About The Journal
  Aims and Scope
  Editorial Board
  Submit a Manuscript 
  Subscription Information
  Guidelines for Publication
  Ethics
Articles & Issues
  Search
  Issue
  Online First
  KJChE on
For Authors
  Instructions to Authors
  Ethical Responsibilities of
  Authors in KJChE
  Ethics in Publishing
  Peer Review Process
  Author's Checklist
  Copyright Transfer Form
Contact us
 
 
 
Issue
Korean Journal of Chemical Engineering,
Vol.32, No.3, 429-435, 2015
Electrochemical characterization of mixed matrix heterogeneous cation exchange membranes modified by simultaneous using ilmenite-co-iron oxide nanoparticles
Hosseini SM, Hamidi A, Moghadassi A, Madaeni SS
Mixed matrix heterogeneous cation exchange membranes were prepared by solution casting technique. Ilmenite-co-iron oxide nanoparticle was also employed as inorganic filler additive in membrane fabrication. The effect of the used additives on membrane electrochemical properties was studied. Membrane ion exchange capacity, membrane potential, transport number and selectivity all were improved by use of FeTiO3/Fe3O4 nanoparticles in membrane matrix. Utilizing FeTiO3-co-Fe3O4 nanoparticles in the casting solution also led to increase in ionic flux obviously. The modified membranes containing FeTiO3-co-Fe3O4 nanoparticles showed higher transport number, selectivity and ionic flux compared to modified membrane containing ilmenite. Electrodialysis experiment in laboratory scale also showed higher cation removal for modified membrane containing FeTiO3-co-Fe3O4 nanoparticles compared to other modified membranes and pristine ones. Results showed that membrane areal electrical resistance declined sharply by use of FeTiO3-co-Fe3O4 nanoparticles in membrane matrix. Moreover, modified membrane containing ilmenite showed lower electrical resistance compared to others. Results showed that oxidative stability of membranes was decreased slightly by use of FeTiO3/Fe3O4 nanoparticles in membrane matrix. The results revealed that modified membranes in this study are comparable with that of other commercial ones.
Keywords: Composite Ion Exchange Membrane; Ilmenite-co-iron Oxide Nanoparticles; Synergy; Electrodialysis; Adsorption-ion Exchange; Preparation/Characterization
[References]
  1. Zarrinkhameh M, Zendehnam A, Hosseini SM, Korean J. Chem. Eng., 31(7), 1187, 2014
  2. Hosseini SM, Gholami A, Koranian P, Nemati M, Madaeni SS, Moghadassi AR, J. Taiwan Inst. Chem. Eng., In Press, DOI:10.1016/j.jtice.2014.01.011.
  3. Nagarale RK, Gohil GS, Shahi VK, Adv. Colloid Interface Sci., 119, 97, 2006
  4. Kariduraganavar MY, Nagarale RK, Kittur AA, Kulkarni SS, Desalination, 197(1-3), 225, 2006
  5. Xu TW, J. Membr. Sci., 263(1-2), 1, 2005
  6. Baker RW, Membrane Technology and Applications, 2nd Ed., Wiley, England, 2004
  7. Dlugolecki P, Anet B, Metz SJ, Nijmeijer K, Wessling M, J. Membr. Sci., 346(1), 163, 2010
  8. Gohil GS, Binsu VV, Shahi VK, J. Membr. Sci., 280(1-2), 210, 2006
  9. Zendehnam A, Arabzadegan M, Hosseini SM, Robatmili N, Madaeni SS, Korean J. Chem. Eng., 30(6), 1265, 2013
