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Issue
Korean Journal of Chemical Engineering,
Vol.32, No.3, 511-520, 2015
Adsorption behavior of α-tocopheryl succinate and α-tocopheryl polyethylene glycol succinate onto weakly basic anion exchange resins
Kong L, Zhang Z, Xing H, Yang Q, Su B, Bao Z, Yang Y, Ren Q
Polyethylene glycol (PEG) esters are important, nontoxic and biodegradable non-ionic surfactants. A key procedure in producing PEG esters is their separation from unreacted or excess acids. We propose an adsorption method using the weakly basic anion exchange resins for the separation of organic acids and PEG esters for the first time. With α-tocopheryl polyethylene glycol succinate (TPGS) and α-tocopheryl succinate (α-TS) as the examples of PEG ester and organic acid, respectively, single-component equilibrium experiments revealed the great potential of this method. Studies on the adsorption equilibrium, thermodynamics and kinetics of α-TS onto a weakly basic anion exchange resin were also carried out. This research is not only important for the production of TPGS, but also instructive for the separation of other PEG-esters from the reaction mixtures.
Keywords: PEG Esters; Organic Acids; Adsorption; Weakly Basic Anion Exchange Resin
[References]
  1. Knop K, Hoogenboom R, Fischer D, Schubert US, Angew. Chem., Int. Ed., 49, 6288, 2010
  2. Xu H, Deng YH, Chen DW, Hong WW, Lu Y, Dong XH, J. Control. Release, 130, 238, 2008
  3. Ihre H, De Jesus OLP, Frechet JMJ, J. Am. Chem. Soc., 123(25), 5908, 2001
  4. Lei JH, Li H, Du XD, Zhang AF, Iran. Polym. J., 22, 117, 2013
  5. Abd Hamid SB, Abdullah FZ, Ariyanchira S, Mifsud M, Iborra S, Corma A, Catal. Today, 97(4), 271, 2004
  6. Climent MJ, Corma A, Hamid SBA, Iborra S, Mifsud M, Green Chem., 8, 524, 2006
  7. Buckingham LE, Balasubramanian M, Safa AR, Shah H, Komarov P, Emanuele RM, Coon JS, Int. J. Cancer, 65, 74, 1996
  8. Buckingham LE, Balasubramanian M, Emanuele RM, Clodfelter KE, Coon JS, Int. J. Cancer, 62, 436, 1995
  9. Padmavathi NC, Chatterji PR, Langmuir, 11(3), 767, 1995
  10. Tong WY, Fu XY, Lee SM, Yu J, Liu JW, Wei DZ, Koo YM, Biochem. Eng. J., 18, 89, 2004
  11. Yoshida H, Takatsuji W, Ind. Eng. Chem. Res., 39(4), 1074, 2000
  12. Kanazawa N, Urano K, Kokado N, Urushigawa Y, J. Colloid Interface Sci., 271(1), 20, 2004
  13. Kananpanah S, Dizadji N, Abolghasemi H, Salamatinia B, Korean J. Chem. Eng., 26(5), 1208, 2009
  14. Ma CH, Yang L, Zu YG, Wang NH, Zhang L, Zhang Y, Chen XQ, Zhao CJ, Chem. Eng. Res. Des., 90(9), 1189, 2012
  15. Xu ZW, Zhang WM, Lv L, Pan BC, Lan P, Zhang QX, Environ. Sci. Technol., 44, 3130, 2010
  16. Traber MG, Schiano TD, Steephen AC, Kayden HJ, Shike M, Am. J. Clin. Nutr., 59, 1270, 1994
  17. Sokol RJ, Heubi JE, Butlersimon N, McClung HJ, Lilly JR, Silverman A, Gastroenterology, 93, 975, 1987
  18. Collnot EM, Baldes C, Wempe MF, Hyatt J, Navarro L, Edgar KJ, Schaefer UF, Lehr CM, J. Control. Release, 111, 35, 2006
  19. Chang YZ, Cao YC, Zhang J, Wen YY, Ren QL, J. Pharmaceut. Biomed., 56, 804, 2011
  20. Mert O, Lai SK, Ensign L, Yang M, Wang YY, Wood J, Hanes J, J. Control. Release, 157, 455, 2012
  21. Wang JY, Su BG, Xing HB, Yang YW, Ren QL, J. Appl. Polym. Sci., 119(5), 3026, 2011
  22. Langmuir I, J. Am. Chem. Soc., 40, 1361, 1918
  23. Carmo AM, Hundal LS, Thompson ML, Environ. Sci. Technol., 34, 4363, 2000
  24. Li Q, Yue QY, Su Y, Gao BY, Sun HJ, Chem. Eng. J., 158(3), 489, 2010
  25. Quinones I, Guiochon G, J. Colloid Interface Sci., 183(1), 57, 1996
  26. Dabrowski A, Jaroniec M, Acta Chim. Hung., 99, 255, 1979
  27. Choy KKH, McKay G, Porter JF, Resour. Conserv. Recycl., 27, 57, 1999
  28. Lin SH, Juang RS, J. Hazard. Mater., 92(3), 315, 2002
  29. Yousef RI, El-Eswed B, Al-Muhtaseb AH, Chem. Eng. J., 171(3), 1143, 2011
  30. Ozacar M, Sengil IA, Turkmenler H, Chem. Eng. J., 143(1-3), 32, 2008
  31. Rudzinski W, Plazinski W, J. Phys. Chem. B, 110(33), 16514, 2006
  32. Ho YS, McKay G, Process Biochem., 34(5), 451, 1999
  33. Ozacar M, Adsorption, 9, 125, 2003
  34. Ho YS, McKay G, Resour. Conserv. Recycl., 25, 171, 1999
  35. Sarkar D, Chattoraj DK, J. Colloid Interface Sci., 157, 219, 1993
  36. Atun G, Sismanoglu T, J. Environ. Sci. Health Part A, 31, 2055, 1996
  37. Greluk M, Hubicki Z, J. Hazard. Mater., 172(1), 289, 2009
[Cited By]
  1. Valizadeh S, Rasoulifard MH, Dorraji MSS, Korean Journal of Chemical Engineering, 33(2), 481, 2016
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