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Issue
Korean Journal of Chemical Engineering,
Vol.30, No.8, 1609-1613, 2013
Synthesis and characterization of acrylate copolymer containing fluorescein functional group
Hui G, Huang W, Song Y, Chen D, Zhong A
We report a novel method to fabricate fluorescent polymer (F-CPA) based on the esterification between acrylate copolymer (CPA) and fluorescein using N, N-dicyclohexylcarbodiimide (DCC)/4-dimethylaminopyridine (DMAP) as catalyst. The resulting copolymer was characterized by Fourier transform-infrared spectroscopy (FT-IR), gel permeation chromatography (GPC), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), ultravioletvisible spectroscopy (UV-Vis) and fluorescence spectroscopy. In addition, the influences of concentration, solvents, pH and metal cations (Cu2+, Fe3+ and Zn2+) on the fluorescent behaviors of F-CPA are discussed in detail. All those observations suggest that the synthesized F-CPA is an excellent luminescent macromolecular material with simple synthesis method and excellent solubility. Moreover, its sensitive fluorescence response behaviors to solvents, pH and metal cations make it to become a polymer-based probe.
Keywords: Fluorescein; Acrylate Copolymer; DCC/DMAP; Fluorescent Polymer; Probe
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[Cited By]
  1. Ghim D, Kim JH, Korean Journal of Chemical Engineering, 33(2), 707, 2016
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