Korean Journal of Chemical Engineering, Vol.32, No.11, 2347-2354, 2015
Cassava starch graft copolymer as an eco-friendly corrosion inhibitor for steel in H2SO4 solution
Cassava starch graft copolymer (CSGC) was prepared by grafting acryl amide (AA) onto cassava starch (CS). The inhibition effect of CSGC on the corrosion of cold rolled steel (CRS) in 1.0M H2SO4 solution was first studied by weight loss, potentiodynamic polarization curves, electrochemical impedance spectroscopy (EIS) and scanning electron microscope (SEM) methods. The results show that CSGC is a good inhibitor, and inhibition efficiency of CSGC is higher than that of CS or AA. The adsorption of CSGC on steel surface obeys Langmuir adsorption isotherm. CSGC is a mixed-type inhibitor at 20 oC, while mainly a cathodic inhibitor at 50 oC.
[References]
Trabanelli G, Corrosion , 47 , 410, 1991
Li XM, Liu YN, Liu JS, Fu CY, Total Corros. Control. , 23 (2), 23, 2012
Jianguo Y, Lin W, Otieno-Alego V, Schweinsberg DP, Corrosion Sci. , 37 , 975, 1995
Ashassi-Sorkhabi H, Ghalebsaz-Jeddi N, Hashemadeh F, Jahani H, Electrochim. Acta , 51 (18), 3848, 2006
Li XH, Deng SD, Fu H, Mu GN, J. Appl. Electrochem. , 39 (7), 1125, 2009
Zhang X, Gao BJ, Shen YL, Chin. J. Appl. Chem. , 25 , 212, 2008
Ali SA, Saeed MT, Polymer , 42 (7), 2785, 2001
Shukla SK, Quraishi MA, J. Appl. Polym. Sci. , 124 (6), 5130, 2012
Manivel P, Sathiyanarayanan S, Venkatachari G, J. Appl. Polym. Sci. , 110 (5), 2807, 2008
He HQ, Hou YJ, He L, Guo J, Yang CH, Li W, Cai YX, Chen JJ, Hao YL, Industry Water Treat. , 32 , 69, 2012
Zhao JG, Mater. Prot. , 41 (5), 23, 2008
Guo Y, Song SZ, J. Chem. Industry Eng. , 51 , 788, 2000
Atta AM, El-Azabawy OE, Ismail HS, Hegazy MA, Corrosion Sci. , 53 , 1680, 2011
Zhou YH, Wang YN, Xie H, Song ZQ, Corros. Sci. Prot. Tech. , 15 , 324, 2003
Qiu XP, Chen JZ, Wang Q, Liu YA, Yunnan Chem. Tech. , 33 (5), 24, 2006
Cheng S, Yin YS, Chen SG, Chang XT, Yan LN, Liu T, J. Chem. Indus. Engin. , 58 , 704, 2007
Zhu L, Wang YF, Xu BX, Corros. Prot. , 22 , 426, 2001
Yi CH, Qiu XQ, Yang DJ, Lou HM, J. Chem. Industry. Eng. , 60 , 959, 2009
Wang XJ, Wang XF, Huang SW, Mater. Prot. , 36 (12), 45, 2003
Fu H, Li XH, Li YX, Liu JX, J. Chin. Soc. Corros. Prot. , 31 , 265, 2011
Li XH, Fu H, Li YX, Zhao N, Chin. J. Spectro. Labor. , 28 , 124, 2011
Li XH, Deng SD, Fu H, Corrosion Sci. , 62 , 163, 2012
Li XH, Deng SD, Fu H, Corrosion Sci. , 55 , 280, 2012
Fuchs-Godec R, Dolecek V, Colloids Surf. A: Physicochem. Eng. Asp. , 244 , 73, 2004
Li XH, Deng SD, Corrosion Sci. , 65 , 299, 2012
Bentiss F, Lebrini M, Lagrenee M, Corrosion Sci. , 47 , 2915, 2005
Cano E, Polo JL, La Iglesia A, Bastidas JM, Adsorption , 10 , 219, 2004
Branzoi V, Branzoi F, Baibarac M, Mater. Chem. Phys. , 65 (3), 288, 2000
Ateya B, El-Anadauli B, El F, Corrosion Sci. , 24 , 509, 1984
Moretti G, Guidi E, Fabris F, Corrosion Sci. , 76 , 206, 2013
Cao C, Corrosion Sci. , 38 , 2073, 1996
Cao CN, Corrosion Electrochemistry Mechanism, Chemical Industrial Engineering Press, Beijing, 235 (2004), (in Chinese).
Labjar N, Lebrini M, Bentiss F, Chihib NE, El Hajjaji S, Jama C, Mater. Chem. Phys. , 119 (1-2), 330, 2010
Lagrenee M, Mernari B, Bouanis M, Traisnel M, Bentiss F, Corrosion Sci. , 44 , 573, 2002
Singh AK, Quraishi MA, Corrosion Sci. , 52 , 152, 2010
Lebrini M, Lagrenee M, Vezin H, Traisnel M, Bentiss F, Corrosion Sci. , 49 , 2254, 2007
Qu Q, Jiang S, Bai W, Li L, Electrochim. Acta , 52 (24), 6811, 2007
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