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Issue
Korean Journal of Chemical Engineering,
Vol.30, No.3, 509-517, 2013
Selective oxidation of refractory sulfur compounds for the production of low sulfur transportation fuel
Jeong KE, Kim TW, Kim JW, Chae HJ, Kim CU, Park YK, Jeong SY
The current technologies for achieving low sulfur in diesel fuel are based on hydrotreating, which requires high temperature, high pressure and excessive supply of hydrogen. Oxidative desulfurization (ODS) is considered one of the promising new methods for super deep desulfurization, which could be carried out under very mild conditions (atmospheric pressure, <100 ℃) without consumption of hydrogen. In this paper, development status of ODS process by major licensors are described as well as general concepts of ODS reaction. In addition, the ODS process has been categorized into single phasic and biphasic system according to the oxidants involved. Recent trends in both systems are reviewed in detail and future work is also proposed.
Keywords: Oxidative Desulfurization; Refractory Sulfur Compounds; Selective Oxidation; Low Sulfur Fuel; Catalyst; Oxidant; Liquid Phase
[References]
  1. Zhang G, Yu F, Wang R, Pet. Coal., 51, 196, 2009
  2. Campos-Martin JM, Capel-Sanchez MC, Perez-Presas P, Fierro JLG, J. Chem. Technol. Biotechnol., 85(7), 879, 2010
  3. Caero LC, Oxidative desulfurization (ODS) of aromatic sulfur compounds to obtain ultra low sulfur fuels, SciTopics, 2010, http://www.scitopics.com/Oxidative_Desulfurization_ODS_of_ aromatic_sulfur_compounds_to_obtain_Ultra_Low_Sulfur_Fuels.html.
  4. Gatan R, Barger P, Gembicki V, Prepr. Pap.-Am. Chem. Soc., Div. Fuel Chem., 49, 577, 2004
  5. Song CS, Catal. Today, 86(1-4), 211, 2003
  6. Babich IV, Moulijn JA, Fuel, 82(6), 607, 2003
  7. Pawelec B, Navarro RM, Campos-Martin JM, Fierro JLG, Catal. Sci. Technol., 1, 23, 2011
  8. Song C, Ma XL, Appl. Catal. B: Environ., 41(1-2), 207, 2003
  9. Song C, Ma X, Int. J. Green Energy., 1, 167, 2004
  10. Kim TW, Kim MJ, Kleitz F, Nair MM, Guillet-Nicolas R, Jeong KE, Chae HJ, Kim CU, Jeong SY, ChemCatChem., 4, 687, 2012
  11. Ma XL, Sakanishi KY, Mochida I, Ind. Eng. Chem. Res., 33(2), 218, 1994
  12. Otsuki S, Nonaka T, Takashima N, Qian WH, Ishihara A, Imai T, Kabe T, Energy Fuels, 14(6), 1232, 2000
  13. Gonzalez-Garcia O, Cedeno-Caero L, Catal. Today, 148(1-2), 42, 2009
  14. Zhang J, Bai X, Li X, Wang A, Ma X, Chinese J. Catal., 30, 1017, 2009
  15. Takahashi A, Yang FH, Yang RT, Ind. Eng. Chem. Res., 41(10), 2487, 2002
  16. Hernndez-Maldonado AJ, Yang RT, Ind. Eng. Chem. Res., 42, 123, 2002
  17. Wang DH, Qian EWH, Amano H, Okata K, Ishihara A, Kabe T, Appl. Catal. A: Gen., 253(1), 91, 2003
  18. Chapados D, Bonde SE, Gore WL, Dolbear G, Skov E, AM-00-25, NPRA 2000 Annual Meeting, 2010
  19. Levy RE, Rappas AS, DeCanio SJ, Nero VP, AM-01-10, NPRA 2001 Annual Meeting, 2001
  20. Cullen M, Avidan A, AM-01-55, NPRA 2001 Annual Meeting, 2001
  21. Liotta F, Han Y, AM-03-23, NPRA 2003 Annual Meeting, 2003
  22. Key RD, Ackerson MD, Byars MS, Laurent J, Hallock J, AM-03-11, NPRA 2003 Annual Meeting, 2003
  23. Tuli D, 19th World Petroleum Congress, June 29 - July 3, Madrid, Spain, 2008
  24. Campos-Martin JM, Blanco-Brieva G, Fierro JLG, Angew.Chem., Int. Ed., 45, 6962, 2006
