| Issue |
Korean Journal of Chemical Engineering,
Vol.31, No.9, 1651-1655, 2014
Vol.31, No.9, 1651-1655, 2014
Low-cost metal oxide activated carbon prepared and modified by microwave heating method for hydrogen storage
Novel microporous activated carbon (MAC) with high surface area and pore volume has been synthesized by microwave heating. Iron oxide nanoparticles were loaded into MAC by using Fe(NO3)3·9H2O followed by microwave irradiation for up to five minutes. The surface modified microporous activated carbon was characterized by BET, XRD, SEM and thermogravimetric examinations. Adsorption data of H2 on the unmodified and modified MACs were collected with PCT method for a pressure range up to 120 bar at 303 K. Greater hydrogen adsorption was observed on the carbon adsorbents doped with 1.45 wt% of iron oxide nanoparticle loaded due to the joint properties of hydrogen adsorption on the carbon surface and the spill-over of hydrogen molecules into carbon structures.
Keywords:
Microporous Activated Carbon; Iron Oxide Nanoparticles; Microwave Synthesis; Surface Modification; Hydrogen Storage
[References]
- Ahluwalia RK, Huaa TQ, Peng JK, Lasher S, McKenney K, Sinha J, Gardiner M, Int. J. Hydrog. Energy, 35(9), 4171, 2010
- Schlapbach L, Nature, 460, 809, 2009
- Bleda-Martinez MJ, Perez JM, Linares-Solano A, Morallon E, Cazorla-Amoros D, Carbon, 46, 1053, 2008
- Surya VJ, Iyakutti K, Venkataramanan N, Mizuseki H, Kawazoe Y, Int. J. Hydrog. Energy, 35(6), 2368, 2010
- Pranevicius L, Wirth E, Milcius D, Lelis M, Pranevicius LL, Bacianskas A, Appl. Surf. Sci., 255(11), 5971, 2009
- Jhi SH, Kwon YK, Bradley K, Gabriel JCP, Solid State Commun., 129, 769, 2004
- Surya VJ, Iyakutti K, Venkataramanan N, Mizuseki H, Kawazoe Y, Int. J. Hydrog. Energy, 35(6), 2368, 2010
- Im JS, Kim SJ, Kang PH, Lee YS, J. Ind. Eng. Chem., 15(5), 699, 2009
- Jung MJ, Kim JW, Im JS, Park SJ, Lee YS, J. Ind. Eng. Chem., 15(3), 410, 2009
- Kim HS, Cha KS, Yoo BK, Ryu TG, Lee YS, Park CS, Kim YH, J. Ind. Eng. Chem., 16(1), 81, 2010
- Rashidi AM, Nouralishahi A, Khodadadi AA, Mortazavi Y, Karimi A, Kashefi K, Int. J. Hydrog. Energy, 35(17), 9489, 2010
- Hirscher M, Becher M, J. Nanosci. Nanotechnol., 3, 3, 2003
- Kim BJ, Park SJ, J. Colloid Interface Sci., 311(2), 619, 2007
- Hejazifar M, Azizian S, Sarikhani H, Li Q, Zhao D, J. Anal. Appl. Pyrol., 92, 258, 2011
- Figueroa-Torres MZ, Robau-Sanchez A, Torre-Saenz L, Aguilar-Elguezabal A, Micropor. Mesopor. Mater., 98, 89, 2007
- Dollimore D, Heal GR, J. Colloid Interface Sci.,, 33, 508, 1970
- Brunauer S, Emmett PH, Teller E, J. Am. Chem. Soc., 60, 309, 1938
- Prakash R, Fanselau K, Ren S, Manda TK, Kube C, Hahn H, Fichtner M, J. Nanotechnol., 4, 699, 2013
- Khiew P, Ho M, Tan TK, Chiu WS, Shamsudin R, Abd-Hamid MA, Chia CH, Mater. Sci. Eng., 7, 86, 2013
- Li YW, Yang RT, J. Am. Chem. Soc., 128(25), 8136, 2006
- Zacharia R, Kim KY, Kibria AKMF, Nahm KS, Chem. Phys. Lett., 412(4-6), 369, 2005
- Im JS, Yun J, Kang SC, Lee SK, Lee YS, Appl. Surf. Sci., 258(7), 2749, 2012
- Moradi SE, Amirmahmoodi S, Baniamerian MJ, J. Alloys Compd., 498, 168, 2010
- Suh MP, Park HJ, Prasad TK, Lim DW, Chem. Rev., 112(2), 782, 2012
- Anson A, Benham M, Jagiello J, Callejas MA, Benito AM, Maser WK, Zuttel A, Sudan P, Martinez MT, Nanotechnology, 15, 1503, 2004
- Luzan S, Materials for hydrogen storage and synthesis of new materials by hydrogenation, Doctoral Thesis, Umea University, 2012
[Cited By]
참고문헌정보(참고문헌, 인용문헌)는 화학공학소재연구정보센터에 의해 제공되고 있습니다.