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Issue
Korean Journal of Chemical Engineering,
Vol.31, No.9, 1674-1680, 2014
Effect of crosslinker feed content on catalaytic activity of silver nanoparticles fabricated in multiresponsive microgels
Farooqi ZH, Khan SR, Hussain T, Begum R, Ejaz K, Majeed S, Ajmal M, Kanwal F, Siddiq M
We investigated the effect of crosslinking density of poly(N-isopropyl acrylamide-co-acrylic acid) microgels on catalytic activity of silver nanoparticles fabricated hybrid microgels. Multiresponsive poly(N-isopropyl acrylamide-co-acrylic acid) microgels with 2, 4, 6 and 8 mole percentage of N,N-methylene-bis-acrylamide were synthesized by emulsion polymerization. These microgels were characterized by dynamic light scattering and were used as microreactors to synthesize silver nanoparticles. Hybrid system was characterized by ultraviolet-visible spectroscopy. The catalytic activity of hybrid microgels with different crosslinker content was compared by studying the reduction of pnitrophenol as a model reaction. Kinetics of reaction was monitored by spectrophotometry. The value of the apparent rate constant decreases from 0.568 to 0.313 min^(-1), when content of crosslinker are increased from 2 to 8 mole percentage respectively. This decreases in value of apparent rate constant is due to increase in diffusional barrier offered by high crosslinking of polymer network at high mole percentages of N,N-methylene-bis-acrylamide.
Keywords: Microgels; Crosslinking Density; Hybrid Microgels; Catalytic Activity
[References]
  1. Nazzal AY, Qu L, Peng X, Xiao M, Nano Lett., 3, 819, 2003
  2. Ionov L, Sapra S, Synytska A, Rogach AL, Stamm M, Diez S, Adv. Mater., 18(11), 1453, 2006
  3. Taton TA, Mirkin CA, Letsinger RL, Science, 289, 1757, 2000
  4. Tokareva I, Minko S, Fendler JH, Hutter E, J. Am. Chem. Soc., 126(49), 15950, 2004
  5. Jones CD, Lyon LA, J. Am. Chem. Soc., 125(2), 460, 2003
  6. Zhang W, Lei X, Wang Z, Zheng D, Tam W, Chan C, Sheng P, Phys. Rev. Lett., 84, 2853, 2000
  7. Graf C, van Blaaderen A, Langmuir, 18(2), 524, 2002
  8. Liang ZJ, Susha AS, Caruso F, Adv. Mater., 14(16), 1160, 2002
  9. Cao YC, Jin R, Mirkin CA, Science, 297, 1536, 2002
  10. Nie SM, Emery SR, Science, 275(5303), 1102, 1997
  11. Ko H, Singamaneni S, Tsukruk VV, Small, 4, 1576, 2008
  12. Ho CH, Tobis J, Sprich C, Thomann R, Tiller JC, Adv. Mater., 16(12), 957, 2004
  13. Daniel MC, Astruc D, Chem. Rev., 104(1), 293, 2004
  14. Grouchko M, Kamyshny A, Mihailescu CF, Anghel DF, Magdassi S, ACS Nano, 5, 3354, 2011
  15. Polavarapu L, Manga KK, Cao HD, Loh KP, Xu QH, Chem. Mater., 23, 3273, 2011
