
The surface modification of poly (vinylidene fluoride) (PVDF) membrane was performed via a two-step polymerization reactions. Poly (acrylic acid) (PAAc) was first grafted onto the membrane surface for the preparation of PVDF-g-PAAc membrane, and then poly (ethylene glycol) 200 (PEG 200) was immobilized on the membrane surface by the esterification reaction for the fabrication of PVDF-g-PEGA membrane. Attenuated total reflectance (ATR) FTIR, X-ray photoelectron spectroscopy (XPS), scanning electron microscope (SEM), and protein adsorption, water flux, water content and dynamic contact angle were conducted to characterize the structures and performance of the resultant PVDF membranes. The experimental results showed that the adsorption of bovine serum albumin (BSA) on the PVDF-g-PEGA membrane decreased about 80% when the grafting ratio reached to 15 wt%, compared with the pristine PVDF membrane. Moreover, the water contact angle of the membrane dropped to 60.5o, while the membrane pore sizes remained little changed.
Keywords: Poly(Vinylidene Fluoride); Surface Modification; Hydrophilic; Anti-fouling; Polymerization
[References]
  1. Liu F, Hashim NA, Liu YT, Abed MRM, Li K, J. Membr. Sci., 375(1-2), 1, 2011
  2. Liu J, Lu X, Li J, Wu C, J. Polym. Res., 21, 568, 2014
  3. Kang GD, Cao YM, J. Membr. Sci., 463, 145, 2014
  4. Sun D, Yang P, Li L, Yang HH, Li BB, Korean J. Chem. Eng., 31(10), 1877, 2014
  5. Park HH, Lim CW, Jo HD, Choi WK, Lee HK, Korean J. Chem. Eng., 24(4), 693, 2007
  6. Kim KM, Hepowit LR, Kim JC, Lee YG, Ko JM, Korean J. Chem. Eng., 32(4), 717, 2015
  7. Liu F, Abed MRM, Li K, Chem. Eng. Sci., 66(1), 27, 2011
  8. Chang Y, Ko CY, Shih YJ, Quemener D, Deratani A, Wei TC, Wang DM, Lai JY, J. Membr. Sci., 345(1-2), 160, 2009
  9. Kemell M, Farm E, Ritala M, Leskela M, Eur. Polym. J., 44, 3564, 2008
  10. Venault A, Liu YH, Wu JR, Yang HS, Chang Y, Lai JY, Aimar P, J. Membr. Sci., 450, 340, 2014
  11. Rana D, Matsuura T, Chem. Rev., 110(4), 2448, 2010
  12. Pezeshk N, Narbaitz RM, Desalination, 287, 247, 2012
  13. Liu F, Xu YY, Zhu BK, Zhang F, Zhu LP, J. Membr. Sci., 345(1-2), 331, 2009
  14. Hashim NA, Liu F, Li K, J. Membr. Sci., 345(1-2), 134, 2009
  15. Ochoa NA, Masuelli M, Marchese J, J. Membr. Sci., 226(1-2), 203, 2003
  16. Hester JF, Mayes AM, J. Membr. Sci., 202(1-2), 119, 2002
  17. Boributh S, Chanachai A, Jiraratananon R, J. Membr. Sci., 342(1-2), 97, 2009
  18. Li MZ, Li JH, Shao XS, Miao J, Wang JB, Zhang QQ, Xu XP, J. Membr. Sci., 405-406, 141, 2012
  19. Chang Y, Chang WJ, Shih YJ, Wei TC, Hsiue GH, ACS Appl. Mater. Interfaces, 3, 1228, 2011
  20. Chang Y, Shih YJ, Ruaan RC, Higuchi A, Chen WY, Lai JY, J. Membr. Sci., 309(1-2), 165, 2008
  21. Zhang MG, Nguyen QT, Ping ZH, J. Membr. Sci., 327(1-2), 78, 2009
  22. Brewis D, Mathieson I, Sutherland I, Cayless R, Dahm R, Int. J. Adhes. Adhes., 16, 87, 1996
  23. Ross GJ, Watts JF, Hill MP, Morrissey P, Polymer, 41(5), 1685, 2000
  24. Byun YJ, Kim JH, Kim SS, Desalin. Water. Treat., 51, 5371, 2013
  25. Rahimpour A, Madaeni SS, Zereshki S, Mansourpanah Y, Appl. Surf. Sci., 255(16), 7455, 2009
  26. Ying L, Wang P, Kang ET, Neoh KG, Macromolecules, 35(3), 673, 2002
  27. Wang P, Tan KL, Kang ET, Neoh KG, J. Membr. Sci., 195(1), 103, 2002
  28. Peng B, Li YY, Zhao ZG, Chen YM, Han CC, J. Appl. Polym. Sci., 130(5), 3112, 2013
  29. Kang GD, Liu M, Lin B, Cao YM, Yuan Q, Polymer, 48(5), 1165, 2007
  30. Liu QF, Lee CH, Kim H, Sep. Sci. Technol., 48, 1209, 2010
  31. Bottino A, Capannelli G, Comite A, J. Membr. Sci., 273(1-2), 20, 2006
  32. Zhang MG, Nguyen QT, Ping ZH, J. Membr. Sci., 327(1-2), 78, 2009
  33. Tamura M, Uragami T, Sugihara M, Polymer, 22, 829, 1981
  34. Zhao YP, Zhao HY, Chen L, Feng X, Zhang QS, Wang JM, Zhang R, J. Polym. Res., 20(1), 1, 2013
  35. Hsu CC, Wu CS, Liu YL, J. Membr. Sci., 450, 257, 2014
  36. Zhao YH, Zhu BK, Kong L, Xu YY, Langmuir, 23(10), 5779, 2007
  37. Zhao XJ, Cheng J, Chen SJ, Zhang J, Wang XL, Colloid Polym. Sci., 288, 1327, 2010
  38. Gu LX, Liu ZF, Hydrophilic fibers (Chinese), China Petrochemical Press, Beijing (1997).
[Cited By]
  1. Yu YA, Kim JJ, Kang H, Lee JC, Korean Chemical Engineering Research, 54(4), 510, 2016
  2. Mei Y, Li H, Xia H, Korean Journal of Chemical Engineering, 33(9), 2668, 2016
  3. Shafaei N, Jahanshahi M, Peyravi M, Najafpour Q, Korean Journal of Chemical Engineering, 33(10), 2968, 2016
  4. Ah CY, Lee BH, Song KC, Korean Chemical Engineering Research, 55(2), 247, 2017
  5. Yang JH, Song KC, Korean Chemical Engineering Research, 55(6), 830, 2017
  6. Goel V, Mandal UK, Korean Journal of Chemical Engineering, 36(4), 573, 2019
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