  25. ZANNIKOS F, LOIS E, STOURNAS S, Fuel Process. Technol., 42(1), 35, 1995
  26. Shiraishi Y, Tachibana K, Hirai T, Komasawa I, Ind. Eng. Chem. Res., 41(17), 4362, 2002
  27. De Filippis P, Scarsella M, Energy Fuels, 17(6), 1452, 2003
  28. Ali SH, Hamad DM, Albusairi BH, Fahim MA, Energy Fuels., 23, 5986, 2009
  29. Shiraishi Y, Hara H, Hirai T, Komasawa I, Ind. Eng. Chem. Res., 38(4), 1589, 1999
  30. Hirai T, Shiraishi Y, Ogawa K, Komasawa I, Ind. Eng. Chem. Res., 36(3), 530, 1997
  31. Yazu K, Furuya T, Miki K, Ukegawa K, Chem. Lett., 32(10), 920, 2003
  32. Al-Shahrani F, Xiao TC, Llewellyn SA, Barri S, Jiang Z, Shi HH, Martinie G, Green MLH, Appl. Catal. B: Environ., 73(3-4), 311, 2007
  33. Hao L, Benxian S, Zhou X, Pet. Sci. Technol., 23, 991, 2005
  34. Chen LJ, Guo SH, Zhao DS, Chin. J. Chem. Eng., 15(4), 520, 2007
  35. de Souza WF, Guimaraes LR, Guerreiro MC, Oliveira LCA, Appl. Catal. A: Gen., 360(2), 205, 2009
  36. Yu G, Lu S, Chen H, Zhu Z, Carbon., 43, 2285, 2005
  37. Yu G, Lu S, Chen H, Zhu Z, Energy Fuels., 19, 447, 2004
  38. Zhou XL, Tan Q, Yu GX, Chen LF, Wang JA, Novaro O, Kinet. Catal., 50, 543, 2009
  39. Borah D, Baruah MK, Haque I, Fuel., 80, 1475, 2001
  40. Te M, Fairbridge C, Ring Z, Appl. Catal. A: Gen., 219(1-2), 267, 2001
  41. Yazu K, Yamamoto Y, Furuya T, Miki K, Ukegawa K, Energy Fuels, 15(6), 1535, 2001
  42. Wang R, Zhang GF, Zhao HX, Catal. Today, 149(1-2), 117, 2010
  43. Mondal S, Hangun-Balkir Y, Alexandrova L, Link D, Howard B, Zandhuis P, Cugini A, Horwitz CP, Collins TJ, Catal. Today, 116(4), 554, 2006
  44. Lai J, Luo G, Pet. Sci. Technol., 24, 1357, 2006
  45. Shen J, Li HP, Zhao H, Pet. Sci. Technol., 26, 2182, 2008
  46. Jiang X, Li HM, Zhu WS, He LN, Shu HM, Lu JD, Fuel, 88(3), 431, 2009
  47. Huang D, Zhai Z, Lu YC, Yang LM, Luo GS, Ind. Eng. Chem. Res., 46(5), 1447, 2007
  48. Komintarachat C, Trakarnpruk W, Ind. Eng. Chem. Res., 45(6), 1853, 2006
  49. Mei H, Mei BW, Yen TF, Fuel, 82(4), 405, 2003
  50. Huang D, Wang YJ, Yang LM, Luo GS, Ind. Eng. Chem. Res., 45(6), 1880, 2006
  51. Etemadi O, Yen TF, Energy Fuels, 21(4), 2250, 2007
  52. Campos-Martin JM, Capel-Sanchez MC, Fierro JLG, Green Chem., 6, 557, 2004
  53. Lu HY, Gao JB, Jiang ZX, Jing F, Yano YX, Wang G, Li C, J. Catal., 239(2), 369, 2006
  54. Huang D, Lu YC, Wang YJ, Yang L, Luo GS, Ind. Eng. Chem. Res., 47(11), 3870, 2008
  55. Li C, Jiang Z, Gao J, Yang Y, Wang S, Tian F, Sun F, Sun X, Ying P, Han C, Chem.-A Eur. J., 10, 2277, 2004
  56. Chica A, Corma A, Domine ME, J. Catal., 242(2), 299, 2006
  57. Liu D, Gui J, Park YK, Yang S, Gao Y, Peng X, Sun Z, Korean J. Chem. Eng., 29(1), 49, 2012
  58. Tang L, Luo G, Kang L, Zhu M, Dai B, Korean J. Chem. Eng., 30(2), 314, 2013
  59. Otsuki S, Nonaka T, Qian W, Ishihara A, Kabe T, Sekiyu Gakkaishi., 44, 18, 2001
  60. Kocal JA, Process for the desulfurization of a hydrocarbonaceous oil, UOP LLC, US Patent 6,277,271, 2001
  61. Kocal JA, Brandvold TA, Removal of sulfur-containing compounds from liquid hydrocarbon streams, UOP LLC, US Patent 6,368,495, 2002
  62. Karas LJ, Han YZ, Leyshon DW, Organosulfur oxidation process, Lyondell, US Patent 2,004,178,122, 2004
  63. Han YZ, Leyshon DW, Desulfurization process, Lyondell, US Patent 2,005,109,677, 2005
