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Issue
Korean Journal of Chemical Engineering,
Vol.32, No.12, 2456-2462, 2015
Preparation, structure and adsorption properties of synthesized multiwall carbon nanotubes for highly effective removal of maxilon blue dye
Alkaim AF, Sadik Z, Mahdi DK, Alshrefi SM, Al-Sammarraie AM, Alamgir FM, Singh PM, Aljeboree AM
Multiwall carbon nanotubes (MWCNTs) have been hydrothermally prepared using polyethylene glycol as the carbon source. Herein, new MWCNTs composites with high adsorption capacity were prepared and applied as efficient adsorbents for adsorption of maxilon blue dye (GRL) from aqueous solution. The morphologies of the MWCNTs were characterized by X-ray diffraction (XRD), Raman spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM) and Fourier transform-infrared (FT-IR) spectroscopy. The adsorption property of maxilon blue (GRL) from aqueous solution onto MWCNTs was studied as a function of mass dosage, pH of solution, initial dye concentration and temperature. The adsorption of GRL depends on the initial pH of the solution with maximum uptake occurring at about pH 10. The maximum adsorption capacity of prepared MWCNTs was 260.7mg/g. Langmuir, Freundlich and Temkin isotherms were applied to fit the experimental data. The Freundlich equilibrium isotherm fitted well the experimental data indicating the homogeneity of the adsorbent surface sites. Thermodynamics parameters were studied the changes in free energy (ΔG0), enthalpy (ΔH0) and entropy (ΔS0) during adsorption. It is noticeable that the adsorption of GRL dye onto MWCNTs was a spontaneous and endothermic process and indicates that the adsorption is favored at high temperature.
Keywords: Multiwall Carbon Nanotube; Hydrothermal; Adsorption; Maxilon Blue Dye
[References]
  1. Royer B, Cardoso NF, Lima EC, Macedo TR, Airoldi C, J. Hazard. Mater., 181(1-3), 366, 2010
  2. Cardoso NF, Lima EC, Royer B, Bach MV, Dotto GL, Pinto LA, Calvete T, J. Hazard. Mater., 241-242, 146, 2012
  3. Prola LT, Acayanka E, Lima EC, Umpierres CS, Vaghetti JP, Santos WO, Laminsi S, Djifon PT, Ind. Crop. Prod., 46, 328, 2013
  4. Wang YR, Chu W, Ind. Eng. Chem. Res., 50(14), 8734, 2011
  5. Hu J, Shao D, Chen C, Sheng G, Ren X, Wang X, J. Hazard. Mater., 185, 463, 2011
  6. Aljebori AM, Alshirifi AN, Asian J. Chem., 24, 5813, 2012
  7. Shirzad-Siboni M, Khataee A, Vafaei F, Joo SW, Korean J. Chem. Eng., 31(8), 1451, 2014
  8. Lafi R, Fradj A, Hafiane A, Hameed BH, Korean J. Chem. Eng., 31(12), 2198, 2014
  9. Simate GS, Iyuke SE, Ndlovu S, Heydenrych M, Walubita LF, Environ. Int., 39, 38, 2012
  10. Sun WL, Jiang BF, Wang F, Xu N, Chem. Eng. J., 264, 645, 2015
  11. Chatterjee S, Chatterjee T, Lim SR, Woo SH, Bioresour. Technol., 102(6), 4402, 2011
  12. Prola LT, Machado FM, Bergmann CP, de Souza FE, Gally CR, Lima EC, Adebayo MA, Dias SLP, Calvete T, J. Environ. Manage., 130, 166, 2013