  16. Kumar A, Vemula PK, Ajayan PM, John G, Nat. Mater., 7(3), 236, 2008
  17. Sondi I, Salopek-Sondi B, J. Colloid Interface Sci., 275(1), 177, 2004
  18. Stevens KN, Crespo-Biel O, van der Bosch EE, ADias A, Knetsch ML, Aldenhoff YB, van der Veen FH, Maessen JG, Stobberingh EE, Koole LH, Biomaterials, 30, 3682, 2009
  19. Wu J, Zhao N, Zhang X, Xu J, Cellulose, 19, 1239, 2012
  20. Xie L, Chen M, Wu LM, J. Polym. Sci. A: Polym. Chem., 47(19), 4919, 2009
  21. Khan SR, Farooqi ZH, Ajmal M, Siddiq M, Khan A, J. Disp. Sci. Technol., 34, 1324, 2013
  22. Shipway AN, Katz E, Willner I, Chem. Phys. Chem., 1, 18, 2000
  23. Burda C, Chen XB, Narayanan R, El-Sayed MA, Chem. Rev., 105(4), 1025, 2005
  24. Jiang ZJ, Liu CY, Sun LW, J. Phys. Chem. B, 109(5), 1730, 2005
  25. Patel AC, Li S, Wang C, Zhang W, Wei Y, Chem. Mater., 19, 1231, 2007
  26. Sharghi H, Khalifeh R, Doroodmand MM, Adv. Synth. Catal., 351, 207, 2009
  27. Alonso F, Moglie Y, Radivoy G, Yus M, Tetrahedron Lett., 50, 2358, 2009
  28. Lee J, Park JC, Song H, Adv. Mater., 20(8), 1523, 2008
  29. Heck R, Nolley Jr J, J. Org. Chem., 37, 2320, 1972
  30. Miyaura N, Suzuki A, Chem. Rev., 95(7), 2457, 1995
  31. Wu S, Kaiser J, Guo XH, Li L, Lu Y, Ballauff M, Ind. Eng. Chem. Res., 51(15), 5608, 2012
  32. Zhou P, Li Y, Sun P, Zhou J, Bao J, Chem. Commun., 1418, 2007
  33. Chen LF, Hu JC, Qi ZW, Fang YJ, Richards R, Ind. Eng. Chem. Res., 50(24), 13642, 2011
  34. Sahiner N, Ozay H, Ozay O, Aktas N, Appl. Catal. B: Environ., 101(1-2), 137, 2010
  35. Rashid MH, Mandal TK, Adv. Funct. Mater., 18(15), 2261, 2008
  36. Wu S, Dzubiella J, Kaiser J, Drechsler M, Guo X, Ballauff M, Lu Y, Angew. Chem. Int. Ed., 51, 2229, 2012
  37. Sharma G, Mei Y, Lu Y, Ballauff M, Irrgang T, Proch S, Kempe R, J. Catal., 246(1), 10, 2007
  38. Ghosh SK, Kundu S, Mandal M, Pal T, Langmuir, 18(23), 8756, 2002
  39. Herves P, Perez-Lorenzo M, Liz-Marzan LM, Dzubiella J, Lu Y, Ballauff M, Chem. Soc. Rev., 41, 5577, 2012
  40. Tu CH, Wang AQ, Zheng MY, Wang XD, Zhang T, Appl. Catal. A: Gen., 297(1), 40, 2006
  41. Biffis A, Cunial S, Spontoni P, Prati L, J. Catal., 251(1), 1, 2007
  42. Biffis A, Sperotto E, Langmuir, 19(22), 9548, 2003
  43. Mei Y, Lu Y, Polzer F, Ballauff M, Drechsler M, Chem. Mater., 19, 1062, 2007
  44. Reek JN, Arevalo S, van Heerbeek R, Kamer PC, Van Leeuwen PW, Adv. Catal., 49, 71, 2006
  45. Gao XT, Wachs IE, Catal. Today, 51(2), 233, 1999
  46. Miyadera T, Appl. Catal. B, 2, 199, 1993
  47. Valden M, Lai X, Goodman DW, Science, 281(5383), 1647, 1998
  48. Pich A, Karak A, Lu Y, Ghosh AK, Adler HJP, Macromol. Rapid Commun., 27(5), 344, 2006
  49. Naeem H, Farooqi ZH, Shah LA, Siddiq M, J. Polym. Res., 19, 1, 2012
