| Issue |
Korean Journal of Chemical Engineering,
Vol.32, No.11, 2295-2299, 2015
Vol.32, No.11, 2295-2299, 2015
Absorption of carbon dioxide in aqueous solutions of imidazolium ionic liquids with carboxylate anions
.The solubility of carbon dioxide at atmospheric pressure in aqueous mixtures of 1,3-alkyl substituted imidazolium ionic liquids (ILs) containing carboxylic anions was studied. The ILs showed increased solubility of CO2 with decreasing water concentration. The relationship between the CO2 concentration in solution and the mole fraction of water in the ILs describes a sigmoidal curve. The regression constants of a logistic function were used to quantitatively assess the absorbent capacity and the effect of water on CO2 absorption. ILs containing the most basic anions, such as pivalate, propionate and acetate, had the best properties. It was observed that the impact of water on absorption primarily depended on the cation structure. The best absorption performance was observed for 1,3-dibutylimidazolium pivalate and 1-butyl-3-methyl imidazolium acetate.
[References]
- Iwata H, Okada K, Environ. Econ. Policy Stud., 16, 325, 2014
- Bakker S, de Coninck H, Groenenberg H, Int. J. Greenh. Gas Control, 4, 321, 2010
- Boot-Handford ME, Abanades JC, Anthony EJ, Blunt MJ, Brandani S, Dowell NM, Fernandez JR, Ferrari MC, Gross R, Hallett JP, Haszeldine RS, Heptonstall P, Lyngfelt A, Makuch Z, Mangano E, Porter RTJ, Pourkashanian M, Rochelle GT, Shah N, Yao JG, Fennell PS, Energy Environ. Sci., 7, 130, 2014
- Lee JH, Kwak NS, Lee IY, Jang KR, Lee DW, Jang SG, Kim BK, Shim JG, Korean J. Chem. Eng., 32(5), 800, 2015
- Harkin T, Hoadley A, Hooper B, Chem. Eng. Trans., 25, 13, 2011
- Zaman M, Lee JH, Korean J. Chem. Eng., 30(8), 1497, 2013
- Kumar S, Cho JH, Moon I, Int. J. Greenh. Gas Control, 20, 87, 2014
- Cevasco G, Chiappe C, Green Chem., 16, 2375, 2014
- Shiflett MB, Drew DW, Cantini RA, Yokozeki A, Energy Fuels, 24, 5781, 2010
- Smiglak M, Pringle JM, Lu X, Han L, Zhang S, Gao H, MacFarlane DR, Rogers RD, Chem. Commun., 50, 9228, 2014
- Hasib-ur-Rahman M, Siaj M, Larachi F, Chem. Eng. Process., 49(4), 313, 2010
- Yu CH, Aerosol Air Qual. Res., 12, 745, 2012
- Gurkan BE, de la Fuente JC, Mindrup EM, Ficke LE, Goodrich BF, Price EA, Schneider WF, Brennecke JF, J. Am. Chem. Soc., 132(7), 2116, 2010
- Yasaka Y, Ueno M, Kimura Y, Chem. Lett., 43(5), 626, 2014
- Wang GN, Hou WL, Xiao F, Geng JA, Wu YT, Zhang ZB, J. Chem. Eng. Data, 56(4), 1125, 2011
- Sharma P, Choi SH, Park SD, Baek IH, Lee GS, Chem. Eng. J., 181-182, 834, 2012
- Baek IH, Chem. Eng. J., 245, 370, 2014
- Seo S, Quiroz-Guzman M, Gohndrone TR, Brennecke JF, Chem. Eng. J., 245, 367, 2014
- Gurau G, Rodriguez H, Kelley SP, Janiczek P, Kalb RS, Rogers RD, Angew. Chem.-Int. Edit., 50, 12024, 2011
- Janiczek P, Kalb RS, Thonhauser G, Gamse T, Sep. Purif. Technol., 97, 20, 2012
- Khonkaen K, Siemanond K, Henni A, Comput. Aided Chem. Eng., 33, 1045, 2014
- Blath J, Deubler N, Hirth T, Schiestel T, Chem. Eng. J., 181-182, 152, 2012
- Wu H, Maginn EJ, Fluid Phase Equilib., 368, 72, 2014
- Stevanovic S, Podgorsek A, Padua AAH, Gomes MFC, J. Phys. Chem. B, 116(49), 14416, 2012
- Premi C, Jain N, Eur. J. Org. Chem., 24, 5493, 2013
- US Patent, 5,182,405 (1991).
- Chen YF, Cui YH, Deng DS, Ai N, Adv. Mater. Res., 807-809, 543, 2013
- Yokozeki A, Shiflett MB, Junk CP, Grieco LM, Foo T, J. Phys. Chem. B, 112(51), 16654, 2008
- Stevanovic S, Podgorsek A, Moura L, Santini CC, Padua AAH, Gomes MFC, Int. J. Greenh. Gas Control, 17, 78, 2013
- Gimeno MP, Mayoral MC, Andres JM, Energy Fuels, 27(7), 3928, 2013
- Kerle D, Ludwig R, Paschek D, Z. Fur Phys. Chem., 227, 167, 2013
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