Issue
Korean Journal of Chemical Engineering,
Vol.31, No.5, 780-784, 2014
Kinetic model of low temperature coal tar hydrocracking in supercritical gasoline for reducing coke production
To reduce coke production during low temperature coal tar hydrocracking in supercritical gasoline, a lump kinetic model was derived on the basis of catalytic cracking reaction mechanism. Lumps were defined by different reaction properties. Reaction rate constants, indexes of hydrogen to coal tar ratio, indexes of gasoline to coal tar ratio, activation energies, and pre-exponential factors were estimated according to the previous experimental data. The results show that the proposed model could not only predict the product yields successfully, but also provide more information which was useful for any attempts to reduce the coke content and promote the conversion of coal tar to light oils.
[References]
  1. Kan T, Wang HY, He HX, Li CS, Zhang SJ, Fuel, 90(11), 3404, 2011
  2. Shi ZJ, Fang MX, Zhou CG, Wang SR, Luo ZY, Adv. Mater. Res., 673, 347, 2012
  3. Liu Y, Bai F, Zhu CC, Yuan PQ, Cheng ZM, Yuan WK, Fuel Process. Technol., 106, 281, 2013
  4. Long J, Shen BX, Ling H, Zhao JG, Lu JC, Ind. Eng. Chem. Res., 50(19), 11259, 2011
  5. Han LN, Zhang R, Bi JC, J. Anal. Appl. Pyrol., 91, 281, 2011
  6. Dou BL, Pan WG, Ren JX, Chen BB, Hwang JH, Yu TU, Energy Conv. Manag., 49(8), 2247, 2008
  7. Yang J, Wang XG, Li L, Shen K, Lu XG, Ding WZ, Appl. Catal. B: Environ., 96(1-2), 232, 2010
  8. Han LN, Zhang R, Bi JC, Fuel Process. Technol., 90(2), 292, 2009
  9. Ma CX, Zhang R, Bi JC, J. Fuel Chem. Technol. (Chin), 31, 401, 2003
  10. Wang SX. Petroleum refinery engineering (in Chinese), Petroleum Industry Press, Beijing, 1988
  11. Gu ZL, Chang N, Hou XP, Wang JP, Liu ZK, Fuel, 91(1), 33, 2012
  12. Chang N, Gu ZL, Wang ZS, Liu ZK, Hou XP, Wang JP, J. Porous Mater., 18, 589, 2010
  13. van den Hark S, Harrod M, Ind. Eng. Chem. Res., 40(23), 5052, 2001
  14. Hitzler MG, Smail FR, Ross SK, Poliakoff M, Org. Process. Res. Dev., 2, 137, 1998