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Issue
Korean Journal of Chemical Engineering,
Vol.30, No.8, 1636-1643, 2013
Thermodynamics of molecular interactions in binary mixtures containing associated liquids
Rani M, Maken S
Experimentally measured data of excess molar volumes and enthalpies at 308.15 K for binary mixtures of formamide with 1-butanol or 2-methyl-1-propanol were fitted to the Redlich-Kister polynomial equation. Thermodynamics of molecular interaction in these mixtures was discussed using Prigogine-Flory-Patterson theory, Treszczanowicz-Benson association model and Graph theoretical approach. Extent of inter-molecular H-bonding in formamide and butanol in their binary mixtures was also reflected in their molar enthalpy of association of H-bonding ΔhH0 and association constant KH calculated from Treszczanowicz-Benson association model. All the three theories predict the excess property data reasonably well.
Keywords: Excess Molar Enthalpy; Excess Molar Volume; Prigogine-Flory-Patterson Theory; Treszczanowicz-Benson Association Model; Graph Theoretical Approach
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[Cited By]
  1. Gahlyan S, Rani M, Lee I, Moon I, Maken SK, Korean Journal of Chemical Engineering, 32(1), 168, 2015
  2. Gahlyan S, Rani M, Maken S, Kwonc H, Tak K, Moon I, Journal of Industrial and Engineering Chemistry, 23, 299, 2015
  3. Dehghani MH, Zarei A, Mesdaghinia A, Nabizadeh R, Alimohammadi M, Afsharnia M, Korean Journal of Chemical Engineering, 34(3), 757, 2017
  4. Gahlyan S, Verma S, Rani M, Maken S, Korean Chemical Engineering Research, 55(4), 520, 2017
  5. Kashyap P, Rani M, Tiwari DP, Park SJ, Korean Chemical Engineering Research, 58(2), 257, 2020
  6. Gahlyan S, Devi R, Verma S, Rani M, Park SJ, Maken S, Korean Journal of Chemical Engineering, 37(7), 1181, 2020
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