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Issue
Korean Journal of Chemical Engineering,
Vol.32, No.3, 436-445, 2015
Characterization of high-alumina coal fly ash based silicate material and its adsorption performance on volatile organic compound elimination
Yuan G, Zhang J, Zhang Y, Yan Y, Ju X, Sun J
A highly stable silicate material from high-alumina coal fly ash was prepared and characterized using X-ray diffraction, scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy, thermal analysis, Xray photoelectron spectroscopy, and elemental analysis. The spectral results show that the silicate material was mainly composed of six elements, C, Ca, O, Si, Mg, and Al, in the form of Ca2+, Mg2+, Al3+, SiO3 2-, and CO3 2- ions. Some adsorbed water and/or water of crystallization was also observed. The silicate material showed exceptionally high capability to adsorb volatile organic compounds (VOCs). The results of dynamic adsorption behavior show that the silicate material presents similar properties with commercial activated carbon and stronger absorption properties than commercial diatomite for the adsorption of VOCs. The FTIR spectral results show weak hydrogen bonding interactions of the silicate material with three VOCs.
Keywords: High-alumina Coal Fly Ash; Silicate Material; Volatile Organic Compounds; Column Breakthrough Curve; Hydrogen Bonding
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[Cited By]
  1. Lee BH, Kim SI, Kim SM, Oh DH, Gupta S, Jeon CH, Korean Journal of Chemical Engineering, 33(1), 147, 2016
  2. Yang X, Liu X, Tang W, Gao Y, Ni H, Zhang J, Korean Journal of Chemical Engineering, 34(3), 723, 2017
  3. Zhang X, Wu Y, Li X, Meng X, Shi H, Wu Z, Zhang J, Korean Journal of Chemical Engineering, 36(5), 753, 2019
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