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In relation to this article, we declare that there is no conflict of interest.
Publication history
Received March 4, 2025
Revised June 12, 2025
Accepted July 3, 2025
Available online December 25, 2025
articles This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Latest issues

Recent Developments in Manganese‑Based Materials for Acidic Oxygen Evolution Catalysis

1 Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology (KAIST)
jwlee1@kaist.ac.kr
Korean Journal of Chemical Engineering, December 2025, 42(14), 3333-3346(14)
https://doi.org/10.1007/s11814-025-00512-2

Abstract

Water electrolysis is gaining attention as a method for clean hydrogen production, making the development of efficient acidic

oxygen evolution reaction (OER) catalysts crucial. MnO2,

with its diverse crystalline phases, has emerged as a promising

candidate due to its stability and catalytic activity under acidic conditions. This review explores MnO2-

based catalysts,

focusing on the role of crystal structure, morphology, valence states, and defect engineering in enhancing performance. The

reaction mechanisms of OER, along with the transformation pathways of MnO2

during the reaction, are examined to provide

a deeper understanding of its catalytic behavior. Furthermore, based on these fundamental insights, recent advancements

in MnO2-

based catalysts are reviewed, categorizing them into unsupported catalysts and MnO2

as a support material, with

discussions on noble- and non-noble-metal incorporation strategies for optimizing their practical application in acidic OER.

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