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Issue
Korean Journal of Chemical Engineering,
Vol.30, No.9, 1667-1680, 2013
Synthesis of metal-organic frameworks: A mini review
Lee YR, Kim J, Ahn WS
Metal organic frameworks (MOFs) are porous crystalline materials of one-, two-, or three-dimensional networks constructed from metal ions/clusters and multidentate organic linkers via coordination bonding, which are emerging as an important group of materials for energy storage, CO2 adsorption, alkane/alkene separation, and catalysis. To introduce newcomers in chemical engineering discipline to the rapidly expanding MOF research works, this review presents a brief introduction to the currently available MOFs synthesis methods. Starting from the conventional solvothermal/hydrothermal synthesis, microwave-assisted, sonochemical, electrochemical, mechanochemical, ionothermal, drygel conversion, and microfluidic synthesis methods will be presented. Examples will be limited to those representative MOF structures that can be synthesized using common organic ligands of 1,4-benzenedicarboxylic acid (and its functionalized forms) and 1,3,5-benzenetricarboxylic acid, in conjunction with metal nodes of Zn2+, Cu2+, Cr3+, Al3+, Fe3+ and Zr4+. Synthesis of widely-investigated zeolitic imidazolate framework (ZIF) structure, ZIF-8 is also included.
Keywords: Metal Organic Frameworks (MOFs); Zeolitic Imidazolate Frameworks (ZIFs); Solvothermal/Hydrothermal Synthesis; Microwave; Sonochemistry; Electrochemical Synthesis; Mechanochemical Synthesis
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  3. Swain SS, Unnikrishnan L, Mohanty S, Nayak SK, Korean Journal of Chemical Engineering, 34(8), 2119, 2017
  4. Kim RK, Jee SH, Ryu UJ, Lee HS, Kim SY, Choi KM, Korean Journal of Chemical Engineering, 36(6), 975, 2019
  5. Gaikwad S, Kim SJ, Han SI, Journal of Industrial and Engineering Chemistry, 87, 250, 2020
  6. Jun HW, Kim SB, Lee JW, Korean Journal of Chemical Engineering, 37(8), 1317, 2020
  7. Yu KS, Won DI, Lee WI, Ahn WS, Korean Journal of Chemical Engineering, 38(4), 653, 2021
  8. Çopur M, Pekdemir T, Kocakerim MM, Korucu H, Guliyev R, Korean Journal of Chemical Engineering, 39(10), 2600, 2022
  9. Ahmadi M, Ebrahimnia M, Shahbazi MA, Keçili R, Ghorbani-Bidkorbeh F, Journal of Industrial and Engineering Chemistry, 115, 1, 2022
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