About The Journal
  Aims and Scope
  Editorial Board
  Submit a Manuscript 
  Subscription Information
  Guidelines for Publication
  Ethics
Articles & Issues
  Search
  Issue
  Online First
  KJChE on
For Authors
  Instructions to Authors
  Ethical Responsibilities of
  Authors in KJChE
  Ethics in Publishing
  Peer Review Process
  Author's Checklist
  Copyright Transfer Form
Contact us
 
 
 
Issue
Korean Journal of Chemical Engineering,
Vol.30, No.2, 488-493, 2013
Synthesis and characterization of waterborne polyurethane acrylate copolymers
Sultan M, Bhatti HN, Zuber M, Barikani M
Polyurethane acrylate copolymers were synthesized by emulsion polymerization process. To reduce the environmental hazards, organic solvents were replaced by eco-friendly aqueous system. Concentration of polyurethane and acrylate monomer was varied to investigate the effect of chemical composition on performance properties of copolymers. FTIR spectroscopy was used as a key tool to record the chemical synthesis route. The synthesized copolymer emulsions were characterized by evaluating their particle size, viscosity, dry weight content, chemical and water resistance. Thermal decomposition was studied by thermogravimetric analysis. Scanning electron microscope was used to visualize the morphological structure of copolymers. The experimental results indicate better polyurethane acrylate compatibility till the ratio of 30/70. However, these copolymers exhibited synergistic effects between the two polymers and revealed a remarkable improvement in numerous coating properties.
Keywords: Polyurethane; Acrylate; Emulsion Polymerization; Copolymers; Eco-friendly; Coating
[References]
  1. Rahman MM, Kim EY, Kwon JY, Yoo HJ, Kim HD, Int. J. Adhes. Adhes., 28, 47, 2008
  2. Kim B, Shin J, Colloid. Polym. Sci., 280, 716, 2002
  3. Zhu X, Jiang X, Zhang Z, Kong XZ, Prog. Org. Coat., 62, 251, 2008
  4. Aznar AC, Pardini OR, Amalvy JI, Prog. Org. Coat., 55, 43, 2006
  5. Chai SL, Jin MM, Tan HM, Eur. Polym. J., 44, 3306, 2008
  6. Oprea S, Vlad S, Stanciu A, Eur. Polym. J., 36, 2409, 2000
  7. Kim IH, Shin JS, Cheong IW, Kim JI, Kim JH, Colloids Surf., 207, 169, 2002
  8. Kukanja D, Golob J, Krajnc M, J. Appl. Polym. Sci., 84(14), 2639, 2002
  9. Sebenik U, Krajnc M, Colloids Surf., 233, 51, 2004
  10. Sebenik U, Golob J, Krajnc M, Polym. Int., 52, 740, 2003
  11. Wu LM, You B, Li D, J. Appl. Polym. Sci., 84(8), 1620, 2002
  12. Wu L, Yu H, Yan J, You B, Polym. Int., 50, 1288, 2001
  13. Huang Y, Ding S, Yang K, Chwang C, Chao D, J. Coat. Technol., 69, 69, 1997
  14. Jan YH, Hwang YT, Shih CY, Li HC, Waterborne High-Solids and Powder Symposium New Orleans U.S.A., 211, 1995
  15. Athawale VD, Kulkarni MA, Prog. Org. Coat., 65, 392, 2009
  16. Kim BK, Lee JC, J. Appl. Polym. Sci., 58(7), 1117, 1995
  17. Kim JY, Suh KD, Polym. Sci., 274, 920, 1996
  18. Sultan M, Bhatti HM, Zuber M, Bhatti IA, Sheikh MA, Carbohyd. Poly., 86, 928, 2011
  19. Sultan M, Zia KM, Bhatti HN, Jamil T, Hussain R, Zuber M, Carbohyd. Poly., 87, 397, 2012
  20. Barikani M, Hepburn C, Cell. Polym., 5, 169, 1986
  21. Wang F, Hu JQ, Tu WP, Prog. Org. Coat., 62, 245, 2008
  22. Zhang T, Wu W, Wang X, Mu Y, Prog. Org. Coat., 68, 201, 2010
  23. Guo A, Cho YJ, Petrovic ZS, J. Polym. Sci. A: Polym. Chem., 38(21), 3900, 2000
  24. Javni I, Petrovic ZS, Guo A, Fuller R, J. Appl. Polym. Sci., 77(8), 1723, 2000
[Cited By]
  1. Huh WY, Yun DG, Song KC, Korean Chemical Engineering Research, 52(4), 451, 2014
  2. Honarkar H, Barmar M, Barikani M, Shokrollahi P, Korean Journal of Chemical Engineering, 33(1), 319, 2016
  3. Ghim D, Kim JH, Korean Journal of Chemical Engineering, 33(2), 707, 2016
  4. Maurya SD, Kurmvanshi SK, Mohanty S, Nayak SK, Macromolecular Research, 25(9), 871, 2017
참고문헌정보(참고문헌, 인용문헌)는 화학공학소재연구정보센터에 의해 제공되고 있습니다.