Issue
Korean Journal of Chemical Engineering,
Vol.32, No.5, 845-851, 2015
Cleaning of gaseous hydrogen chloride in a syngas by spray-dried potassium-based solid sorbents
There are corrosive gases such as H2S and HCl in a coal- or biomass-derived syngas. HCl can be removed by Na2CO3 or K2CO3 at hot temperatures. Hot syngas cleaning has the advantage of improving thermal efficiency. We investigated HCl removal by spray-dried potassium-based solid sorbents which were originally developed for postcombustion CO2 capture. Both fresh and spent CO2 sorbents were tested to confirm the applicability as a sorbent for HCl cleaning. Saturation chlorine sorption capacity was measured using a fixed-bed reactor at a temperatures of 300- 500 oC under an ambient pressure. Both fresh and spent CO2 sorbents showed saturation chlorine sorption capacity above 15 wt%. HCl removal performance of the sorbents was investigated in a micro fluidized-bed reactor and a benchscale bubbling fluidized-bed reactor. HCl concentration was lowered from 150-900 ppmv to less than 5 ppmv and from 130-390 ppmv to less than 1 ppmv in a micro fluidized-bed reactor and in a bench-scale bubbling fluidized-bed reactor, respectively, at 300-540 oC and 20 bar. It could be concluded that both fresh and spent spray-dried potassium-based CO2 sorbents could be utilized as a disposable HCl sorbent for hot syngas cleaning.
[References]
  1. “DOE/NETL advanced carbon dioxide capture R&D program: Technology update,” National Energy Technology Laboratory, U.S. Department of Energy, 2010
  2. Finkenrath, M. “Cost and Performance of Carbon Dioxide Capture from Power Generation,” OECD/IEA, 2011
  3. Gerdes, K. “Current and future technologies for gasification-based power generation,” DOE/NETL-2009/1389, National Energy Technology Laboratory, 2009
  4. “Preliminary Feasibility Analysis of RTI Warm Gas Cleanup (WGCU) Technology” Nexant, 2007
  5. Kang SH, Lee SJ, Jung WH, Chung SW, Yun Y, Jo SH, Park YC, Baek JI, Korean J. Chem. Eng., 30(1), 67, 2013
  6. Park YC, Jo SH, Ryu HJ, Moon JH, Yi CK, Yoon YS, Baek JI, Korean J. Chem. Eng., 29(12), 1812, 2012
  7. Jung SY, Park JJ, Lee SJ, Jun HK, Lee SC, Kim JC, Korean J. Chem. Eng., 27(5), 1428, 2010
  8. Cheah S, Carpenter DL, Magrini-Bair KA, Energy Fuels, 23, 5291, 2009
  9. Ohtsuka Y, Tsubouchi N, Kikuchi T, Hashimoto H, Powder Technol., 190(3), 340, 2009
  10. Chyang CS, Han YL, Zhong ZC, Energy Fuels, 23(8), 3948, 2009
  11. Coda B, Aho M, Berger R, Hein KRG, Energy Fuels, 15(3), 680, 2001
  12. Weinell CE, Jensen PJ, Dam-Johansen K, Livbjerg H, Ind. Eng. Chem. Res., 31, 164, 1992
  13. Partanen J, Backman P, Backman R, Hupa M, Fuel, 84(12-13), 1674, 2005
  14. Duo W, Kirkby NF, Seville JP, Kiel JH, Bos A, Denuil H, Chem. Eng. Sci., 51(11), 2541, 1996
  15. Verdone N, De Filippis P, Chem. Eng. Sci., 61(22), 7487, 2006
  16. Dou BL, Gao JS, Baek SW, Sha XH, Energy Fuels, 17(4), 874, 2003
  17. Dou BL, Gao JS, Sha XZ, Fuel Process. Technol., 72(1), 23, 2001
  18. Krishnan GN, Gupta RP, Canizales A, Sheluka S, Ayala R, In: Schmidt E, Gang P, Pilz T, Dittler A, Eds. “High Temperature Gas Cleaning” Karlsruhe: G. Braun Printconsult GmbH, 405, 1996
  19. Nunokawa M, Kobayashi M, Shirai H, In: Dittler, Hemmer AG, Kasper G, Eds. “High Temperature Gas Cleaning, Vol. II” Karlsruhe: G. Braun Printconsult GmbH, 684, 1999
  20. Lee JB, Baek JI, Ryu CK, Yi CK, Jo SH, Kim SH, Ind. Eng. Chem. Res., 47(13), 4455, 2008
  21. Lee JB, Ryu CK, Baek JI, Lee JH, Eom TH, Kim SH, Ind. Eng. Chem. Res., 47(13), 4465, 2008
  22. Baek JI, Ryu CK, Ryu J, Kim JW, Eom TH, Lee JB, Yi J, Energy Fuels, 24, 5757, 2010
  23. Lee JB, Eom TH, Oh BS, Baek JI, Ryu J, Jeon WS, Wi YH, Ryu CK, Energy Procedia, 4, 1494, 2011