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Issue
Korean Journal of Chemical Engineering,
Vol.31, No.12, 2286-2290, 2014
One-pot synthesis of 5-hydroxymethylfurfural directly from cottonseed hull biomass using chromium (III) chloride in ionic liquid
Wang S, Du Y, Zhang P, Cheng X, Qu Y
We studied the direct synthesis of 5-hydroxymethylfurfural (5-HMF) from cottonseed hull biomass under acid condition in one-pot. The influence of HCl dosage, reaction temperature and time, CrCl3·6H2O amount, and cottonseed hull loading on the yield of 5-HMF was investigated. As a result, a 5-HMF yield up to 51% was obtained using 1-butyl-3-methylimidazolium chloride ([Bmim]Cl) catalyzed with chromium (III) chloride at 130 ℃ for 2 h. The [Bmim]Cl/ CrCl3·6H2O/HCl system was found to have high activity and selectivity for the dehydration of cellulose into 5-hydroxymethylfurfural. This work provides a low cost, environment-friendly and energy-efficient process to directly convert raw biomass into bio-fuels and chemicals.
Keywords: Cottonseed Hull; 5-Hydroxymethylfurfural; Furfural; Chromium (III) Chloride; [BMIM]Cl
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[Cited By]
  1. You SJ, Park ED, Park MJ, Korean Journal of Chemical Engineering, 33(3), 806, 2016
  2. Esmaeili N, Zohuriaan-Mehr MJ, Bouhendi H, Bagheri-Marandi G, Korean Journal of Chemical Engineering, 33(6), 1964, 2016
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