  64. Li JY, Zhou XR, Zhao DF, Zhao CX, J. Fuel Chem. Technol., 34, 249, 2006
  65. Zhou XR, Zhao CX, Yang JZ, Zhang SF, Energy Fuels, 21(1), 7, 2007
  66. Kyle EL, Jennifer LV, Oxidative desulfurization using a titanium (IV) catalyst and organohydroperoxides, US Patent 8,283,498, 2012
  67. Hulea V, Fajula F, Bousquet J, J. Catal., 198(2), 179, 2001
  68. Ishihara A, Wang DH, Dumeignil F, Amano H, Qian EWH, Kabe T, Appl. Catal. A: Gen., 279(1-2), 279, 2005
  69. Prasad VVDN, Jeong KE, Chae HJ, Kim CU, Jeong SY, Catal. Commun., 9, 1966, 2008
  70. Chica A, Gatti G, Moden B, Marchese L, Iglesia E, Chem.-A Eur. J., 12, 1960, 2006
  71. Sharipov AK, Nigmatullin VR, Chem. Tech. Fuels Oils, 41(4), 309, 2005
  72. Jeong KE, Chae HJ, Kim CU, Jeong SY, Ahn WS, Solid State Phenom., 135, 88, 2008
  73. Kim J, Bhattacharjee S, Jeong KE, Jeong SY, Ahn WS, Chem. Commun., 3904, 2009
  74. Cedeno-Caero L, Gomez-Bernal H, Fraustro-Cuevas A, Guerra-Gomez HD, Cuevas-Garcia R, Catal. Today., 133-135, 244, 2008
  75. Shiraishi Y, Hirai T, Komasawa I, Ind. Eng. Chem. Res., 37(1), 203, 1998
  76. Fang Y, Hu H, Catal. Commun., 8, 817, 2007
  77. Jeong KE, Cho CS, Chae HJ, Kim CU, Jeong SY, J.Nanosci. Nanotechnol., 10, 3547, 2010
  78. Gao G, Cheng S, An Y, Si X, Fu X, Liu Y, Zhang H, Wu P, He MY, ChemCatChem., 2, 459, 2010
  79. Song H, Li G, Wang X, Micropor. Mesopor. Mater., 120, 346, 2009
  80. Kong LY, Li G, Wang XS, Catal. Today, 93-95, 341, 2004
  81. Capel-Sanchez MC, Campos-Martin JM, Fierro JLG, Energ. Environ. Sci., 3, 328, 2010
  82. Yang ST, Jeong KE, Jeong SY, Ahn WS, Mater. Res. Bull., 47(12), 4398, 2012
  83. Wu P, Komatsu T, Yashima T, J. Phys. Chem., 100(24), 10316, 1996
  84. Diaz-Cabanas MJ, Villaescusa LA, Camblor MA, Chem.Commun., 761, 2000
  85. Cheng S, Liu Y, Gao J, Wang L, Liu X, Gao G, Wu P, He M, Chinese J. Catal., 27, 547, 2006
  86. Bal R, Chaudhari K, Srinivas D, Sivasanker S, Ratnasamy P, J. Mol. Catal. A-Chem., 162(1-2), 199, 2000
  87. Capel-Sanchez MC, Blanco-Brieva G, Campos-Martin JM, de Frutos MP, Wen W, Rodriguez JA, Fierro JLG, Langmuir, 25(12), 7148, 2009
  88. Berube F, Khadhraoui A, Janicke MT, Kleitz F, Kaliaguine S, Ind. Eng. Chem. Res., 49(15), 6977, 2010
  89. Brub F, Nohair B, Kleitz F, Kaliaguine S, Chem. Mater., 22, 1988, 2010
  90. Caero LC, Navarro JF, Gutierrez-Alejandre A, Catal. Today, 116(4), 562, 2006
  91. Shephard DS, Zhou W, Maschmeyer T, Matters JM, Roper CL, Parsons S, Johnson BFG, Duer MJ, Angew. Chem., Int. Ed., 37, 2719, 1998
  92. Koyano KA, Tatsumi T, Tanaka Y, Nakata S, J. Phys. Chem. B, 101(46), 9436, 1997
  93. Subba Rao YV, De Vos DE, Bein T, Jacobs PA, Chem.Commun., 355, 1997
  94. Sutra P, Brunel D, Chem. Commun., 2485, 1996
  95. Li XF, Gao HX, Jin GJ, Chen L, Ding L, Yang HY, Chen QL, J. Mol. Struct., 872, 10, 2008
  96. Anwander R, Nagl I, Widenmeyer M, Engelhardt G, Groeger O, Palm C, Roser T, J. Phys. Chem. B, 104(15), 3532, 2000
  97. Kim TW, Jeong KE, Chae HJ, Kim CU, Jeong SY, Kim GR, Oh SH, Ryu JW, Kim DW, Kim YW, KR Patent 0-2010-0089590, 2010
  98. Cho CS, Jeong KE, Chae HJ, Kim CU, Jeong SY, Oh SG, Korean Chem. Eng. Res., 46(5), 845, 2008
[Cited By]
  1. Liu M, Zhang LZ, Zhang C, Yuan SH, Zhao DZ, Duan LH, Korean Journal of Chemical Engineering, 35(2), 375, 2018
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