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Korean Journal of Chemical Engineering, Vol.13, No.5, 530-537, 1996
PREPARATION OF SUPPORTED PALLADIUM MEMBRANE AND SEPARATION OF HYDROGEN
Palladium acetate was sublimed at a reduced pressure at 400℃, carried into the macropores of the porous wall of an α-alumina support tube and was decomposed there. A thin palladium membrane which was thus formed showed a hydrogen permeance of 10-6 mol m-2 s-1 Pa-1 and a hydrogen/nitrogen permselectivity higher than 1000. The membrane was stable against hydrogen embrittlement even when the permeation temperature was varied between 100 and 300℃, and it was stable to sulfur or chlorine. To test the ability of this system for the separation of hydrogen and deuterium, a palladium disk was used instead of the prepared membrane since a definite membrane thickness was necessary for calculation. When H2 and D2 permeated through the membrane independently, the H/D permselectivity was appro- ximately 7 at 150-200℃ under a feed side pressure of 0.4 MPa and a permeate side pressure of 0.1 MPa. When a mixture of H2 and D2 was fed, the H/D permselectivity was reduced to 1.2-1.6.
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[Cited By]
- Kim SS, Sea BK, Korean Journal of Chemical Engineering, 18(3), 322, 2001
- Shin EW, Cho SI, Kang JH, Kim WJ, Park JD, Moon SH, Korean Journal of Chemical Engineering, 17(4), 468, 2000
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- Qian H, Zhang L, Xu N, Korean Journal of Chemical Engineering, 20(2), 359, 2003
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