About The Journal
  Aims and Scope
  Editorial Board
  Submit a Manuscript 
  Subscription Information
  Guidelines for Publication
  Ethics
Articles & Issues
  Search
  Issue
  Online First
  KJChE on
For Authors
  Instructions to Authors
  Ethical Responsibilities of
  Authors in KJChE
  Ethics in Publishing
  Peer Review Process
  Author's Checklist
  Copyright Transfer Form
Contact us
 
 
 
Issue
Korean Journal of Chemical Engineering,
Vol.31, No.7, 1265-1270, 2014
Few-layered graphene oxides as superior adsorbents for the removal of Pb(II) ions from aqueous solutions
Jia W, Lu S
Few-layered graphene oxides (GOs) were successfully synthesized from graphite using Hummers’ method. The synthesized GOs were characterized in detail by SEM, AFM, XRD, and FTIR spectroscopy. The prepared GOs were used as adsorbents to preconcentrate Pb(II) ions from large volumes of aqueous solutions. The effects of pH, ionic strength and temperature on the removal of Pb(II) ions from solution to GOs were investigated. The sorption of Pb(II) on GOs was dependent on pH values and independent of ionic strength, which suggested that Pb(II) sorption on GOs was mainly dominated by strong inner-sphere surface complexation. The maximum adsorption capacities (Csmax) of Pb(II) on GOs were calculated to be 344 mg/g at 293 K, 487 mg/g at 308 K, and 758 mg/g at 333 K, respectively. The Csmax values are the highest sorption capacities of today’s materials for the sorption of Pb(II) ions from aqueous solutions. The thermodynamic parameters were calculated from the temperature-dependent sorption isotherms, and the results indicated that Pb(II) sorption on GOs was spontaneous and endothermic. The results suggested that the GOs were promising materials for the preconcentration of Pb(II) and other kinds of heavy metal ions from aqueous solutions in environmental pollution cleanup in real work.
Keywords: Graphene Oxides; Pb(II) Ions; Sorption; Thermodynamic Parameter; Interaction Mechanism
[References]
  1. Singh CK, Sahu JN, Mahalik KK, Mohanty CR, Mohan BR, Meikap BC, J. Hazard. Mater., 153(1-2), 221, 2008
  2. Xu D, Tan XL, Chen CL, Wang XK, J. Hazard. Mater., 154(1-3), 407, 2008
  3. Xu D, Tan XL, Chen CL, Wang XK, Appl. Clay Sci., 41, 37, 2008
  4. Tan X, Chang P, Fan Q, Zhou X, Yu S, Wu W, Wang X, Colloids Surf., A., 328, 8, 2008
  5. Li JF, Li YM, Lu JH, Appl. Clay Sci., 46, 314, 2009
  6. Zhang Y, Li Y, Zheng X, Sci. Total Environ., 409, 625, 2011
  7. Sheng GD, Wang SW, Hu J, Lu Y, Li JX, Dong YH, Wang XK, Colloids Surf., A., 339, 159, 2009
  8. Hu J, Shao DD, Chen CL, Sheng GD, Li JX, Wang XK, Nagatsu M, J. Phys. Chem. B, 114(20), 6779, 2010
  9. Li J, Jiang M, Wu H, Li Y, J. Agric. Food Chem., 56, 1336, 2009
  10. Shao D, Jiang Z, Wang X, Plasma Process Polym., 7, 552, 2010
  11. Li J, Li Y, Dong H, J. Agric. Food Chem., 56, 1336, 2008
  12. Fan QH, Tan XL, Li JX, Wang XK, Wu WS, Montavon G, Environ. Sci. Technol., 43, 5776, 2009
  13. Zhang Y, Li Y, Li J, Sheng G, Zhang Y, Zheng X, Chem. Eng. J., 185-186, 243, 2012
  14. Chen C, Wang X, Nagatsu M, Environ. Sci. Technol., 43, 2362, 2009
  15. Shao D, Hu J, Wang X, Plasma Process Polym., 7, 977, 2010
  16. Yang S, Hu J, Chen C, Shao D, Wang X, Environ. Sci. Technol., 45, 3621, 2011
  17. Li Y, Zhang Y, Li J, Zheng X, Environ. Pollut., 159, 3744, 2011
  18. Zhao G, Wen T, Chen C, Wang X, RSC Adv., 2, 9286, 2012
  19. Li J, Zhang S, Chen C, Yang X, Li J, Wang X, ACS Appl. Mater. Interf., 4, 4991, 2012
  20. Sun YB, Wang Q, Chen CL, Tan XL, Wang XK, Environ. Sci. Technol., 46, 6020, 2012
  21. Tung VC, Allen MJ, Yang Y, Kaner RB, Nat. Nanotechnol., 4(1), 25, 2009
  22. Mativetsky JM, Treossi E, Orgiu E, Melucci M, Veronese GP, Samori P, Palermo V, J. Am. Chem. Soc., 132(40), 14130, 2010
