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Issue
Korean Journal of Chemical Engineering,
Vol.32, No.5, 950-957, 2015
A novel technology for extraction of phenolic antioxidants from mandarin (Citrus deliciosa Tenore) leaves: Solvent-free microwave extraction
Sahin S
Solvent-free microwave extraction (SFME) of polyphenols and flavonoids from mandarin (Citrus deliciosa Tenore) leaves was investigated. A face central composite design (FCCD) through response surface methodology (RSM) was applied to study the effects of extraction time (30-90 sec), microwave irradiation power (250-350 W) and solid mass (2.5-7.5 g), and to optimize the extraction process. The optimum conditions were: extraction time, 53.155 sec; microwave power, 339.190W; and solid mass, 2.500 g. Under the optimum conditions, 0.8610mg-GAE/g-DL of total phenolic content (TPC) and 0.2440mg-CE/g-DL of total flavonoid content (TFC) were extracted. The antioxidant activity of the extracts was assessed by cupric ion reducing antioxidant capacity (CUPRAC), 2,2-diphenyl-1-picrylhydrazyl (DPPH) and 2,2'-azino-bis-(3-ethylbenzothiazoline-6-sulfonic acid) diammonium salt (ABTS) methods, respectively. Antioxidant values were expressed as mg trolox equivalent antioxidant capacity per gram of dried leaf (mg-TEAC/g-DL). CUPRAC values were highly correlated with both TPC and TFC (r=0.9282/0.8842, P=0.05) in the extracts, whilst DPPH (r=0.7717/0.7435, P=0.05) and ABTS (r=0.6814/0.7072, P=0.05) were relatively less correlated with the same responses.
Keywords: Citrus deliciosa Tenore Leaves; Solvent-free Microwave Extraction; Optimization; TPC; TFC; Antioxidant Activity
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[Cited By]
  1. Sahin S, Sayim E, Samli R, Korean Journal of Chemical Engineering, 34(8), 2284, 2017
  2. Kim YW, Shin HJ, Korean Journal of Chemical Engineering, 34(12), 3163, 2017
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