Korean Journal of Chemical Engineering, Vol.27, No.6, 1689-1694, 2010
Enhancement of oxygen reduction activity by sequential impregnation of Pt and Pd on carbon support
Two Pd-based PtPd bimetallic catalysts (mole ratio of Pt to Pd=1 : 18) were prepared by co-impregnation (Pt-Pd/C) and sequential impregnation of Pt on Pd/C [Pt(Pd/C)] for the application to oxygen reduction reaction (ORR). The prepared bimetallic catalysts had lower ORR activities than Pt/C, while they showed largely enhanced activity compared to Pd/C. In particular, the extent of enhancement was found to be dependent on the surface composition. The observed mass and specific activities of Pt(Pd/C) were more than two times higher than those of Pt-Pd/
C. The superior activity of Pt(Pd/C) observed from the performed studies was attributed to its Pt-rich surface.
[References]
Steele BCH, Heninzel A, Nature , 414 , 345, 2001
Joh HI, Seo SJ, Kim HT, Moon SH, Korean J. Chem. Eng. , 27 (1), 45, 2010
Stamenkovic VR, Fowley B, Mun BS, Wang G, Ross PN, Lucas CA, Markovic NM, Sci. , 315 , 493, 2007
Fuerte A, Corma A, Iglesias M, Morales E, Sanchez F, Catal. Lett. , 101 (1-2), 99, 2005
Bashyam R, Zelenay P, Nature , 443 , 63, 2006
Shao YY, Sui JH, Yin GP, Gao YZ, Appl. Catal. B: Environ. , 79 (1-2), 89, 2008
Tanaka K, Shou M, He H, Zhang CB, Lu DL, Catal. Lett. , 127 (1-2), 148, 2009
Joo JB, Kim YJ, Kim W, Kim ND, Kim P, Kim Y, Lee YW, Yi J, Korean J. Chem. Eng. , 25 (3), 431, 2008
Wakabayashi N, Takeichi M, Uchida H, Watanabe M, J. Phys. Chem. B , 109 (12), 5836, 2005
Shim J, Lee CR, Lee HK, Lee JS, Cairns EJ, J. Power Sources , 102 (1-2), 172, 2001
Mani P, Srivastava R, Strasser P, J. Phys. Chem. C , 112 , 2770, 2008
Toda T, Igarashi H, Uchida H, Watanabe M, J. Electrochem. Soc. , 146 (10), 3750, 1999
Choi JH, Noh SY, Han SD, Yoon SK, Lee CS, Hwang TS, Rhee YW, Korean J. Chem. Eng. , 25 (5), 1026, 2008
Zhang JL, Vukmirovic MB, Sasaki K, Nilekar AU, Mavrikakis M, Adzic RR, J. Am. Chem. Soc. , 127 (36), 12480, 2005
Wang W, Huang Q, Liu J, Zou Z, Li Z, Yang H, Electrochemistry Communications , 10 , 1396, 2008
Joo JB, Kim YJ, Kim W, Kim ND, Kim P, Kim Y, Yi J, Korean J. Chem. Eng. , 25 (4), 770, 2008
Arico AS, Shukla AK, Kim H, Park S, Min M, Antonucci V, Appl. Surf. Sci. , 172 (1-2), 33, 2001
Prabhuram J, Wang X, Hui CL, Hsing IM, J. Phys. Chem. B , 107 (40), 11057, 2003
Bard AJ, Parsons R, Jordan J, Standard potential in aqueous solution, Marcel Dekker, New York, 1985
Grden M, Lukaszewski M, Jerkiewicz G, Czerwinski A, Electrochim. Acta , 53 (26), 7583, 2008
Liu H, Manthiram A, Electrochemistry Communications , 10 , 740, 2008
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