|
Korean Journal of Chemical Engineering, Vol.21, No.1, 132-139, 2004
Synthesis, Characterization, and Applications of Organic-Inorganic Hybrid Mesoporous Silica
Organic-inorganic hybrid mesoporous materials composed of homogeneously distributed ethane group in a silica framework were prepared by using 1,2 bis(trimethoxysilyl) ethane (BTME) as a precursor and alkyltrimethylammonium-chloride or -bromide surfactant as a structure directing agent with or without the presence of a swelling agent, mesitylene. Characterization of the materials was performed by XRD, TEM/SEM, 29Si-/13C-solid state NMR, and N2-adsorption. Testing of the hybrid material as a reversed phase HPLC column stationary phase after C18 surfacefunctionalization demonstrated a promising result, which closely approaches the performance of a commercial product. Mn-salen complex tethering on the hybrid material produced a catalyst with somewhat enhanced performance in liquid phase etherification with tert-butyl hydroperoxide as oxidant.
[References]
- Asefa T, MacLachlan MJ, Coombs N, Ozin GA, Nature, 402, 867, 1999
- Asefa T, Kruk M, MacLachlan MJ, Coombs N, Grondey H, Jaroniec M, Ozin GA, J. Am. Chem. Soc., 123(35), 8520, 2001
- Asefa T, Ozin GA, Grondey H, Kruk M, Jaroniec M, Stud. Surf. Sci. Catal., 141, 1, 2002
- Boissiere A, Larbot A, Prouzet E, Stud. Surf. Sci. Catal., 129, 31, 2000
- Bruzzoniti MC, Mentasti E, Sarzanini C, Onida B, Bonelli B, Garrone E, Anal. Chim. Acta, 422, 231, 2000
- Burleigh MC, Markowitz MA, Wong EM, Lin Js, Gaber BP, Chem. Mater., 13, 4411, 2001
- Cauvel A, Renard G, Brunel D, J. Org. Chem., 62, 749, 1997
- Cheong WJ, Lee CS, An HJ, Bull. Korean Chem. Soc., 18, 1036, 1997
- Choudary BM, Kantam ML, Bharathi B, Sreekanth P, Figueras F, J. Mol. Catal. A-Chem., 159, 417, 2000
- Diaz JF, Balkus KJ, Bedioui F, Kurshev V, Kevan L, Chem. Mater., 9, 61, 1997
- Gallis KW, Araujo JT, Duff KJ, Moore JG, Landry CC, Adv. Mater., 11, 1452, 1999
- Grun M, Kruganov AA, Schacht S, Schuth F, Unger KK, J. Chromatogr. A, 740, 1, 1996
- Guan S, Inagaki S, Ohsuna T, Terasaki O, J. Am. Chem. Soc., 122(23), 5660, 2000
- Guo W, Park JY, Oh MO, Jeong HW, Cho WJ, Kim I, Ha CS, Chem. Mater., 15, 2295, 2003
- Inagaki S, Guan S, Fukushima Y, Ohsuna T, Terasaki O, J. Am. Chem. Soc., 121(41), 9611, 1999
- Kang T, Park Y, Park JC, Cho YS, Yi J, Korean J. Chem. Eng., 19(4), 685, 2002
- Kim GJ, Park DW, Ha JM, Korean J. Chem. Eng., 17(3), 337, 2000
- Kisler JM, Dahler A, Stevens GW, O'Connor AJ, Microporous Mesoporous Mater., 44-45, 769, 2001
- Kresge CT, Leonowicz ME, Roth WJ, Vartuli JC, Beck JS, Nature, 359, 710, 1992
- Lindlar B, Kogelbauer A, Kooyman PJ, Prins R, Microporous Mesoporous Mater., 44-45, 89, 2001
- Liu J, Feng X, Fryxell GE, Wang LQ, Kim AY, Adv. Mater., 10, 161, 1998
- Lu YF, Fan HY, Doke N, Loy DA, Assink RA, LaVan DA, Brinker CJ, J. Am. Chem. Soc., 122(22), 5258, 2000
- Macquarrie DJ, Chem. Commun., 1961, 1996
- Melde BJ, Holland BT, Blanford CF, Stein A, Chem. Mater., 11, 3302, 1999
- Moller K, Bein T, Fisher RX, Chem. Mater., 11, 665, 1999
- Schroden RC, Blanford CF, Melde BJ, Johnson BJS, Stein A, Chem. Mater., 13, 1074, 2001
- Tolbert SH, Landry CC, Stucky GD, Chmelka BF, Norby P, Hanson JC, Monnier A, Chem. Mater., 13, 2247, 2001
- VanRhijn WM, Devos DE, Sels BF, Bossaert WD, Jacobs PA, Chem. Commun., 317, 1998
- Yamamoto K, Nohara Y, Tatsumi T, Chem. Lett., 648, 2001
- Yoshina-Ishii C, Asefa T, Coombs N, MacLachlan MJ, Ozin GA, Chem. Commun., 2539, 1999
- Zhu H, Jones DJ, Zajac J, Dutartre R, Rhomari M, Roziere J, Chem. Mater., 14, 4886, 2002
[Cited By]
- Song MG, Kim JY, Cho SH, Kim JD, Korean Journal of Chemical Engineering, 21(6), 1224, 2004
- Baek CM, Jung KY, Park KY, Park SB, Cho SB, Korean Chemical Engineering Research, 46(5), 880, 2008
- Lee S, Oh KK, Park S, Kim JS, Kim H, Korean Journal of Chemical Engineering, 26(6), 1550, 2009
- Park YK, Kim SY, Kim HJ, Jung KY, Jeong KE, Jeong SY, Jeon JK, Korean Journal of Chemical Engineering, 27(2), 459, 2010
- Song SK, Kim JH, Hwang KS, Ha KR, Korean Chemical Engineering Research, 49(2), 181, 2011
- Ryu HS, Lee YS, Lee JC, Ha K, Polymer(Korea), 37(3), 308, 2013
|