Issue
Korean Journal of Chemical Engineering,
Vol.32, No.5, 808-815, 2015
Adsorption breakthrough dynamics of zeolites for ethylene recovery from fluid catalytic cracking fuel-gas
The adsorption dynamics of zeolite 13X, 10X and 5A beds was investigated for recovering ethylene (C2H4) from fluidized catalytic cracking fuel-gas. As a feed gas, a ternary mixture (CH4 : C2H4 : C2H6) and a model FCC fuelgas (CH4 : C2H4 : C2H6 : C3H6 : N2 : H2) were used for breakthrough experiments. In the ternary mixture, the concentration profiles showed similar patterns in all zeolite beds. C2H4 showed higher adsorption affinity than the others in all zeolites and zeolite 5A had the highest adsorption capacity of C2H4. In the six-component mixture, the breakthrough curves in the zeolite 5A bed showed similar patterns to the results of the ternary mixture. Although weak adsorbates could be removed during the adsorption step, CH4 and N2 imparted a steric hindrance to the initial stage of C2H4 adsorption in the zeolite 5A bed. Since vacuum desorption contributed to producing a high purity of C2H4, a pressure vacuum swing adsorption process was recommended to recover C2H4.
[References]
  1. Cho S, Han S, Kim J, Park J, Rhee H, Korean J. Chem. Eng., 19(5), 821, 2002
  2. Park JH, Han SS, Kim JN, Cho SH, Korean J. Chem. Eng., 21(1), 236, 2004
  3. Cho SH, Park JH, Han SS, Kim JN, Adsorption, 11, 145, 2005
  4. Triebe RW, Tezel FH, Khulbe KC, Gas Sep. Purif., 10(1), 81, 1996
  5. Grande CA, Gigola C, Rodrigues AE, Ind. Eng. Chem. Res., 41(1), 85, 2002
  6. Granato MA, Vlugt TJH, Rodrigues AE, Ind. Eng. Chem. Res., 46(22), 7239, 2007
  7. Jin M, Kim SS, Kim YD, Park JN, Kim JH, Ko CH, Kim JN, Kim JM, J. Mater. Chem. A, 1, 6653, 2013
  8. Ko CH, Han SS, Park JH, Cho SH, Kim JN, Ind. Eng. Chem. Res., 45(26), 9129, 2006
  9. Lee JW, Park JH, Han SS, Kim JN, Cho SH, Lee YT, Sep. Sci. Technol., 39(6), 1365, 2004
  10. You YW, Lee DG, Yoon KY, Moon DK, Kim SM, Lee CH, Int. J. Hydrog. Energy, 37(23), 18175, 2012
  11. Ahn S, You YW, Lee DG, Kim KH, Oh M, Lee CH, Chem. Eng. Sci., 68(1), 413, 2012
  12. Han SS, Park JH, Kim JN, Cho SH, Adsorption, 11, 621, 2005
  13. Kim YH, Lee DG, Moon DK, Byeon SH, Ahn HW, Lee CH, Korean J. Chem. Eng., 31(1), 132, 2014
  14. Jee JG, Lee SJ, Kim MB, Lee CH, AIChE J., 51(11), 2988, 2005
  15. Lee SJ, Jung JH, Moon JH, Jee JG, Lee CH, Ind. Eng. Chem. Res., 46(11), 3720, 2007
  16. Lee DG, Kim JH, Lee CH, Sep. Purif. Technol., 77(3), 312, 2011
  17. Lee DG, Han YJ, Lee CH, Korean J. Chem. Eng., 29(9), 1246, 2012
  18. Park YH, Moon DK, Kim YH, Ahn H, Lee CH, Adsorption, 20, 631, 2014
  19. Carter JW, Husain H, Chem. Eng. Sci., 29, 267, 1974
  20. Li G, Xiao P, Xu D, Webley PA, Chem. Eng. Sci., 66(9), 1825, 2011
  21. Bae YS, Lee CH, Carbon, 43, 95, 2005
  22. Jee JG, Kim MB, Lee CH, Chem. Eng. Sci., 60(3), 869, 2005
  23. Kim MB, Bae YS, Choi DK, Lee CH, Ind. Eng. Chem. Res., 45(14), 5050, 2006
  24. Chu XZ, Cheng ZP, Xiang XX, Xu JM, Zhao YJ, Zhang WG, Lu JS, Zhou YP, Zhou L, Moon DK, Lee CH, Int. J. Hydrog. Energy, 39(9), 4437, 2014
  25. Yang JY, Lee CH, AIChE J., 44(6), 1325, 1998
  26. Jee JG, Kim MB, Lee CH, Ind. Eng. Chem. Res., 40(3), 868, 2001