Issue
Korean Journal of Chemical Engineering,
Vol.31, No.12, 2198-2206, 2014
Coffee waste as potential adsorbent for the removal of basic dyes from aqueous solution
We evaluated the adsorption performance of coffee waste (CW), collected from coffee shops, for the removal of two basic dyes, toluidine blue (TB) and crystal violet (CV), from aqueous solutions. Batch adsorption experiments were conducted under different conditions including contact time, initial concentration of dye, pH, sorbent dosage and temperature. The Langmuir, Freundlich, Temkin and Dubinin-Radushkevich (D-R) isotherms were tested to examine the adsorption behavior. The equilibrium data were well fitted by Langmuir isotherm model. The kinetic study indicates that adsorption follows the pseudo second-order model. The maximum adsorption capacity was found to be as high as 142.5 mg/g for TB and 125 mg/g for CV, which makes CW a prospective adsorbent for the removal of basic dyes from aqueous solution.
[References]
  1. Singh K, Arora S, Crit. Rev. Env. Sci. Technol., 41, 807, 2011
  2. dos Santos AB, Cervantes FJ, van Lier JB, Bioresour. Technol., 98(12), 2369, 2007
  3. Sauer T, CesconetoNeto G, Jose HJ, Mureira RFPM, J. Photochem. Photobiol. A, 149, 147, 2002
  4. Jain AK, Gupta VK, Bhatnagar A, Suhas, Sep. Sci. Technol., 38(2), 463, 2003
  5. Reffas A, Bernardet V, David B, Reinert L, Lehocine MB, Dubois M, Batisse N, Duclaux L, J. Hazard. Mater., 175(1-3), 779, 2010
  6. Namane A, Mekarzia A, Benrachedi K, Belhaneche-Bensemra N, Hellal A, J. Hazard. Mater., 119(1-3), 189, 2005
  7. Crini G, Bioresour. Technol., 97(9), 1061, 2006
  8. Gupta VK, J. Environ. Manage., 90, 2313, 2009
  9. Mussatto SI, Machado EMS, Carneiro LM, Teixeira JA, Appl. Energy, 92, 763, 2012
  10. Oliveira LS, Franca AS, Camargos RRS, Ferraz VP, Bioresour. Technol., 99(8), 3244, 2008
  11. Azouaou N, Sadaoui Z, Djaafri A, Mokaddem H, J. Hazard. Mater., 184(1-3), 126, 2010
  12. Oliveira WE, Franca AS, Oliveira LS, Rocha SD, J. Hazard. Mater., 152(3), 1073, 2008
  13. Kyzas GZ, Lazaridis NK, Mitropoulos AC, Chem. Eng. J., 148, 189, 2012
  14. Al-Zaben MI, Mekhamer WK, Arabian Journal of Chemistry, In Press, DOI: http://dx.doi.org/10.1016/j.arabjc.2013.05.003.
  15. Oliveira LS, Franca AS, Alves TM, Rocha SDF, J. Hazard. Mater., 155(3), 507, 2008
  16. Franca AS, Oliveira LS, Ferreira ME, Desalination, 249(1), 267, 2009
  17. Kyzas GZ, Materials, 5, 1826, 2012
  18. Kyzas GZ, Materials, 5, 2069, 2012
  19. Boehm HP, Adv. Catal., 16, 179, 1966
  20. Valdes H, Sanchez-Polo M, Rivera-Utrilla J, Zaror CA, Langmuir, 1, 2111, 2002
  21. Hameed BH, El-Khaiary MI, J. Hazard. Mater., 159(2-3), 574, 2008
  22. Hameed BH, J. Hazard. Mater., 161(2-3), 753, 2009
  23. Kumar R, Ahmad R, Desalination, 265(1-3), 112, 2011
  24. Jain S, Jayaram RV, Desalination, 250(3), 921, 2010
  25. Saeed A, Sharif M, Iqbal M, J. Hazard. Mater., 179(1-3), 564, 2010
  26. Cho SY, Park SS, Kim SJ, Kim TY, Korean J. Chem. Eng., 23(4), 638, 2006
  27. Aksu Z, Kabasakal E, Sep. Purif. Technol., 35(3), 223, 2004
  28. Cardoso LP, Valim JB, J. Phys. Chem. Solids, 67, 987, 2006
  29. Gonga R, Dingb Y, Lic M, Yanga C, Liua H, Suna Y, Dyes Pigm., 64, 187, 2005
  30. Sari A, Tuzen M, Soylak M, J. Hazard. Mater., 144(1-2), 41, 2007
  31. Langmuir I, J. Am. Chem. Soc., 38, 2221, 1916
  32. Hall KR, Eagleton LC, Acrivos A, Vermeulen T, Ind. Eng. Chem. Fundam., 5, 212, 1966
  33. Freundlich HMF, J. Phys. Chem., 57, 1906
  34. Temkin MJ, Pyzhev V, Acta Physiochem., USSR, 12, 217, 1940
  35. Dubinin MM, Radushkevich LV, Proc. Acad. Sci. U.S.S.R. Phys. Chem. Sect., 55, 331, 1947
  36. Nasuha N, Hameed BH, Din ATM, J. Hazard. Mater., 175(1-3), 126, 2010
  37. Uddin MT, Islam MA, Mahmud S, Rukanuzzaman M, J. Hazard. Mater., 164(1), 53, 2009
  38. Lagergren S, Sven K, Vetenskapsakad. Handl., 24, 1, 1898
  39. Ho YS, McKay G, Chem. Eng. J., 70(2), 115, 1998
  40. Azizian S, J. Colloid Interface Sci., 276(1), 47, 2004
  41. Siboni MH, Jafari SJ, Farrokhi M, Yang JK, Environ. Eng. Res., 18, 247, 2013
  42. Ho YS, McKay G, Process Biochem., 34(5), 451, 1999
  43. Iqbal M, Saeed A, Zafar SI, J. Hazard. Mater., 164(1), 161, 2009
  44. Gnanasambandam R, Protor A, Food Chem., 68, 327, 2000
  45. Kaikake K, Hoaki K, Sunada H, Dhakal RP, Baba Y, Bioresour. Technol., 98(15), 2787, 2007
  46. Ahmad R, Kumar R, J. Environ. Manage., 91, 1032, 2010