  50. Dong Y, Ma Y, Zhai TY, Shen FG, Zeng Y, Fu HB, Yao JN, Macromol. Rapid Commun., 28(24), 2339, 2007
  51. Suzuki D, Kawaguchi H, Langmuir, 22(8), 3818, 2006
  52. Bhattacharya S, Eckert F, Boyko V, Pich A, Small, 3, 650, 2007
  53. Liu YY, Liu XY, Yang JM, Lin DL, Chen X, Zha LS, Colloids Surf., A, 393, 105, 2012
  54. Pich A, Karak A, Lu Y, Ghosh AK, Adler HJP, J. Nano. Nanotechnol., 6, 3763, 2006
  55. Sahiner N, Ozay H, Ozay O, Aktas N, Appl. Catal. A: Gen., 385(1-2), 201, 2010
  56. Carregal-Romero S, Buurma NJ, Perez-Juste J, Liz-Marzan LM, Herves P, Chem. Mater., 22, 3051, 2010
  57. Ozlem Nazli K, Pester CW, Konradi A, Boker A, van Rijn P, Chem. A Eur. J., 19, 5586, 2013
  58. Varga I, Gilanyi T, Meszaros R, Filipcsei G, Zrinyi M, J. Phys. Chem. B, 105(38), 9071, 2001
  59. Senff H, Richtering W, J. Chem. Phys., 111(4), 1705, 1999
  60. Saunders BR, Vincent B, Adv. Colloid Interface Sci., 80, 1, 1999
  61. Eichenbaum GM, Kiser PF, Dobrynin AV, Simon SA, Needham D, Macromolecules, 32(15), 4867, 1999
  62. Calvet D, Wong JY, Giasson S, Macromolecules, 37(20), 7762, 2004
  63. Wang SQ, Liu QL, Zhu AM, Eur. Polym. J., 47, 1168, 2011
  64. Farooqi ZH, Khan A, Siddiq M, Polym. Int., 60, 1481, 2011
  65. Burmistrova A, Richter M, Uzum C, Klitzing R, Colloid. Polym. Sci., 289, 613, 2011
  66. Ajmal M, Farooqi ZH, Siddiq M, Korean J. Chem. Eng., 30(11), 2030, 2013
  67. Lizmarzan LM, Giersig M, Mulvaney P, Langmuir, 12(18), 4329, 1996
  68. Kozlovskaya V, Kharlampieva E, Khanal BP, Manna P, Zubarev ER, Tsukruk VV, Chem. Mater., 20, 7474, 2008
  69. Joseph STS, Ipe BI, Pramod P, Thomas KG, J. Phys. Chem. B, 110(1), 150, 2006
  70. Mohan YM, Lee K, Premkumar T, Geckeler KE, Polymer, 48(1), 158, 2007
  71. Heath J, Phys. Rev. B, 40, 9982, 1989
  72. Wunder S, Polzer F, Lu Y, Mei Y, Ballauff M, J. Phys. Chem. C, 114, 8814, 2010
  73. Ghosh SK, Mandal M, Kundu S, Nath S, Pal T, Appl. Catal. A: Gen., 268(1-2), 61, 2004
  74. Guillermo A, Addad JPC, Bazile JP, Duracher D, Elaissari A, Pichot C, J. Polym. Sci. B: Polym. Phys., 38(6), 889, 2000
  75. Zhang JT, Wei G, Keller TF, Gallagher H, Stotzel C, Muller FA, Gottschaldt M, Schubert US, Jandt KD, Macromol. Mater. Eng., 295, 1049, 2010
  76. Antonels NC, Meijboom R, Langmuir, 29(44), 13433, 2013
  77. Vadakkekara R, Chakraborty M, Parikh PA, Colloids Surf., A, 399, 11, 2012
[Cited By]
  1. Haleem A, Syaal SB, Ajmal M, Ambreen J, Rauf S, Ali N, Muhammad S, Shah A, Zia MA, Siddiq M, Korean Journal of Chemical Engineering, 37(4), 614, 2020
  2. Najeeb J, Ahmad G, Nazir S, Naseem K, Kanwal A, Korean Journal of Chemical Engineering, 38(2), 248, 2021
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