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Korean Journal of Chemical Engineering, Vol.21, No.1, 206-211, 2004
Kinetics of Gas Adsorption on Strongly Heterogeneous Solid Surfaces: A Statistical Rate Theory Approach
A fundamental theoretical investigation is carried out on the applicability of the Condensation Approximation (CA) method of generalizing the theoretical description of the kinetics of gas adsorption/desorption on/from energetically heterogeneous solid surfaces. Our investigation implies that the commonly observed Elovich’s behavior is a consequence of carrying out kinetic experiments at conditions not far from equilibrium. This striking result seems to suggest that the applicability of that popular approximation deserves further fundamental study.
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[Cited By]
- Bae YS, Moon JH, Ahn H, Lee CH, Korean Journal of Chemical Engineering, 21(3), 712, 2004
- Choi BU, Nam GM, Choi DK, Lee BK, Kim SH, Lee CH, Korean Journal of Chemical Engineering, 21(4), 821, 2004
- Shun D, Bae DH, Paek JY, Park YS, Korean Journal of Chemical Engineering, 21(4), 890, 2004
- Jang SC, Yang SI, Oh SG, Choi DK, Korean Journal of Chemical Engineering, 28(2), 583, 2011
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