  13. Baghapour MA, Pourfadakari S, Mahvi AH, J. Ind. Eng. Chem., 20(5), 2921, 2014
  14. Salam MA, El-Shishtawy RM, Obaid AY, J. Ind. Eng. Chem., 20(5), 3559, 2014
  15. Shirmardi M, Mahvi AH, Hashemzadeh B, Naeimabadi A, Hassani G, Niri MV, Korean J. Chem. Eng., 8, 1603, 2013
  16. Machado FM, Bergmann CP, Fernandes THM, Lima EC, Royer B, Calvete T, Fagan SB, J. Hazard. Mater., 192(3), 1122, 2011
  17. Gong J, Feng JD, Liu J, Jiang ZW, Chen XC, Mijowska E, Wen X, Tang T, Chem. Eng. J., 248, 27, 2014
  18. Cheng J, Chang PR, Zheng PW, Ma XF, Ind. Eng. Chem. Res., 53(4), 1415, 2014
  19. Machado FM, Bergmann CP, Fernandes THM, Lima EC, Royer B, Calvete T, Fagan SB, J. Hazard. Mater., 192(3), 1122, 2011
  20. Wang W, Huang JY, Wang DZ, Ren ZF, Carbon, 43, 1328, 2005
  21. Morsy M, Helal M, Okr ME, Ibrahim M, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 132, 594, 2014
  22. Akbayrak S, Ozkar S, Appl. Mater. Interfaces, 4, 6302, 2012
  23. Sun ZY, Zhang XR, Na N, Liu ZM, Han BX, An GM, J. Phys. Chem. B, 110(27), 13410, 2006
  24. Chen CL, Hu J, Shao DD, Li JX, Wang XK, J. Hazard. Mater., 164(2-3), 923, 2009
  25. Gupta VK, Agarwal S, Saleh TA, J. Hazard. Mater., 185, 17, 2011
  26. Oh WC, Zhang FZ, Chen ML, J. Ind. Eng. Chem., 16(2), 321, 2010
  27. Osswald S, Flahaut E, Ye H, Gogotsi Y, Chem. Phys. Lett., 402(4-6), 422, 2005
  28. Eklund PC, Holden JM, Jishi RA, Carbon, 33, 959, 1995
  29. Saito R, Gruneis A, Samsonidze GG, Brar VW, Dresselhaus G, Dresselhaus MS, Jorio A, Cancado LG, Fantini C, Pimenta MA, Filho AGS, New J. Phys., 5, 157, 2003
  30. Salam MA, Makki MI, Abdelaal MA, J. Alloy. Compd., 509, 2582, 2011
  31. Aljeboree AM, Alkaim AF, Al-Dujaili AH, Desalin. Water Treat., 53, 3656, 2015
  32. Lin Y, Leu J, Biochem. Eng. J., 39, 457, 2008
  33. Li YH, Du QJ, Liu TH, Peng XJ, Wang JJ, Sun JK, Wang YH, Wu SL, Wang ZH, Xia YZ, Xia LH, Chem. Eng. Res. Des., 91(2), 361, 2013
  34. Peydayesh M, Rahbar-Kelishami A, J. Ind. Eng. Chem., 21, 1014, 2015
  35. Aksu Z, Kabasakal E, Sep. Purif. Technol., 35(3), 223, 2004
  36. Kara M, Yuzer H, Sabah E, Celik MS, Water Res., 37, 224, 2003
  37. Ai LH, Li M, Li L, J. Chem. Eng. Data, 56(8), 3475, 2011
  38. Rocher V, Siaugue J, Cabuil V, Bee A, Water Res., 42, 1290, 2008
  39. Musyoka SM, Mittal H, Mishra SB, Ngila JC, Int. J. Biol. Macromol., 65, 389, 2014
  40. Langmuir I, J. Am. Chem. Soc., 40, 1361, 1918
  41. Njoku VO, Foo KY, Asif M, Hameed BH, Chem. Eng. J., 250, 198, 2014
  42. Temkin MJ, Pyzhev V, Acta Physiochem. USSR, 12, 217, 1940
[Cited By]
  1. Cui C, Sun M, Zheng Q, Korean Journal of Chemical Engineering, 33(5), 1640, 2016
  2. Liu G, Hu Z, Guan R, Zhao Y, Zhang H, Zhang B, Korean Journal of Chemical Engineering, 33(11), 3141, 2016
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