About The Journal
  Aims and Scope
  Editorial Board
  Submit a Manuscript 
  Subscription Information
  Guidelines for Publication
  Ethics
Articles & Issues
  Search
  Issue
  Online First
  KJChE on
For Authors
  Instructions to Authors
  Ethical Responsibilities of
  Authors in KJChE
  Ethics in Publishing
  Peer Review Process
  Author's Checklist
  Copyright Transfer Form
Contact us
 
 
 
Issue
Korean Journal of Chemical Engineering,
Vol.30, No.11, 2078-2087, 2013
Preparation and characterization of L-phenylalanine-derivatized β-cyclodextrin-bonded silica and its application on chiral separation of alanine acid racemates
He K, Qiu F, Qin J, Yan J, Yang D
A chiral adsorption material, L-phenylalanine-derivatized β-cyclodextrin-bonded silica (L-Phe-CD/SiO2), was prepared and characterized by Fourier transform infrared (FT-IR), elemental analysis, field emission scanning electron microscope (FESEM), differential scanning calorimetry (DSC) and thermogravimetric analysis (TG) measurements. Langmuir and Freundlich isotherm models were employed to simulate the equilibrium data. The results showed that the equilibrium data were well represented by Langmuir isotherm model. Experimental data were analyzed using pseudofirst order and pseudo-second order kinetic models and the obtained results indicated that kinetics followed a pseudosecond order equation. The static adsorption experiments indicated that L-Phe-CD/SiO2 had significantly higher adsorption capacity for L-alanine (L-Ala) compared with D-alanine (D-Ala); and the selectivity coefficient is 2.53. The result shows that the prepared L-Phe-CD/SiO2 could be applied to chiral separation of the racemic alanine acid solution.
Keywords: β-Cyclodextrin; Chiral Separation; Adsorption Isotherm; Kinetic Model; Thermodynamics Parameters
[References]
  1. Ghosh S, Badruddoza AZM, Uddin MS, Hidajat K, J. Colloid Interface Sci., 354(2), 483, 2011
  2. Horiike K, Ishida T, Tanaka H, Arai R, J. Mol. Catal. B-Enzym., 12, 37, 2001
  3. Liu X, Meng L, Korean J. Chem. Eng., 30(4), 918, 2013
  4. Shin JA, Lim YG, Lee KH, J. Org. Chem., 77, 4117, 2012
  5. Stephany O, Tisse S, Coadou G, Bouillon JP, Peulon-Agasse V, Cardinael P, J. Chromatogr. A., 1270, 254, 2012
  6. Feng YQ, Xie MJ, Da SL, Anal. Chim. Acta., 403, 187, 2000
  7. Shah N, Ha JH, Ul-Islam M, Park JK, Korean J. Chem. Eng., 28(9), 1936, 2011
  8. Vozka J, Kalikova K, Janeckova L, Armstrong DW, Tesarova E, Anal. Lett., 45, 2344, 2012
  9. Kenjiro H, Keiko T, Masahito M, Hideo W, J. Chromatogr.A., 355, 383, 1986
  10. Liu Y, Han BH, Li B, Zhang YM, Zhao P, Chen YT, Wada T, Inoue Y, J. Org. Chem., 63, 1444, 1998
  11. Liu Y, Han BH, Sun SX, Wada T, Inoue Y, J. Org. Chem., 64, 1487, 1999
  12. Wang SY, Dai Y, Wu JH, Zhou J, Tang J, Tang WH, J.Chromatogr. A., 1277, 84, 2013
  13. Paik P, Mastai Y, Kityk I, Rakus P, Gedanken A, J. Solid. State.Chem., 192, 127, 2012
  14. Paik P, Gedanken A, Mastai Y, Micropor. Mesopor. Mater., 129, 82, 2010
  15. Paik P, Gedanken A, Mastai Y, ACS Appl. Mater. Int., 1, 1834, 2009
  16. Paik P, Gedanken A, Mastai Y, J. Mater. Chem., 20, 4085, 2010
  17. Kaveh A, Behdad GA, Amirhossein HAK, J. Inorg. Mater., 27, 660, 2012
  18. Wang SB, Ng CW, Wang WT, Li Q, Li LQ, J. Chem. Eng. Data, 57(5), 1563, 2012
  19. Breslow R, Czarniecki MF, Emert J, Hamaguchi H, J. Am.Chem. Soc., 102, 762, 1980
  20. Pan JM, Zou XH, Wang X, Guan W, Yan YS, Han JA, Chem. Eng. J., 162(3), 910, 2010
  21. Guo JF, Gao BJ, Acta Polym. Sinica., 1, 47, 2012
  22. Fujimura K, Ueda T, Ando T, Anal. Chem., 55, 446, 1983
  23. Crini G, Morin N, Morcellet M, J. Chromatogr. Sci., 37, 121, 1999
  24. Crini G, Morcellet M, Torri G, J. Chromatogr. Sci., 34, 477, 1996
  25. Crini G, Morcellet M, J. Chromatogr. Sci., 34, 485, 1996
  26. Crini G, Lekchiri Y, Morcellet M, Chromatographia., 40, 296, 1995
  27. Ho YS, McKay G, Water Res., 33, 578, 1999
  28. Ho YS, McKay G, Process Biochem., 34(5), 451, 1999
  29. Mazzotti M, J. Chromatogr. A., 1126, 311, 2006
  30. Allen SJ, Mckay G, Porter JF, J. Colloid Interface Sci., 280(2), 322, 2004
  31. Fytianos K, Voudrias E, Kokkalis E, Chemosphere., 40, 3, 2000
  32. Li KL, Wang XH, Bioresour. Technol., 100(11), 2810, 2009
[Cited By]
  1. Ingole PG, Ingole NP, Korean Journal of Chemical Engineering, 31(12), 2109, 2014
참고문헌정보(참고문헌, 인용문헌)는 화학공학소재연구정보센터에 의해 제공되고 있습니다.