  23. Zhao D, Sheng G, Chen C, Wang X, Appl. Catal. B: Environ., 111-112, 303, 2012
  24. Tian L, Meziani MJ, Lu F, Kong CY, Cao L, Thorne TJ, Sun YP, ACS Appl. Mater. Interf., 2, 3217, 2010
  25. Zhang LL, Zhao SY, Tian XN, Zhao XS, Langmuir, 26(22), 17624, 2010
  26. Zhao GX, Jiang L, He YD, Li JX, Dong HL, Wang XK, Hu WP, Adv. Mater., 23(34), 3959, 2011
  27. Sun YB, Shao DD, Chen CL, Yang SB, Wang XK, Environ. Sci. Technol., 47, 9904, 2013
  28. Zhao G, Ren X, Gao X, Tan X, Li J, Chen C, Huang Y, Wang X, Dalton Trans., 40, 10945, 2011
  29. Yang X, Chen C, Li J, Zhao G, Ren X, Wang X, RSC Adv., 2, 8821, 2012
  30. Zhao G, Wen T, Yang X, Yang S, Liao J, Hu J, Shao D, Wang X, Dalton Trans., 41, 6182, 2012
  31. Sun Y, Yang S, Zhao G, Wang Q, Wang X, Chem. Asian J., 8, 2755, 2013
  32. Ren XM, Chen CL, Nagatsu M, Wang XK, Chem. Eng. J., 170(2-3), 395, 2011
  33. Lv K, Zhao G, Wang X, Chinese Sci. Bull., 57, 1223, 2012
  34. Zhang SW, Zeng MY, Xu WQ, Li JX, Li J, Xu JZ, Wang XK, Dalton Trans., 42, 7854, 2013
  35. Huang ZH, Zheng XY, Lv W, Wang M, Yang QH, Kang FY, Langmuir, 27(12), 7558, 2011
  36. Hirata M, Gotou T, Horiuchi S, Fujiwara M, Ohba M, Carbon, 42, 2929, 2004
  37. Wang Q, Wang X, Chai Z, Hu W, Chem. Soc. Rev., 42, 8821, 2013
  38. Li JX, Chen SY, Sheng GD, Hu J, Tan XL, Wang XK, Chem. Eng. J., 166(2), 551, 2011
  39. Ren XM, Shao DD, Yang ST, Hu J, Sheng GD, Tan XL, Wang XK, Chem. Eng. J., 170(1), 170, 2011
  40. Zhang L, Liang JJ, Huang Y, Ma YF, Wang Y, Chen YS, Carbon, 47, 3365, 2009
  41. Zhang L, Li X, Huang Y, Ma YF, Wan XJ, Chen YS, Carbon, 48, 2367, 2010
  42. Fan XB, Peng WC, Li Y, Li XY, Wang SL, Zhang GL, Zhang FB, Adv. Mater., 20(23), 4490, 2008
  43. McAllister MJ, Li JL, Adamson DH, Schniepp HC, Abdala AA, Liu J, Herrera-Alonso M, Milius DL, Car R, Prud'homme RK, Aksay IA, Chem. Mater., 19, 4396, 2007
  44. Meng X, Geng D, Liu J, Banis MN, Zhang Y, Li R, Sun X, J. Phys. Chem. C, 114, 18330, 2010
  45. Zhao G, Li J, Ren X, Chen C, Wang X, Environ. Sci. Technol., 45, 10454, 2011
  46. Chen CL, Hu J, Xu D, Tan XL, Meng YD, Wang XK, J. Colloid Interface Sci., 323(1), 33, 2008
  47. Dzombak DA, Morel FMM, Surface complexation modeling, Hydrous ferric Oxide, John Wiley and Sons Inc. New York, 1990
  48. Weng CH, J. Colloid Interface Sci., 272(2), 262, 2004
  49. Yang ST, Sheng GD, Tan XL, Hu J, Du JZ, Montavon G, Wang XK, Geochim. Cosmochim. Acta, 75, 6520, 2011
  50. Sheng G, Yang S, Sheng J, Hu J, Tan X, Wang X, Environ. Sci. Technol., 45, 7718, 2011
  51. Yang S, Sheng G, Montavon G, Guo Z, Tan X, Grambow B, Wang X, Geochim Cosmochim Acta, 121, 84, 2013
  52. Tan XL, Fan QH, Wang XK, Grambow B, Environ. Sci. Technol., 43, 3115, 2009
  53. Langmuir I, J. Am. Chem. Soc., 40, 1361, 1918
  54. Yang S, Zong P, Ren X, Wang Q, Wang X, ACS Appl. Mater. Interf., 4, 6891, 2012
  55. Wang Q, Li J, Song Y, Wang X, Chem. Asian J., 8, 225, 2013
  56. Wen T, Wu X, Tan X, Zhu Q, Xu A, Wang X, ACS Appl. Mater. Interf., 5, 3304, 2013
  57. Chen CL, Wang XK, Ind. Eng. Chem. Res., 45(26), 9144, 2006
  58. Rao MM, Ramana DK, Seshaiah K, Wang MC, Chien SWC, J. Hazard. Mater., 166(2-3), 1006, 2009
  59. Nassar NN, J. Hazard. Mater., 184(1-3), 538, 2010
  60. Pehlivan E, Altuna T, Cetin S, Bhanger MI, J. Hazard. Mater., 167(1-3), 1203, 2009
  61. Wang S, Dong Y, He M, Chen L, Yu X, Appl. Clay Sci., 43, 164, 2009
  62. Yang YF, Xie YL, Pang LC, Li M, Song XH, Wen JG, Zhao HY, Langmuir, 29(34), 10727, 2013
[Cited By]
  1. Li X, Li F, Fang L, Korean Journal of Chemical Engineering, 32(12), 2449, 2015
  2. Tan W, Liu Y, Liu L, Xing R, Zhu G, Korean Journal of Chemical Engineering, 33(11), 3251, 2016
  3. Abbasi F, Karimi-Sabet J, Ghotbi C, Abbasi Z, Korean Journal of Chemical Engineering, 35(5), 1174, 2018
참고문헌정보(참고문헌, 인용문헌)는 화학공학소재연구정보센터에 의해 제공되고 있습니다.