ISSN: 0256-1115 (print version) ISSN: 1975-7220 (electronic version)
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In relation to this article, we declare that there is no conflict of interest.
Publication history
Received June 4, 2025
Revised November 27, 2025
Accepted December 28, 2025
Available online April 25, 2026
articles This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Char Contribution as Heterogeneous Reaction To NO Reduction During Rice Husk Reburning in a Drop Tube Furnace

Department of Mechanical and Automotive Engineering , Kongju National University 1Global Institute of Manufacturing Technology (GITECH) , Kongju National University 2Low-Carbon Emission Control R&D Department, Research Institute of Sustainable Development Technology , Korea Institute of Industrial Technology 3Environment & Energy Engineering Team, Blast Furnace Business Division , Hyundai-Steel Company
stoh@kongju.ac.kr, seongju@kitech.re.kr
Korean Journal of Chemical Engineering, April 2026, 43(5), 1437-1446(10)
https://doi.org/10.1007/s11814-025-00639-2

Abstract

Biomass reburning has emerged as a promising method for reducing nitrogen oxide (NO) emissions. However, a comprehensive

understanding of reburning reactions using biomass remains limited. In particular, the char contribution to NO 

reduction requires further clarifi cation, especially when using rice husk. This study investigates the contribution of rice 

husk char to NO reduction during the reburning process in a drop-tube furnace. The eff ects of reaction temperature, NO 

concentration, and equivalence ratio on the contribution of the homogeneous and heterogeneous reactions were analyzed. 

Results showed that increasing the reburning temperature enhanced the heterogeneous reaction by promoting CO release 

from the char surface, thereby increasing the char’s contribution to the overall reburning reaction. As the initial NO concentration

increased, NO reduction increased for both rice husk and its char; however, due to the limited amount of fuel 

for reburning reactions, the rate of increase in NO reduction decreased. The homogeneous reaction decreased above a 

certain equivalence ratio because oxygen limitation reduced the conversion of intermediate species into N 2 . In contrast, 

the char reaction increased and eventually reached saturation with an increasing equivalence ratio, further enhancing char 

contribution. These fi ndings provide valuable insights for optimizing biomass reburning systems, particularly by clarifying 

the distinct role and operational dependencies of heterogeneous char-NO reactions. 

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