  10. Hosseini SM, Madaeni SS, Zendehnam A, Moghadassi AR, Khodabakhshi AR, Sanaeepur H, J. Ind. Eng. Chem., 19(3), 854, 2013
  11. Ng LY, Mohammad AW, Leo CP, Hilal N, Desalination, 308, 15, 2013
  12. Hosseini SM, Madaeni SS, Heidari AR, Amirimehr A, Desalination, 284, 191, 2012
  13. Fujii T, Yamashita M, Fujimori S, Saitoh Y, Nakamura T, Kobayashi K, Takada J, J. Magn. Magn. Mater., 310, 555, 2007
  14. Raghavender AT, Hong NH, Lee KJ, Jung MH, Skoko Z, Vasilevskiy M, Cerqueira MF, Samantilleke AP, J. Magn. Magn. Mater., 331, 129, 2013
  15. Xu P, Zeng GM, Huang DL, Feng CL, Hu S, Zhao MH, Lai C, Wei Z, Huang C, Xie GX, Liu ZF, Science of the Total Environment, 424, 1, 2012
  16. Mark E, J. Polymer Data Handbook, Oxford University Press Inc., New York, 1999
  17. Harper CA, Handbook of plastic and elastomers, New York, McGraw-Hill, 1975
  18. Li XF, Wang Z, Lu H, Zhao CJ, Na H, Zhao C, J. Membr. Sci., 254(1-2), 147, 2005
  19. Nagarale RK, Gohil GS, Shahi VK, Rangarajan R, Colloids Surf. A, 251, 133, 2004
  20. Nagarale RK, Shahi VK, Thampy SK, Rangarajan R, React. Funct. Polym., 61(1), 131, 2004
  21. Nagarale RK, Shahi VK, Rangarajan R, J. Membr. Sci., 248(1-2), 37, 2005
  22. Lide DR, CRC Handbook of Chemistry and Physics, 87th Ed. Boca Raton, CRC Press, 2006
  23. Kang MS, Choi YJ, Choi IJ, Yoon TH, Moon SH, J. Membr. Sci., 216(1-2), 39, 2003
  24. Shahi VK, Trivedi GS, Thampy SK, Rangarajan R, J. Colloid Interface Sci., 262(2), 566, 2003
  25. Kerres J, Cui W, Disson R, Neubrand W, J. Membr. Sci., 139(2), 211, 1998
  26. Tanaka Y, Ion exchange membranes: Fundamentals and applications, Netherlands: Membrane Science and Technology Series Elsevier, 2007
  27. Sata T, Ion exchange membranes: Preparation, characterization, modification and application, Cambridge/United Kingdom: The Royal Society of Chemistry, 2004
  28. Schauer J, Brozova L, J. Membr. Sci., 250(1-2), 151, 2005
  29. Powell CE, Qiao GG, J. Membr. Sci., 279(1-2), 1, 2006
  30. Dlugolecki P, Nymeijer K, Metz S, Wessling M, J. Membr. Sci., 319(1-2), 214, 2008
[Cited By]
  1. Hosseini S, Hamidi A, Moghadassi A, Parvizian F, Madaeni SS, Korean Journal of Chemical Engineering, 32(9), 1827, 2015
  2. Halek FS, Farahani SK, Hosseini SM, Korean Journal of Chemical Engineering, 33(2), 629, 2016
  3. Nemati M, Hosseini SM, Bagheripour E, Madaeni SS, Korean Journal of Chemical Engineering, 33(3), 1037, 2016
  4. Bagheripour E, Moghadassi A, Hosseini SM, Korean Journal of Chemical Engineering, 33(4), 1462, 2016
  5. Jung IL, Park YC, Park DH, Korean Journal of Chemical Engineering, 33(6), 1865, 2016
  6. Moochani M, Moghadassi A, Hosseini SM, Bagheripour E, Parvizian F, Korean Journal of Chemical Engineering, 33(9), 2674, 2016
  7. Nemati M, Hosseini SM, Shabanian M, Korean Journal of Chemical Engineering, 34(6), 1813, 2017
  8. Hosseini SM, Karami F, Farahani SK, Bandehali S, Shen J, Bagheripour E, Seidypoor A, Korean Journal of Chemical Engineering, 37(5), 866, 2020
  9. Ansari S, Moghadassi A, Hosseini SM, Korean Journal of Chemical Engineering, 37(11), 2011, 2020
참고문헌정보(참고문헌, 인용문헌)는 화학공학소재연구정보센터에 의해 제공되고 있습니다.