|
Korean Journal of Chemical Engineering, Vol.29, No.12, 1776-1781, 2012
Synthesis and characterization of nanocomposite MCM-48-PEHA-DEA and its application as CO2 adsorbent
Three nanocomposites containing MCM-48-35PEHA-15DEA (35 and 15 as weight percent of amine addition), MCM-48-30PEHA-20DEA and MCM-48-25PEHA-25DEA of mesoporous silica MCM-48 modified by the mixture of pentaethylenehexamine (PEHA) and diethanolamine (DEA) have been synthesized and used to study the adsorption of carbon dioxide (CO2). They are characterized by low angle x-ray diffraction (XRD), Fourier transform infrared (FT-IR) and Brunauer-Emmet-Teller (BET) analysis. MCM-48-35PEHA-15DEA (as optimized adsorbent)
shows CO2 adsorption capacity of 0.51 (m·mol CO2/g-adsorbent) at 1 bar and 298 K, much higher than CO2 adsorption capacity on polyethyleneimine, pyrrolidinepropyl and polymerized aminopropyl loaded MCM-48.
[References]
- Intergovernmental Panel on Climate Change (IPCC), Climate Change 1995: The Science of Climate Change, Cambridge University Press, 1996
- Bryant E, Climate Process and Change, Cambridge University Press, Cambridge, UK, 1997
- Yokoyama T, In Separations Technology, Queensland, Australia, 2006
- Aaron D, Tsouris C, Sep. Sci. Technol., 40(1-3), 321, 2005
- Kikkinides ES, Yang RT, Cho SH, Ind. Eng. Chem. Res., 32, 2714, 1993
- Hyun SH, Song JK, Kwak BI, Kim JH, Hong SA, J.Mater. Sci., 34, 309, 1999
- Harlick PJE, Sayari A, Ind. Eng. Chem. Res., 46(2), 446, 2007
- Hook RJ, Ind. Eng. Chem. Res., 36(5), 1779, 1997
- Tan CS, Chen JE, Sep. Purif. Technol., 49(2), 174, 2006
- Krutka HM, Sjostrom SJ, Bustard CJ, Paper #08-A--Mega-AWMA., 173, 2008
- Chue KT, Kim JN, Yoo YJ, Cho SH, Yang RT, Ind. Eng. Chem. Res., 34(2), 591, 1995
- Katoh M, Yoshikawa T, Tomonari T, Katayama K, Tomida T, J. Colloid Interface Sci., 226(1), 145, 2000
- Mimura T, Simayoshi H, Suda T, Iijima M, Mituoka S, Energy Convers. Manage., Suppl. S., 57, 38, 1997
- Leci CL, Energy Convers. Manage., Suppl. S., 57, 38, 1997
- Critchfield JE, Su WY, Kenney TJ,Holub PE, US Patent, 5,861,051, 1996
- Anbia M, Hariri SA, Desalination, 261(1-2), 61, 2010
- Anbia M, Lashgari M, Chem. Eng. J., 150(2-3), 555, 2009
- Anbia M, Moradi SE, Appl. Surf. Sci., 255(9), 5041, 2009
- Anbia M, Moradi SE, Chem. Eng. J., 148(2-3), 452, 2009
- Anbia M, Mohammadi N, Mohammadi K, J. Hazard. Mater., 176(1-3), 965, 2010
- Shen SC, Chen XY, Kawi S, Langmuir, 20(21), 9130, 2004
- Macario A, Katovic A, Giordano G, Iucolano F, Caputo D, Micropor. Mesopor. Mater., 81, 139, 2005
- Chaffee AL, Delaney SW, Knowles G, Abstr. Pap. 223rd ACS Nat., Meeting P, 2002
- Huang HY, Yang RT, Chinn D, Munson CL, Ind. Eng. Chem. Res., 42(12), 2427, 2003
- Chang ACC, Chuang SSC, Gray M, Soong Y, Energy Fuels, 17(2), 468, 2003
- Kim S, Ida J, Guliants VV, Lin JYS, J. Phys. Chem. B, 109(13), 6287, 2005
- Anbia M, Mohammadi N, J. Porous. Mater., 18, 13, 2011
- Alfredsson V, Anderson MW, Chem. Mater., 8, 1141, 1996
- Mercier L, Pinnavaia T, J. Environ. Sci. Technol., 32, 2749, 1998
- Yoshitake H, Yokoi T, Tatsumi T, Chem. Mater., 14, 4603, 2002
- Xu XC, Song CS, Andresen JM, Miller BG, Scaroni AW, Energy Fuels, 16(6), 1463, 2002
- Jaroniec CP, Kruk M, Jaroniec M, Sayari A, J. Phys. Chem. B, 102(28), 5503, 1998
- Pierotti RA, Rouquerol J, Siemieniewska T, J. Pure Appl.Chem., 57, 603, 1985
- Leal O, Bolivar C, Ovalles C, Garcia JJ, Espidel Y, Inorg. Chim. Acta., 240, 183, 1995
- Satyapal S, Filburn T, Trela J, Strange J, Energy Fuels, 15(2), 250, 2001
- Yue MB, Sun LB, Cao Y, Wang ZJ, Wang Y, Yu Q, Zhu JH, Micropor. Mesopor. Mater., 114, 74, 2008
- Kim S, Ida J, Guliants VV, Lin JYS, J. Phys. Chem. B, 109(13), 6287, 2005
- Son WJ, Choi GS, Ahn WS, Micropor. Mesopor. Mater., 113, 31, 2008
|