Korean Journal of Chemical Engineering, Vol.31, No.10, 1766-1772, 2014
Leaching kinetics of neodymium in sulfuric acid of rare earth elements (REE) slag concentrated by pyrometallurgy from magnetite ore
We studied the leaching kinetics of recovering neodymium in sulfuric acid from the rare earth elements (REE) slag concentrated by smelting reduction from a magnetite ore containing monazite. The leaching kinetics on neodymium was conducted at a reactant concentration of 1.5 g REE slag per L of 0.3 M H2SO4, agitation of 750 rpm and temperature ranging from 30 to 80 ℃. Neodymium oxide included in the REE slag was completely converted into neodymium sulfate phase (Nd2(SO4)3) in H2SO4 after the leaching of 5 h, 80 ℃. As a result, the leaching mechanism was determined in a two-stage model based on the shrinking core model with spherical particles. The first step was determined by chemical reaction, and the second step was determined by ash layer diffusion because the leaching of REEs by the first chemical reaction increases the formation of the ash layer affecting as a resistance against the leaching.
By using the Arrhenius expression, the apparent activation energy of the first chemical reaction step was found to be 9 kJmol^(-1). After the first chemical reaction, leaching reaction rate was determined by the ash layer diffusion. The apparent activation energy of ash layer diffusion was found to be 32 kJmol^(-1).
[References]
Massari S, Ruberti M, Resources Policy , 38 , 36, 2013
Cui JR, Zhang LF, J. Hazard. Mater. , 158 (2-3), 228, 2008
Lee JC, Song HT, Yoo JM, Conservation and Recycling , 50 , 380, 2007
Tuncuk A, Stazi V, Akcil A, Yazici EY, Deveci H, Miner. Eng. , 25 , 28, 2012
Nnorom IC, Osibanjo O, Conservation and Recycling , 52 , 843, 2008
Stefania M, Marcello R, Resources Policy , 3 , 36, 2013
Aarabi-Karasgani M, Rashchi F, Mostoufi N, Vahidi E, Hydrometallurgy , 102 , 14, 2010
Dehghan R, Noaparast M, Kolahdoozan M, Hydrometallurgy , 96 , 275, 2009
El-Nadi YA, Hydrometallurgy , 119 , 23, 2012
Kul M, Topkaya Y, Karakaya I, Hydrometallurgy , 93 , 129, 2008
Liu K, Chen Q, Yin Z, Hu H, Ding Z, Hydrometallurgy , 125 , 125, 2012
Minting L, Chang W, Shuang Q, Xuejiao Z, Cunxiong L, Zhigan D, Hydrometallurgy , 104 , 193, 2010
Moldoveanu GA, Papangelakis VG, Hydrometallurgy , 117 , 71, 2012
Yoo SJ, Yoon HS, Jang HD, Lee MJ, Lee SI, Hong ST, Park HS, Chem. Eng. J. , 133 (1-3), 79, 2007
Yoo SJ, Kwak DH, Lee JW, Hwang UY, Jang HD, Hydrometallurgy , 96 , 223, 2009
Dodson JR, Hunt AJ, Parker HL, Yang Y, Clark JH, Chem. Eng. Process. , 51 , 69, 2012
Kostova I, Curr. Med. Chem. , 5 , 591, 2005
Manhique AJ, Focke WW, Carvalho M, Hydrometallurgy , 109 , 230, 2011
Levenspiel O, Chemical Reaction Engineering, 3rd Ed., John Wiley & Sons Inc., New York, 2003
Schmidt LD, The Engineering of Chemical Reactions, 2nd Ed., Oxford University Press, 2005
Avrami M, J. Chem. Phys. , 7 , 1103, 1939
Dickinson CF, Heal GR, Thermochim. Acta , 340 , 89, 1999
Orfao JJM, Martins FG, Thermochim. Acta , 390 (1-2), 195, 2002
Kanazawa Y, Kamitani M, J. Alloys Compd. , 408 , 1339, 2006
El-Nadi YA, Daoud JA, Aly HF, Int. J. Miner. Process. , 76 (1-2), 101, 2005
Ding Y, Xue Q, Wang G, Wang J, Matallurgy and Materials Transactions B , 28 , 28, 2013
Fozia A, Muhammad S, Ata A, Hydrometallurgy , 117 , 1, 2012
Georgiana AM, Vladimiros GP, Hydrometallurgy , 117 , 71, 2012
Kandil AT, Aly MM, Moussa EM, Kamel AM, Gouda MM, Kouraim MN, J. Rare Earths , 28 , 576, 2010
Sapsford DJ, Bowell RJ, Geroni JN, Penman KM, Dey M, Miner. Eng. , 39 , 165, 2012
Tian J, Yin J, Chi R, Rao G, Jiang M, Ouyang K, Hydrometallurgy , 101 , 166, 2010
Akinlua A, Torto N, Ajayi TR, Fuel , 87 (8-9), 1469, 2008
HSC Chemistry 5.0 Chemical Reaction and Equilibrium Software with Extensive Thermochemical Database, Ver 5.11, Outokumpu Research, Finland.
