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Issue
Korean Journal of Chemical Engineering,
Vol.31, No.2, 253-261, 2014
Effect of pH, ionic strength, foreign ions, humic acid and temperature on Zn(II) sorption onto γ-Al2O3
Xiao J, Zhao L, Zhang W, Liu X, Chen Y
The sorption of Zn(II) on γ-alumina was investigated as a function of contact time, pH, ionic strength, foreign ions, solid amount, humic acid (HA) and temperature by using batch technique. The results indicated that the sorption of Zn(II) onto γ-alumina was strongly dependent on pH and ionic strength. The sorption of Zn(II) increased slowly with increasing pH at pH 2-5, then increased sharply with pH increasing from 5 to 8.5, and at last maintained a maximum value at pH>8.5. A positive effect of HA on Zn(II) sorption was found at pH<7, whereas a negative effect was observed at pH>7. The thermodynamic data (ΔG°, ΔS°, ΔH°) were calculated from the temperature-dependent sorption isotherms, and the results suggested that the sorption of Zn(II) on γ-alumina was endothermic and spontaneous. The sorption results revealed that the γ-alumina can be as a cost-effective sorbent for pre-concentration of Zn(II) from large volumes of aqueous solutions in environmental pollution cleanup.
Keywords: Zn(II); γ-Alumina; Sorption; pH; Humic Acid; Thermodynamic Data
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[Cited By]
  1. Liu Z, Yang J, Li C, Li J, Jiang Y, Dong Y, Li Y, Korean Chemical Engineering Research, 52(6), 781, 2014
  2. Chen X, Wang J, Wang S, Ma F, Chen X, Li J, Korean Journal of Chemical Engineering, 32(11), 2264, 2015
  3. Chitan M, Hosseini SA, Salari D, Niaei A, Mehrizadeh H, Korean Journal of Chemical Engineering, 34(1), 66, 2017
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