Korean Journal of Chemical Engineering, Vol.38, No.11, 2365-2374, 2021
Industrial by-product utilized synthesis of mesoporous aluminum silicate sorbent for thorium removal
Recently, there has been an increasing concern in finding sorbents for radionuclide removal from natural sources. AS-BFS sorbent (aluminum silicate composites derived from blast furnace slag) is a suitable candidate for this purpose; due to economic and environmental reasons. Blast furnace slag (BFS) is a by-product of the iron and steel industry plants. The development of a cost-effective route for recycling and utilization assessment of BFS is an urgent task. AS-BFS was prepared from BFS and its physicochemical properties were determined. The elemental composition of the AS-BFS is mainly oxygen (44%), Si (34%), and Al (19%), with traces of titanium, iron, chloride, and calcium. Experimental potentiality regarding sorption characteristics of AS-BFS to thorium ions was explored via the batch method. AS-BFS showed good adsorption capacity for thorium (obtained after 240 min) from aqueous streams (39.7 mg/g). The sorption process is fitted to the mono-layer adsorption model at optimum conditions. It was also proved that adsorption kinetics follows the pseudo-second-order model. The desorption results revealed that thorium ions (93%) could be eluted using 1M HNO3. Hence, the research work indicates that the thorium sorption method with AS-BFS is cost-effective, efficient, and recommended for thorium removal from natural sources.
[References]
Lancmuir D, Herman JS, Geochim. Cosmochim. Acta , 44 , 1753, 1980
Dill HGA, Arab. J. Geosci. , 4 , 123, 2011
Vertes A, Nagy S, Klencsar Z, Lovas RG, Rosch F, Handbook of nuclear chemistry, Springer US, New York, (2010).
Abd El-Magied MO, Tolba AA, El-Gendy HS, Zaki SA, Ati AA, Hydrometallurgy , 169 , 89, 2017
Habashi F, Handbook of extractive metallurgy, WILEY-VCH, Weinheim, Germany (1997).
Sadeek SA, Moussa EM, El-Sayed MA, Amine MM, Abd El-Magied MO, J. Dispersion Sci. Technol. , 35 , 926, 2014
Agency for Toxic Substances and Disease Registry (ATSDR), Public Health Service (1990).
EPA, U.S. Environmental Protection Agency, Office of Water, EPA822S12001 (2012).
FDA, U.S. Food and Drug Administration, Code of Federal Regulations 21 CFR 165.110 (2017).
Hung NT, Thuan LB, Thanh TC, et al., Hydrometallurgy , 198 , 105506, 2020
Akl ZF, Hegazy MA, J. Environ. Chem. Eng. , 8 , 104185, 2020
Yuan D, Zhang S, Tan J, Dai Y, Wang Y, He Y, Liu Y, Zhao X, Sep. Sci. Technol. , 237 , 116379, 2020
Yuan D, Zhang S, Xiang Z, He Y, Wang Y, Liu Y, Zhao X, Zhou X, Zhang Q, ACS Appl. Mater. Interfaces , 11 , 24512, 2019
Seader JD, Henley EJ, Separation process principles, John Wiley & Sons, Inc., New York (2006).
Worch E, Adsorption technology in water treatment-fundamentals, processes, and modeling, Berlin (2012).
Broujeni BR, Nilchi A, Azadi F, Environ. Nanotechnol. Monit. Manage. , 15 , 100400, 2021
Metaxas M, Kasselouri-Rigopoulou V, Galiatsatou P, Konstantopoulou C, Oikonomou D, J. Hazard. Mater. , 97 (1-3), 71, 2003
Dolatyari L, Shateri M, Yaftian MR, Rostamnia S, Sep. Sci. Technol. , 54 (17), 2863, 2019
Dousti Z, Dolatyari L, Yaftian MR, Rostamnia S, Sep. Sci. Technol. , 54 , 2606, 2019
Dolatyari L, Yaftian MR, Rostamnia S, Sep. Sci. Technol. , 53 (9), 1282, 2018
Dolatyari L, Yaftian MR, Rostamnia S, J. Environ. Manage. , 169 , 8, 2016
Dolatyari L, Yaftian MR, Rostamnia S, J. Taiwan Inst. Chem. Eng. , 60 , 174, 2016
Karmakar R, Singh P, Sen K, Sep. Sci. Technol. , 56 , 2369, 2021
Marczenko Z, Balcerzak M, Separation, preconcentration and spectrophotometry in inorganic analysis, Amsterdam (2000).
Coates J, Interpretation of infrared spectra, a practical approach, encyclopedia of analytical chemistry, Chichester (2000).
Ersoy B, Sariisik A, Dikmen S, Sariisik G, Powder Technol. , 197 (1-2), 129, 2010
Arrigo I, Catalfamo P, Cavallari L, Di Pasquale S, J. Hazard. Mater. , 147 (1-2), 513, 2007
Borges ME, Hernandez L, Ruiz-Morales JC, Martin-Zarza PF, Fierro JLG, Esparza P, Clean Techn. Environ. Policy , 19 , 2113, 2017
Umegaki T, Ogawa R, Toyama N, Ohki S, Tansho M, Shimizu T, Kojima Y, Inorg. Chem. Front. , 4 , 1568, 2017
Thommes M, Kaneko K, Neimark A, Olivier J, Rodriguez-Reinoso F, Rouquerol J, Sing K, Pure Appl. Chem. , 87 , 1051, 2015
Ansari Z, Singha SS, Saha A, Sen K, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr. , 176 , 67, 2017
Singh P, Maiti PK, Sen K, Bull. Mater. Sci. , 43 , 56, 2020
Yokoyama T, Ueda A, Kato K, Mogi K, Matsuo S, J. Colloid Interface Sci. , 252 (1), 1, 2002
Treto-Suarez MA, Prieto-Garcia JO, Mollineda-Trujillo A, Lamazares E, Hidalgo-Rosa Y, Mena-Ulecia K, Sci. Rep. , 10 , 10836, 2020
Kannan C, Muthuraja K, Devi MR, J. Hazard. Mater. , 244-245 , 10, 2013
Chargui F, et al., Boletin de la Sociedad Espanola de Ceramica y Vidrio, 57, 169 (2018).
Ekberg C, Albinsson Y, Comarmond MJ, Brown PL, J. Solution Chem. , 29 , 63, 2000
Beardmore J, Lopez X, Mujika JI, Exley C, Sci. Rep. , 6 , 30913, 2016
Foo KY, Hameed BH, Chem. Eng. J. , 156 (1), 2, 2010
Kaygun AK, Akyil S, J. Hazard. Mater. , 147 (1-2), 357, 2007
Hongxia Z, Zheng D, Zuyi T, Colloids Surf. A: Physicochem. Eng. Asp. , 278 , 46, 2006
Nilchi A, Dehaghan TS, Garmarodi SR, Desalination , 321 , 67, 2013
Chen CL, Wang XK, Appl. Geochem. , 22 , 436, 2007
Abd El-Magied MO, J. Eng. , 2016 , 1, 2016
Foo KY, Hameed BH, Chem. Eng. J. , 156 (1), 2, 2010
Abu El-Soad AM, Abd El-Magied MO, Atrees MS, Kovaleva EG, Lazzara G, Int. J. Biol. Macromol. , 139 , 153, 2019
이전 논문 다음 논문
Result Search