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Korean Journal of Chemical Engineering, Vol.24, No.2, 226-232, 2007
Optimal conditions for partial oxidation of propane over ceria-promoted nickel/calcium hydroxyapatite
.In order to produce hydrogen for application to fuel cells, the optimal conditions for partial oxidation of propane were studied in this research. Ceria-promoted nickel-calcium hydroxyapatite catalysts (CexNi2.5Ca10(OH)2(PO4)6; x=0.1-0.3) were investigated for determination of the optimal content of ceria and ratio of O2/C3H8. With O2/C3H8=1.5 (ideal reaction), ceria-promoted catalysts did not exhibit higher hydrogen yield than the unpromoted catalyst. However, as the O2/C3H8 ratio was increased to 2.0 and higher, ceria-promoted catalysts exhibited higher hydrogen yield and lower hydrocarbon by-product selectivities. The optimal conditions were determined to be content of ceria (x) of 0.1 and O2/
C3H8 ratio of 2.0.
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[Cited By]
- Seo JG, Youn MH, Park S, Lee J, Lee SH, Lee H, Song IK, Korean Journal of Chemical Engineering, 25(1), 95, 2008
- Kwak JH, Lee SY, Nam SW, Lim TH, Hong SA, Yoon KJ, Korean Journal of Chemical Engineering, 25(6), 1309, 2008
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