Gharabaghi M, Noaparast M, Irannajad M, Hydrommetallurgy , 95 , 341, 2009
KADIOGLU YY, KARACA S, BAYRAKCEKEN S, Fuel Process. Technol. , 41 (3), 273, 1995
Momade FWY, Momade ZG, Hydrometallurgy , 54 , 25, 1999
Okur H, Tekin T, Ozer AK, Bayramoglu M, Hydrometallurgy , 67 , 79, 2002
Alkan M, Dogan M, Chem. Eng. Process. , 43 (7), 867, 2004
Lacin O, Donmez B, Demir F, Int. J. Miner. Process. , 75 (1-2), 91, 2005
Bakan F, Lacin O, Bayrak B, Sarac H, Int. J. Miner. Process. , 80 (1), 27, 2006
Aydogan S, Erdemoglu M, Aras A, Ucar G, Ozkan A, Hydrometallurgy , 84 , 239, 2006
Souza AD, Pina PS, Lima EVO, Da Silva CA, Leao VA, Hydrometallurgy , 89 , 337, 2007
Ekmekyapar A, Demirkiran N, Kunkul A, Chem. Eng. Res. Des. , 86 (9A), 1011, 2008
Souza AD, Pina PS, Santos FMF, Da Silva CA, Leao VA, Hydrometallurgy , 95 , 207, 2009
Donmez B, Demir F, Lacin O, J. Ind. Eng. Chem. , 15 (6), 865, 2009
Safarzadeh MS, Moradkhani D, Ojaghi-Ilkhchi M, J. Hazard. Mater. , 163 (2-3), 880, 2009
Heydarpour T, Rezai B, Gharabaghi M, Chem. Eng. Res. Des. , 89 (10A), 2153, 2011
Kandi AT, Aly MM, Moussa EM, Kamel AM, Gouda MM, Kouraim MN, J. Rare Earths , 28 , 576, 2010
Guliyev R, Kuslu S, Calban T, Colak S, J. Ind. Eng. Chem. , 18 (4), 1202, 2012
Gharabaghi M, Irannajad M, Azadmehr AR, Sep. Purif. Technol. , 86 , 9, 2012
Raschman P, Smincakova E, Hydrometallurgy , 113 , 60, 2012
Huang HQ, Li JS, Li XX, Zhang ZZ, Sep. Purif. Technol. , 108 , 45, 2013
Du GX, Lu GC, He XW, Chin. J. Chem. Eng. , 21 (7), 736, 2013
Gharabaghi M, Irannajad M, Azadmehr AR, Chem. Eng. Res. Des. , 91 (2), 325, 2013
Feng X, Long Z, Cui D, Wang L, Huang X, Zhang G, Tran. Nonferrous Met. Soc. China , 23 , 849, 2013
Martins JP, Hydrometallurgy , 42 , 221, 1996
Souza AD, Pina PS, Leao VA, Silva CA, Siqueira PF, Hydrometallurgy , 89 , 72, 2007
Aarabi-Karasgani M, Rashchi F, Mostoufi N, Vahidi E, Hydrometallurgy , 102 , 14, 2010
Liu K, Chen Q, Yin Z, Hu H, Ding Z, Hydrometallurgy , 125 , 125, 2012
Feng X, Long Z, Cui D, Wang L, Huang X, Zhang G, Trans. Nonferrous Met. Soc. China , 23 , 849, 2013
Bian X, Yin S, Luo Y, Wu W, Trans. Nonferrous Met. Soc. China , 21 , 2306, 2011
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